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《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 1998-02
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Hydrothermal Synthesis of a Giant Magnetoresistance Material La 0.5 Ba 0.5 MnO 3 Under Mild Conditions

WANG Dan, YU Ran Bo, FENG Shou Hua , ZHENG Wen Jun PANG Guang Sheng, ZHAO Hui (Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Department of Chemistry, Jilin University, Changchun, 130023)  
A giant magnetoresistance material La 0.5 Ba 0.5 MnO 3 was prepared by hydrothermal method at 240 ℃ for 24 hours. The product was characterized by X ray powder diffraction, differential thermal analysis thermogravimetric analysis, chemical analysis, and iodometry. The compound crystallizes in a cubic system with cell parameters a =0.391 3 nm and V =0.059 90 nm 3 . The average valence state of manganese was 3.5, and the magnetoresistance (MR) is about 29% at 1 T.
【Fund】: 国家自然科学基金
【CateGory Index】: O611.4
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