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《Acta Polymerica Sinica》 1993-05
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STUDIES OF INVERSE MICROEMULSION COPOLYMERIZATION OF (2-METHACRY LOYLOXYETHYL) TRIMETHYL AMMONIUM CHLORIDE AND ACRYLAMIDE

HA Runhua, HOU Sjian(Applied Chemistry Department ,Tianjin University, Tianjin, Post code: 300072)  
Using SPAN-OP composite emulsifier and K2S2O8Na2SO3 redox initiator ,the inverse mi-croemulsion copolymerization of (2-methacryloyloxyethyl) trimethyl ammonium chloride (DM. MC) and acrylamide (AM) was developed. The monomer reactivity ratios are rDM.MC= 1.11±0.16 and rAM = 0. 53±0. 08. Under the conditions of total concentration of monomer being 20%-40%(wt), initiator concentration being 0.01%-0. 05%,emulsifier concentration being 10%-18% and polymerization temperature being 299 K,the kinetic equation of copolymerization can be expressed:RP = k[M]1.07[I]0.52[E]0.90. In this paper,above results were explained.
【Fund】: 国家自然科学基金
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【References】
Chinese Journal Full-text Database 10 Hits
1 CHEN Wen-jun, LI Gan-zuo,ZHOU Guo-wei, CHEN Hua, HAN Jun-yan (Key Lab for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan 250100, China);Progress of microemulsion system as microreactor[J];China Surfactant Detergent & Cosmetics;2002-02
2 SHEN Yinghua,XIE Long,WANG Zhizhong(College of Chemical Engineering and Technology,Taiyuan University of Technology,Taiyuan030024,China);Recent development on kinetics of inverse microemulsion polymerization[J];China Surfactant Detergent & Cosmetics;2003-05
3 Li Xiao 1,Zhang Weiying 1,Yuan Huigen 2 (1.College of Chemistry and Chemical Engineering of Fuzhou University, Fuzhou 350002,China; 2.Department of Chemical Engineering of Zhejiang University, Hangzhou 310027,China)[;Mechanism and Modeling for Polymerization of Acrylamide in Inverse Microemulsions[J];Engineering Science;2003-01
4 SHEN Yinghua,XIE Long,WANG Zhizhong(College of Chemical Engineering and Technology,Taiyuan University of Technology,Taiyuan 030024);KINETICS OF THE INVERSE MICROEMULISION POLYMERIZATION OF AM/MADQUAT/NaAMPS[J];Acta Polymerica Sinica;2005-06
5 HA Runhua; HOU Sijian; WANG Desong; SUN Ximing(Department of Applied Chemistry, Tianjin University, Tianjin 300072);THE INVERSE MICROEMULSION POLYMERIZATIONS AT THE HIGH MONOMER CONCENTRATION[J];ACTA POLYMERICA SINICA;1995-06
6 YIN Li song 1,SHEN Hui 2 (1.Center South University, Changsha 410075,China; 2.Guangzhou Institute of Energy Conversion,CAS,Guangzhou 510070,China);Research progress of microemulsification technology for preparing nano particle[J];Journal of Functional Materials;2001-06
7 Li Xiao and Zhang Weiying(Department of Chemical Engineering,Fuzhou University,Fuzhou,Fujian 350002)Yuan Huigen(Institute of Polymer Science and Engineering,Zhejiang University, Hangzhou,Zhejiang 310027);Development in microemulsion polymerization[J];CHINA SYNTHETIC RUBBER INDUSTRY;2000-06
8 Ye Wenyu Liu Zhiguo Zhang Puyu Zhang Juxian (Department Chemistry, Henan University, Kaifeng 475001);Studies of Inverse Emulstion Polymerization of AMPS Initiated by Redox System[J];JOURNAL OF HENAN UNIVERSITY (NATURAL SCIENCE);1997-01
9 Zhu Xiaolei Lan Qing Xie Lincheng Chen Tong(1.Key Laboratory of Karst Environment and Geohazard Prevention,Ministry of Education,Guizhou University,Guiyang 550003;2.College of Resources and Environmental Engineering of Guizhou University,Guiyang 550003);The progress in the poly(AM-MAH) by reverse microemulsion[J];New Chemical Materials;2010-03
10 Li Xiao Liu Ge Yuan Huigen (Institute of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027);KINETICS OF INVERSE MICROEMULSION POLYMERIZATION IN THE SYSTEM OF KEROSINE/SPAN80 TWEEN60/WATER/ACRYLAMIDE[J];CHEMICAL REACTION ENGINEERING AND TECHNOLOGY;1999-01
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Yang Xinyuan,Yu Hui and Bao Yufang (Beijing Research Institute of Chemical Industry,Ministry of Chemical Industry);Copolymerization of Methyl Chloride Salt of Dimethylaminoethyl Methacrylate with Acrylamide and ~1H-NMR Characcterization of the Cationic Copolymers[J];Petrochemical Technology;1988-01
