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《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 1999-03
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Surface Activity of the PAMAM Dendrimer Aqueous Solutions

LONG Fei, FAN Yu, DING Hui\|Jun\+*, JIA Xin\|Ru, LI Ming\|Qian (College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871)  
The generations of 0\^5, 1\^5, 2\^5, 3\^5, 4\^5 of the PAMAM dendrimers and 1, 2, 3, 4 of the PAMAM dendrimers have been synthesized with an EDA core. Surface tensions of the dendrimer aqueous solution have been measured by drop\|volume method. It is showed that (1) the dendrimer aqueous solutions have a surface activity and the order of the surface activity is \%G=4\^5G=3\^5G=2\^5G=1\^5G=0\^5; (2) \%the plateau area of \%G\%=4\^5 is more obvious than those of \%G\%=3\^5 and \%G\%=2\^5, the reason is not clear now; (3) as compared with \%G\%=0\^5, 1\^5, 2\^5, 3\^5, 4\^5 of dendrimer, the cationic ones containing \{\_C\-\{12\}H\-\{25\}\} had a higher surface activity.
【Fund】: 国家自然科学基金
【CateGory Index】: O631
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