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《ACTA POLYMERICA SINICA》 1999-05
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MORPHOLOGY, THER MAL BEHAVIOR, AND MECHANICAL PROPERTIES OF NYLON6/ MULTI- MONOMER GRAFTED POLYPROPYLENE BLENDS

X I E Xuming , C H E N Nianhuan , L I Song( Institute of Poly m er Sci .& Eng ., Tsinghua University , Beijing 100084)  
In a previous study ,the melt grafting of glycidal methacrylate( G M A) and styrene( St) onto polypropylene( P P) was carried out. The multi monomers melt grafted P P, P P g ( G M A co St) was used as a compatibilizer of P A6/ P Pblendsin this study . The addition of P P g ( G M A co St) markedly improved the mechanical properties of the incompatibilized P A6/ P P( P A6 content 70 % ) ,particularly in the tensile strength of the blends . There arealso significant changesin glass transition temperature ( Tg) for the blends characterized by D S Canalysis,implying excellentcompatibility between P A6 and P Pwith the addition ofthe P P g ( G M A co St) . Different blend morphologies were observed by S E M and T E Maccording to the content of P P g ( G M A co St) used . Aspecial novel microphase separatedstructure in the P A6/ P P g ( G M A co St) blends were observed . It should be due to theformation of P P P A6 copolymer by chemical reactions occurred between G M Ain P P g ( G M A co St) and the terminal amino or carboxylic groups of P A6 during the melt mixing . The formation of P P P A6 copolymeris also characterized by F T I R.
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