【Co-citations】
Chinese Journal Full-text Database 2 Hits
1 HA Run-Hua , HOU Si-Jian(Department of Applied Chemistry, Tianjin University, Tianjin, 300072);Studies on the Characteristics of Inverse Microemulsion Copolymerization of (2-Methacryloyloxyethyl )trimethyl Ammonium Chloride and Acrylamide[J];Chemical Research In Chinese Universities;1993-08
2 Lu Jianmei, Zhu Xiulin, Yu Jun, Zhu Jian(Department of Chemical Engineering, Suzhou University, Suzhou);SYNTHESIS OF CATIONIC SUPER WATER-ABSORBING RESIN BY MICROWAVE METHOD[J];POLYMERIC MATERIALS SCIENCE & CNGINEERING;1998-01
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 ZHU Chang-jian,CHEN Song-lin,WANG Song,NIE Kang-ming(College of Chemistry and Chemical Engineering,Anhui University,Hefei 230039,China);Preparation of fluorinated acrylate emulsion with core-shell structure[J];Journal of Anhui University(Natural Sciences Edition);2010-01
2 Cheng Guoxiang, Zhang Renbo, Wan Yizao, Shen Feng, Yao Kangde College of Materials Science and Engineering, Tianjin University, Tianjin 300072;PROPERTIES OF REVERSE MICELL MICROREACTORS AND PREPARATION OF Fe 3O 4 NANOPARTICLES[J];ORDNANCE MATERIAL SCIENCE AND ENGINEERING;1998-06
3 SHEN Xinghai\ LI Gailing\ GAO Hongcheng (Department of Technical Physics, Peking University, Beijing, 100871);The Effects of Alcohols on The Stability of the Formed Microemulsion in Extraction Organic Phase[J];ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS;1997-02
4 Meng Kun Zhao Jing-bo Zhang Xing-ying (The Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing University of Chemical Technology, Beijing 100029, China);Preparation of cationic copolymer of DMDAAC/AM by inverse emulsion polymerization[J];Journal of Beijing University of Chemical Technology;2004-05
5 LI Shuo ZHAO ChunFang WU ZeQiang XIONG Yin YU LongJiang(Institute of Resource Biology and Biotechnology,College of Life Science and Technology,Huazhong University of Science and Technology,Wuhan Hubei 430074);Process optimization of the synthesis of anhydrovinblastine using artificial neural networks[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2008-01
6 WANG Jian-quan,WU Wen-hui,LIU Yan,YANG Rong-jie (School of Materials Science and Engineering, Beijing Institute of Technology, Beijing100081, China);Studies on Swelling,Tensile Properties and Network Parameters of HEMA/St Copolymeric Hydrogels[J];Journal of Beijing Institute of Technology;2005-06
7 MA Dong-ping~(1,2),RUAN Xiao-gang~1(1.Electronic Information and Control Engineering School, Beijing University of Technology, Beijing100022, China; 2.Biochemistry Engineering College of Beijing Union University, Beijing100023, China);Prediction Protein Secondary Structure by Improved BP Neural Network[J];Journal of Beijing Union University;2005-02
8 HE Yao-chun,HUANG Bu-geng,WANG Jiang,HOU Shi-fa(Department of Chemical Engineering,Chengde Petroleum College,Chengde,Hebei 067000,China);Synthesis and Properties of Reducing Filtrate Loss of Phosphinomethyl Phenolic Resin[J];Journal of Chengde Petroleum College;2005-03
9 HUANG Jian-shao ZHANG Hong ZHAO Dong-hai (Biology Department,changde Teachers' University, Changde Hunan,415000);THE PREPARTIONA AND CHARACTERIZATION OF IMMOBILIZED PAPAIN ON CHITOSAN[J];Journal of Changde Teachers University;2002-01
10 SHEN Jun-ju~(1,2),ZHUANG Yuan-yi~1(1.College of Environmental Science and Engineering,Nankai University,Tianjin 300071,China;2.School of Chemistry and Material Science,Shanxi Teachers University,Linfen Shanxi 041004,China);Decolorization of Reactive Red K-2BP by Flocculant P(AM-DMC)[J];Urban Environment & Urban Ecology;2006-01
China Proceedings of conference Full-text Database 1 Hits
1 WANG Ya-zhen YAN Hai-bao YANG Guo-xing GONG Zhen-ping WANG Yuan-wu (College of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar 161006,China);Reactivity ratio of acrylonitrile copolymerization determination by infrared spectrum[A];[C];2007
