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《ACTA POLYMERICA SINICA》 2000-01
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STUDY ON THE COPOLYMERIZATION OF MMA WITH RARE EARTH COMPLEXES

WANG Lianhui, LING Qidan, ZHANG Wengong, WANG Wen (Institute of Polymer Science,Fujian Normal University,Fuzhou\ 350007) YANG Mujie, SHEN Zhiquan (Department of Polymer Science and Engineering,Zhejiang University,Hangzhou\ 310027)  
copolymers containing rare earth metal were prepared by the copolymerization of rare earth complexes with Methyl Methacrylate (MMA).The formula of rare erath complexes can be expressed as:RE( β )\-2(AA)( L ) n ,where RE=Sm,Eu,Tb,Ho or Y, β =acac,BA,DBM or TTA,AA=acrylic acid, L =1,10\|phenanthroline(phen),or 2,2′ bipyridyl(bipy), n =0,1 or 2.These rare earth copolymers were characterized by elemental analysis,FT\|IR, 1H\|NMR,XPS,and UV.They are soluble in common organic solvents,such as benzene,chloroform,THF and acetone,which make them useful for forming films.Their molecular weights ( w) are in the range of 20,000~50,000 measured by GPC.Rare earth complex units in copolymers did not dissociate during polymerization and purification.Thermal analysis indicated that copolymers show higher thermal stability than PMMA.The effect of monomer concentration,initiator concentration,solvent,reaction time and temperature on copolymerization were discussed.The kinetic behavior of copolymerization was also investigated.The reactivity ratio of MMA( r \-1) and Sm(BA)\-2(AA)( r \-2) were found to be 1.62 and 0.056,respectively.
【Fund】: 福建省自然科学基金
【CateGory Index】: O634
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