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《Paper Science & Technology》 2012-03
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Synthesis of the Cationic Acrylate Copolymer and Its Application in Surface Sizing

Zhang Jun-miao1 Fu Yong-shan2 (1.Sichuan Technology & Business College,Dujiangyan 611830,Sichuan,China; 2.Asia Silicon(Qinghai) Co.Ltd.,Xining 810007,Qinghai,China)  
Cationic acrylate copolymer emulsion was prepared by using monomer materials of dodecafluoro-heptyl methacrylate(RfAA),butyl acrylate(BA),2-Hydroxypropyl acrylate(HPAA) and dimethylaminoethyl methacrylate(DM) as a free radical initiator K2S2O8.The main factors,such as monomer proportion,dosages of initiator and emulsifier,on the copolymer emulsion performance were analyzed.The optimum synthesis conditions were established.Chemical structure of the copolymer was characterized by infrared spectrum(IR) and the particles and particle morphology of polymer emulsion were investigated by transmission electron microscopy(TEM).The results showed that the use of the surface sizing agent only or combined with oxidized starch,the picking speed and the smoothness of the resulted paper reached to more than 280cm·s-1 and 40 seconds respectively.
【CateGory Index】: TS727.5
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【Citations】
Chinese Journal Full-text Database 7 Hits
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【Co-citations】
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