Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Acta Polymerica Sinica》 2002-05
Add to Favorite Get Latest Update


CHENG Shiyuan, CHEN Yanjun, WANG Kangli (The Chemistry and Material Faculty of Hubei University, Wuhan 430062)  
Fluoropolymer films have so low surface energy that they have good special surface properties, such as water resistant, oil resistant and self cleaning properties. Nowdays, surface properties of polyacrylates can be modified by introducing fluorine containing groups to polymer chains. The acrylate copolymer emulsion containing fluorine was prepared, with fluoromoner (Zonyl TM), butyl acrylate (BA), methyl methylacrylate(MMA) as monomers, sodium dodocyl sulfonate (SDS) as emulsifier. The solid content of copolymer emulsion was about 25wt%. The kinetics of emulsion copolymerization was studied by the weight method. The effects of the concentration of emulsifier, initiator, monomer and polymerization temperature on polymerization rate ( R p) were investigated in detail. The results showed that R p∝[SDS] 0 28 , R p∝[I] 0 98 . The apparent activation energy was 50 756?kJ·mol -1 . The copolymer emulsions had no change after stored at room temperature for 72?h, at 60℃ for 48?h and at -5℃ for 24?h respectively. The centrifugal stability of emulsions was characterized at 12000?r/min for 120?min. The sedimentation ratios showed that the centrifugal stability of emulsions increased with increasing the amount of emulsifier, while decreased with increasing the amounts of initiator and fluoromonomer respectively. The latex films could be dissolved in THF and toluene, while could be swelled in methanol and ethanol. The water absorption of latex films decreased with increasing the amount of fluoromonomer. The surface property of films was determined by Wilhelmy method. The contact angles for latex films to water increased apparently by introducing fluorine containing groups, above 100°. This result showed the water resistant property of copolymer latex films containing fluorine was improved.
【CateGory Index】: TQ325.7
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 10 Hits
1 XU Xuan LI Xiao-rui (School of Chemistry and Chemical Engineering.Shanxi University of Science and Technology.Xi'an 710021.Shaanxi);The preparation and an investigation of modified fluoro-acrylate copolymer SAE surface sizing agent[J];China Pulp & Paper Industry;2008-02
2 SHEN Yi-ding,WANG Chun-lei,FEI Gui-qiang,WANG Hai-hua(School of Chemistry and Chemical Engineering,Shaanxi University of Science and Technology,Xi'an 710021,China);The influence of cationic degree on fluo-rinated acrylate copolymer emulsion and the surface properties of its membrane[J];China Pulp & Paper Industry;2009-14
3 ZHOU Chun-Xiao CHEN Guo-Qiang~*(Institute of Material Engineering,Soochow Uinversity,Suzhou Jiangsu 215021,China);Graft Modification of Silk Using Hexafluorobutyl Mathacrylate[J];Science of Sericulture;2006-03
4 Zhou Chunxiao, Zhang Jun & Chen Guoqiang, Institute of Material Engineering, Suzhou University;Water-and-Oil-Repellent Finishing of Silk Fabric[J];China Textile Leader;2006-01
5 ZHAO Xingshun, DING Xiaobin, ZHANG Junhua, ZHENG Zhaohui, PAN Yi, ZHU Zhu, PENG Yuxing (Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041);PREPARATION AND SURFACE PROPERTIES OF ACRYLATE COPOLYMERLATEX CONTAINING FLUORINE[J];Acta Polymerica Sinica;2004-02
6 LIN Yi, YU Zi-li, XU Bin(Analytic and Testing Center, Sichuan University, Chengdu 610064, China);PREPARATION AND CHARACTREIZATION OF FLUOROALKYL METHACRYLATE COPOLYMER EMULSION[J];Polymeric Materials Science & Engineering;2005-05
7 TANG Min-feng,FAN Xiao-dong,LIU Tao,LIU Xiang(Department of Applied Chemistry,School of Science,NorthwesternPolytechnical University,Xi′an 710072,China);Synthesis and Property of Fluorine-Containing Polyacrylate Latex with Core-Shell Structure[J];Polymer Materials Science & Engineering;2007-02
8 LI Xiao-rui,XU Xuan,LI Pei-zhi(Chemistry and Chemical Engineering College,Shanxi University of Science & Technology,Xi'an 710021,China);Synthesis and Surface Propertes of Latex Film of a Cationic Fluoride-Bearing Polyacrylate Emulsion[J];Polymer Materials Science & Engineering;2008-11
