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《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 1999-06
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Enantioselective Permeation of Amino Acids Through Cyclodextrin Polymer Membranes

LONG YuanDe, HUANG TianBao (Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041)  
The cyclodextrin polymer membranes based on poly(vinyl alcohol) for enantioselective permeation of amino acids were described. The cyclodextrin membrane modified with acetic anhydride had higher permeation enantioselectivity of DLamino acids than the unmodified membrane. The enhanced abilities were explained as a result of the additional steric hindrance effect besides inclusion. The maximum of enantiomeric excess for DLtryptophan was 254% with the permeation rate of Dtryptophan being up to 14810-5 gmm-2h-1.
【Fund】: 国家自然科学基金 四川省应用基础基金
【CateGory Index】: O641.6
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