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LIANG Wei-dong et al(School of Petrochemical Engineering,Lanzhou University of Technology,Lanzhou,Gansu 730050);Synthesis and Structural Characterization of Starch-Azo Derivatives Grafting Copolymers in Inverse Emulsion[J];Journal of Anhui Agricultural Sciences;2007-30
2 WANG Cai,WANG Shaohong,HOU Zhaoxia,LU Haoran,WANG Hao,HU Xiaodan, XUE Zhaolu,NIU Changlei(Key Laboratory of Advanced Functional Materials of Shenyang,Shenyang University,Shenyang 110044,China);Advances in preparation of hydroxyapatite nano-particles by inverse micro-emulsions[J];Ordnance Material Science and Engineering;2011-06
3 SHEN Yinghua,XIE Long,WANG Zhizhong(College of Chemical Engineering and Technology,Taiyuan University of Technology,Taiyuan030024,China);Recent development on kinetics of inverse microemulsion polymerization[J];China Surfactant Detergent & Cosmetics;2003-05
4 REN Zhaohua, ZHANG Guanghua(College of Chemistry & Chemical Engineering, Shaanxi University of Science & Technology, Xianyang712081,China);Preparation of nanoparticles with microemulsification technology and its application in coating preparing[J];China Surfactant Detergent & Cosmetics;2003-05
5 ZHU Yin-yan,AN Xue-qin(Jiangsu Key Laboratory of Biofunctional Materials,College of Chemistry and Environmental Science,Nanjing Normal University,Nanjing 210097,China);Preparation of insulin nanocapsules by interfacial polymerization in microemulsion[J];China Surfactant Detergent & Cosmetics;2009-01
6 ZHANG Shi-zhao,XU Bao-cai(School of Chemical and Environmental Engineering,Beijing Technology and Business University,Beijing 100048,China);Special surfactants and functional surfactants(Ⅸ)——Progress in research work with respect to reactive surfactant[J];China Surfactant Detergent & Cosmetics;2010-04
7 CHEN Zilu, YE Hongqi, LIU Hui, HE Xianda(Institute of Powder Technology, College of Chemical Engineering,Central South University, Changsha 410083);The Surface Encapsulation of Ultrafine Metallic Particles by Organic Materials[J];Materials Review;2006-S2
8 BAO Mengru,ZHU Guiru,WANG Meng,GAO Congjie (Key Laboratory of Marine Chemistry Theory and Technology,Ministry of Education,College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao 266100);Progress on Preparation of Mono-dispersed Spherical Nano-silica[J];Materials Review;2011-S2
9 ZHANG Yong, JI Jia-you, LIU Yu School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430073, China;Nanometer Magnetite Prepared by Inverse Micelle Microemulsion Method[J];Journal of Magnetic Materials and Devices;2008-03
10 TANG Guofeng;Revere Mcelle-based chemiluminescence determination of petheidine hydrochloride[J];Journal of Chuxiong Teacher's College;2004-06
China Proceedings of conference Full-text Database 4 Hits
1 ZHU Zhenfeng ZHANG Xin-he HUANGJian-feng (School of Material Science and Technology, Shaanxi University of Science & Technology, Xianyang 712081);Study on Influence of component of microemulsion to its solubilization and structure of CoAl_2O_4 blue pigment[A];[C];2005
2 YANG Kaiji SU Wenqiang SHEN Jing Key Laboratory of bio-based Material science and Technology of ministry of education, Northeast Forestry University,Harbin 150040,China;Synthesization and Application of Amphoteric-Polyacryamide-Based Chemicals[A];[C];2006
3 ZHU Wen - yuan ZHAO Chuan - shan (Shandong Key Laboratory of Pulp and Paper Engineering,Shandong Institute Of Light Industry,Jinan,250100);The Status and Progress of the Study on Amphoteric Polyacrylamide[A];[C];2006
4 Yang Kaiji~(1,2) Su Wenqiang~1 Xu Qinglin~2 Shen Jing~1 (1.Key Laboratory of Bio-based Material Science and Technology of Ministry of Education,Northeast Forestry University Harbin 150040 China; 2.Research Institute of Beijing Hengju Chemical Group Corporation Beijing 101109 China);Preparation and Polymerization of Inverse Microemulsion Polymerization System Based on DADMAC/AM/AA[A];[C];2007
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