9 YANG Ting ting, WANG Shi min, XU Zu shun, CHENG Shi yuan\+* (School of Chemistry and Material Science, Hubei University, Wuhan 430062, China);Progress in Studies of Perfluoroacrylates Polymer Emulsions[J];Polymer Bulletin;2003-06
10 ZHAO Xing-shun, DING Xiao-bin, ZHENG Zhao-hui, PAN Yi, ZHU Zhu, DAI Jing, PENG Yu-xing (Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041 .China);Preparation and Characterization of Fluorine-Containing Copolymer Emulsion[J];Journal of Functional Polymers;2003-04
China Proceedings of conference Full-text Database 2 Hits
1 Cai Jiquan (Transfar Group Co.,Ltd,Xiaoshan,Zhejiang 311215);Studies on Sythesis of fluorosurfactants and application of it in paper-making[A];[C];2007
2 CAI Jiquan (Zhejiang Transfar Co.,Ltd,Hangzhou,311215,Zhejiang,China);Innovation and Development of Fluorosurfactant[A];[C];2008
Chinese Journal Full-text Database 4 Hits
1 LI Kun, GUO Jianhua, LI Xinxin, WU Pingping, HAN Zhewen (Department of Polymer Science and Engineering,East China University of Science & Technology,Shanghai\ 200237);SYNTHESIS AND CHARACTERIZATION OF DIBLOCK COPOLYMER OF BUTYL METHACRYLATE AND PERFLUOROALKYL ACRYLATE[J];Acta Polymerica Sinica;2002-02
2 LIU Jinhui; LI Xiaoyu; JIAO Shuke(Department of Polymer Science, Beijing, University of Chemical Technology, Beijing, 100029);A KINETIC STUDY ON EMULSION COPOLYMERIZATION OF BUTYL ACRYLATE AND STYRENE USING CATIONIC EMULSIFIER[J];ACTA POLYMERICA SINICA;1995-04
3 YU Zhang\|qing (Department of Chemistry and Chemical Engineering,Suzhou University,Suzhou 215006,China);Research and Application of the Fluoropolymer Latex Used for Coatings[J];POLYMER BULLETIN;2000-02
4 XU Zu shun, CHEN Zhong hua, TU Wei ping, YANG Zhuo ru, CHEN Huan qin (Research Institute of Chemical Engineering, South China University of Technology, Guangzhou 510640, China);Studies and Application of Fluorine-Containing Polymer Emulsions[J];JOURNAL OF FUNCTIONAL POLYMERS;2000-02
Chinese Journal Full-text Database 10 Hits
1 Wang Xiaobing1,2, He Shangjin2, Zhang Baolong2, Zheng Wei1, Jin Ziming1(1.CNGC Institute 53, Jinan 250031, China; 2.Department of Chemistry, Nankai University, Tianjin 300071, China);STUDY ON BLOCK POLYMERIZATION OF (METH)ACRYLATE AND PROPERTIES OF EP/DDM/COPOLYMER CURED SYSTEMS[J];Engineering Plastics Application;2007-12
2 ZHAO HongChi GAO LingLing Qiao Bing GAO JunGang(College of Chemistry and Environmental Science,Hebei University,Baoding Hebei 071002,China);Synthesis and polymerization kinetics of styrene-ethyl acrylate-vinyltrimethoxysilane copolymers[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2009-04
3 LI Zhong-ming,WAN Kun,ZHENG Qi(College of Chemical and Environment Engineering,Jianghan University,Wuhan 430056,China).;Effects of Pretreating with Organic Compounds Containing Fluorine/Silicon on Modified Styrene-Acrylate Emulsion[J];Materials Protection;2004-09
4 HAN Lei,ZHANG Qiu-yu(Department of Applied Chemistry,Northwestern Polytechnical University,Xi′an 710072,China);Recent Progress in Study of Antifouling Coatings with Low Surface Energy[J];Materials Protection;2006-02
5 HE Ling LIANG Guozheng LAN Liwen (Chemical Engineering Department,Northwestern Polytechnical University,Xi'an 710072,China);A Review of Studies of Fluorine-Containing Polymer Coating[J];Materials Review;2002-02
6 XIAO Xinyan1,LIU Jianfei1,WAN Caixia2,ZHANG Huiping1(1 School of Chemical & Energy Engineering,South China University of Technology,Guangzhou 510640;2 College of Chemistry,South China University of Technology,Guangzhou 510640);Progress in the Fluorine-containing Polymer Self-stratifying Functionalized Gradient Materials[J];Materials Review;2007-06
7 TANG Feng, ZHANG Xin-ya, FU He-qing, HUANG Hong, CHEN Huan-qin (Research Institute of Chemical Engineering, South China University of Technology, Guangzhou 510640, China);New trend of study on organofluorine coatings[J];Electroplating & Finishing;2004-02
8 LIAN Yuan1,XING Hong-long2(1.Experiment Center of Biology and Chemical Engineering,JiaXing University,JiaXing 314001,China; 2.Department Of Chemical Engineering,Anhui University of Science and Technology,Huainan 232001,China);Kinetics of Emulsion Copolmerization of Quadipolymer Reactive Microgel[J];Journal of Fuyang Teachers College(Natural Science);2007-01
9 ZHANG Qing-hua, ZHAN Xiao-li, CHEN Feng-qiu (Department of Chemical Engineering,Zhejiang University,Hangzhou, Zhejiang 310027,China);Synthesis and properties of the FA/LMA/MMA copolymer emulsion[J];Journal of Textile Research;2005-02
10 LIAO Yong-Qin, WANG Qi *, WANG Liang-Wen (State Key Laboratory of Polymer Material Engineering, Institute of Polymer Research, Sichuan University, Chengdu 610065, China);Studies on Kinetics of Ultrasonic Induced Microemulsion Polymerization of MMA[J];Chemical Research In Chinese Universities;2002-11
China Proceedings of conference Full-text Database 4 Hits
1 ZHANG Xin-ya, TANG Feng, LAN Ren-hua, CHEN Huan-qin (Research Institute of Chemical Engineering, South China University of Technology, Guangzhou 510640,China);New development in fluororesin building coatings[A];[C];2004
2 SUN Rong, LI Xiao-hong, ZHANG Zhi-jun, DANG Hong-xin (Laboratory of Special Functional Materials, Henan University, Kaifeng 475001, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China);Synthesis and Friction-reducing Behavior of Unsaturated Polyester[A];[C];2002
3 LIN Min, GU Kali (Wuhan research institute of material protection, Wuhan, 430030);Several excellent cathodic electrophoretic coatings in future[A];[C];2006
4 Ma Jifeng Dai Hongqi (Nanjing Forestry University,Nanjing 210037);The Application of St-BA Cationic Copolymer Latex in Ink-jet Paper[A];[C];2005
Chinese Journal Full-text Database 10 Hits
1 Hao Ladi Editorial Office of Journal of Dalian Fisheries University,116023,Dalian,Liaoning,China,Yu Huadong;On use of orthogonal experimental design[J];Acta Editologica;2005-05
2 CHEN Xiang nan(74);Developing Trends of Fluoropolymer Coating[J];MATERIAIS PROTECTION;2000-01
3 LIU Fu-chun,HAN En-hou,KE Wei(Institue of Metal Research,The Chinese Academy of Sciences Shenyang,P.R.China 110015).;Present Status and Development of Nano-composite Coations[J];Materiais Protection;2001-02
4 LIN An, CHENG Xue-qun, ZHANG San-ping, PAN Ying, TANG Shu-qiong, ZHANG Xue-feng (Wuhan Research Institute of Materials Protection, Wuhan 430030, China);Surface Chemical Modifications of Nano-Titanium Oxide and its Applications in Coating[J];Materiais Protection;2002-11
5 Kong Xiangming Xie Xuming Zhang ZengminDepartment of Chemical Engineering, Tsinghua University, Beijing 100084,P. R. China;Study on Formation of Gradient Structure in Polymer Blends by Self-organization[J];Materials Review;2000-01
6 XIA Zhengbin TU Weiping CHEN Huanqin (Chemical Engineering College,South China University of Technology,Guangzhou 510640);Progress in Studies on Synthesis of Waterborne Fluorine-Containing Polymers[J];Materials Review;2003-03
7 ZHAI Lanlan LING Guoping (College of Materials Science and Chemical Engineering,Zhejiang University,Hangzhou 310027);The Adhesion between Polymer Coating and Metal and Its Research Progress[J];Materials Review;2005-07
8 ZHANG Xinya,SUN Zhijuan, HUANG Hong, LI Yongjin,CHEN Huanqin(Research Institute of Chemical Engineering, South China University of Technology, Guangzhou 510640);Research Progress in Zero-VOC Latex Coatings[J];Materials Review;2006-08
9 XU Yue, LI Ying-jie, LU Zu-shun, GUO Yuan-dong, YANG Yu (School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, Dept. of Applied Chemistry,Harbin Institute of Technology,Harbin 150001, China; Hech- eng Science and Technology Co. ,Ltd. ,Nankai University, Tianjin 308371,China);Technique and application of anticorrosion coatings prepared by Sol-gel method[J];Material Science and Technology;2005-02
10 Bai Xiue Chen Guoqiang(College of Material Engineering,Soochow University,Suzhou 215021);The Effect of Initiationless Graft Copolymerization on Silk Fibre Properties[J];Acta Sericologica Sinica;2002-04
China Proceedings of conference Full-text Database 1 Hits
1 WANG Xiu-hua, WANG Ling, WENG Lu-qian, WANG Qin, WANG Han, TAI Guo-an (School of material science and technology. Naniine University of Aeronautics and Astronautics. Naniine 210016. China);Preparation and characterization of organic -inorganic hybrid nanocompsites and coatings[A];[C];2004
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 CHEN Ping,HUANG Yi-ping,RU Ling,CHEN Lei,ZHANG Yan(School of Chemistry and Chemical Engineering,Anhui University,Hefei 230039,China);Determination of Fluor-acrylate terpolymer system Reactivity-ratios[J];Journal of Anhui University(Natural Sciences);2008-03
2 HUANG Zun-qiao1,CHEN Guang-mei2 (1.Qiqiao Chemical Engineering Ltd. Co.,Hangzhou 310026,China; 2.Anhui Institute of Architecture and Industry,Hefei 230601,China);Syntheses and Studies on the Properties for Fluorine-containing Acrylate Copolymer Latex[J];Anhui Chemical Industry;2007-02
3 WANG Luyan,SUN Yanpin(Research Institute of Clean Chemical Engineering,Taiyan University of Technology,Taiyuan 030024);Research Progress in Photo-degradation Resistance and Durable Antimicrobial Property of Nano-crystalline TiO_2 Composite Fiber/Fabric[J];Materials Review;2006-09
4 MA Wen-yan, CHEN Ke-fu, LIAO Xu-shen, YANG Fei, YANG Ren-dang, LI Jun (State Key Laboratory of Pulp and Paper Engineering, Guangdong Public Laboratory of Paper Technology and Equipment, South China University of Technology, Guangzhou 510640, China);Synthesis and properties of cationic polymerized surfactant DMSB[J];China Pulp & Paper Industry;2009-10
5 HOU Zai-jian a, b, MENG Wei-dong a, b(a. College of Chemistry, Chemical Engineering and Biotechnology;b. Key Laboratory of Science and Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai 201620, China);The Synthesis and Application of Polyperfluoroalkylalcohol[J];Journal of Donghua University(Natural Science);2009-01
6 Shen Shu-Chang*1, Zhang Wei-Bing2, Fu Shuang1, Liu Cai-Yun1, Li Xiao-Long11(Collge of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006)2(Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116011);Preparation Phenylethylene-Butyl Acrylate Vinyltriethoxy Siloxane Terpolymer for Solid Phase Microextraction Coating[J];Chinese Journal of Analytical Chemistry;2007-06
7 PAN Wenyan~(1,2),LIU Yanjun~(1,2),SUN Xiangshan~2,WANG Wei~2(1.Department of Chemistry Engineering,Dalian Institute of Light Industry,Dalian,Liaoning 116034,China;2.Liaoning Fluorine Material Institute,Dalian,Liaoning 116036,China);Properties and application of fluorine-containing textile finishing agent emulsion[J];Journal of Textile Research;2007-09
8 AN Qiufeng,FU Yongshan,XU Yongjing(Chemistry and Chemical Engineering College,Shaanxi University of Science and Technology,Xi′an,Shanxi 710021,China);Preparation and application of fluorinated acrylate emulsion[J];Journal of Textile Research;2008-08
9 LI Jun,GENG Hongbin,CHEN Qingmin(Department of Polymer Science and Engineering,State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093);MODIFICATION OF NATURAL RUBBER LATEX BY RADIATION GRAFTING WITH PERFLUOROALKYLETHYL METHACRYLATE[J];Acta Polymerica Sinica;2006-06
10 ZHANG Jide,YANG Mujie,YANG Huan,ZHU Yangrong(Department of Polymer Science and Engineering,Zhejiang University,Hangzhou 310027);SYNTHESIS,CHARACTERIZATION AND CROSSLINKING REACTION OF REACTIVE COMPOSITE LATEX[J];Acta Polymerica Sinica;2006-07
China Proceedings of conference Full-text Database 2 Hits
1 CHEN Weihong,DU Wenfeng,XU Xiaonan,Guo Zidong,He Wei (Department of Fire Protection Engineering,Chinese People's Armed Police Academy,Langfang 065000,China);Effect of Fluorocarbon Surfactants on Anti-Solubility and Anti-Burning Performance of Hollow Microsphere Three-Phase Foam[A];[C];2008
2 Cai Jiquan (Transfar Group Co.,Ltd,Xiaoshan,Zhejiang 311215);Studies on Sythesis of fluorosurfactants and application of it in paper-making[A];[C];2007
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 Pan Huiming, An Yingzan, Dong Ruqin (The Chemical Industry Institute of Chenguang);DETERMINATION OF THE SURFACE ENERGY OF SOME FLUOROPOLYMERS[J];;1981-05
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved