Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Acta Polymerica Sinica》 2004-02
Add to Favorite Get Latest Update

SYNTHESIS AND CHARACTERIZATION OF NOVEL HYDROGELS OF POLY(DMAEMA-co-β-CYCLODEXTRIN ACRYLATE)

HUANG Yi, FAN Xiaodong, HU Hui (Department of Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072)  
Two kinds of β-cyclodextrin(β-CD)-acrylic monomers,β-CD-3-A and β-CD-6-A,carrying the acryl groups were synthesized relying on their reactivity of different hydroxyl groups in cyclodextrin. 13C-NMR spectra indicated that,for β-CD-3-A,acylation occurs at C-2 and C-3 positions of β-CD,and for β-CD-6-A,the acylation occurs at its C-2 and C-6 positions. Two functional hydrogels were synthesized by copolymerization of β-CD-3-A and β-CD-6-A with N,N-dimethylaminoethyl methacrylate(DMAEMA) using a redox initiator system in aqueous solutions. The hydrogels were characterized by FTIR and elementary analysis. The equilibrium swelling experiments show that the hydrogels possess pH-,ionic strength and thermo-sensitivities. However,due to the difference of monomer structures,the physical properties of the two hydrogels,especially their swelling behavior in response to the external stimuli,exhibit certain difference. It is reasonable to assume that the structure of β-CD-3-A in its hydrogel is more favorable to initiate hydrophobic interactions between dimethylaminoethyl segments and hydrophobic caves in β-CD,as a result,reducing the hydrogel's transition points. It can also be observed that the transition regions for both hydrogels shift to lower temperatures with the increase in contents of β-CD-3-A or β-CD-6-A.
【Fund】: 陕西省自然科学基金资助项目 (基金号 2 0 0 0H11)
【CateGory Index】: O631
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 HU Hui, FAN Xiaodong, HUANG Yi(Department of Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072);SYNTHESIS AND CHARACTERIZATION OF THE THERMO- AND pH SENSITIVE STAR POLYMERS WITH A RIGID CORE OF β-CYCLODEXTRIN[J];Acta Polymerica Sinica;2004-06
2 HU Hui, LIU Yuyang, FAN Xiaodong, HUANG Yi (Department of Applied Chemistry, Northwestern Polytechnical University, Xi'an\ 710072);SYNTHESIS OF THERMO- AND pH SENSITIVE POLYMER BEADS CONTAINING β-CYCLODEXTRIN AND POLY(N, N-DIMETHYLAMINOETHYL METHACRYLATE AND THEIR CONTROLLED DRUG RELEASE BEHAVIOR[J];Acta Polymerica Sinica;2005-03
3 PAN Tong~1,ZHANG Guolin~3,MA Jianbiao~2( ~1Department of Chemistry & Envimmental Engineering, Changsha University of Science and Technology, Changsha 410077)( ~2Institute of Polymer Chemistry, Nankai University, Tianjin 300071)( ~3School of Chemical Science and Engineering, Liaoning University, Shenyang 110036);SYNTHESIS AND CHARACTERIZATION OFβ-CYCLODEXTRIN/POLY(DL-LACTIDE) GRAFT COPOLYMERS[J];Acta Polymerica Sinica;2006-02
4 HU Hui, CAO Zhonglin, FAN Xiaodong, Huang Yi(Department of Applied Chemistry, Northwestern Polytechnical University, Xi'an 710072);SYNTHESIS AND CHARACTERIZATION OF THE THERMO-AND pH-SENSITIVE DENTRITIC POLYMERS BASED ON POLYAMIDOAMINE DENDRIMER AND POLY(N,N-DIMETHYLAMINOETHYL METHACRYLATE) AND STUDY ON THEIR CONTROLLED DRUG RELEASE BEHAVIOR[J];Acta Polymerica Sinica;2006-04
5 WANG Jing,JIANG Ming(The Key Laboratory of Molecular Engineering of Polymers,Department of Macromolecular Science,Fudan University,Shanghai 200433);STUDIES ON SELF-ASSEMBLY FROM LIGHTLY-CROSSLINKED POLYMERS via INCLUSION INTERACTION[J];Acta Polymerica Sinica;2007-10
6 TIAN Wei,FAN Xiaodong,JIANG Min,WANG Shengjie,LIU Yuyang,YU Yu(Department of Applied Chemistry,School of Science,Northwestern Polytechnical University,Xi'an 710072);STNTHESIS AND CHARACTERIZATION OF HYPERBRANCHED POLYCARBOSILANE-g-CYCLODEXTRIN POLYMER BRUSHES[J];Acta Polymerica Sinica;2007-11
7 XIE Xiao-rui,ZHANG Li-ming,YI Ju-zhen (Institute of Polymer Science,School of Chemistry and Chemical Engineering,Sun Yat-Sen University,Guangzhou 510275,China);The Advance of Biodegradable Polymer Drug Film[J];Chinese Polymer Bulletin;2006-12
8 DING Ping-ping1,2,FU Xiang-kai1,2,CHEN Zhu-jun1,2,TU Xiao-bo1,2(1.Research Institute of Applied Chemistry,College of Chemistry and Chemical Engineering,Southwest China University,Chongqing 400715,China;2.Key Laboratory of Applied Chemistry of Chongqing Municipality,Chongqing 400715,China);Study on the characteristics and application of the temperature-sensitive N-isopropylacrylamide copolymer with methacrylate segments[J];Journal of Functional Materials;2009-04
9 Li Zhijun1, Ye Wei2 (1. College of Science and Technology, Nanchang Hangkong University, Nanchang 330034; 2. Department of Chemistry, Institute of Chemical Defense, Beijing 102205);Sensitivity Research on Poly(DMAEMA) Hydrogels[J];Chemical Production and Technology;2009-02
10 WU Sheng-hui,LI Yi,YANG Fen,WANG Yu-ling,SONG Hong-rui (School of Pharmaceutical Engineering,Shenyang Pharmaceutical University,Shenyang 110016,China);Synthesis and Properties of pH-and Temperature-sensitive Hydrogel[J];Fine Chemical Intermediates;2007-03
【Citations】
Chinese Journal Full-text Database 3 Hits
1 CHEN Yanfeng, YI Min (Department of Technical Physics, Peking University, Beijing\ 100871);UV-SYNTHESES AND PROPERTIES OF RESPONSIVE HYDROGELS CONTAINING N,N-DIMETHYLAMINOETHYL METHACRYLATE[J];Acta Polymerica Sinica;2001-02
2 ZHUO Renxi, ZHANG Xianzheng (Department of Chemistry,Wuhan University,Wuhan\ 430072);THE SYNTHESIS AND CHARACTERIZATION OF TEMPERATURE AND pH SENSITIVE POLY(ACRYLIC ACID)/POLY (N ISOPROPYLACRYLAMIDE)IPN HYDROGEL[J];ACTA POLYMERICA SINICA;1998-01
3 Liu Xiaohua, Wang Xiaogong, Liu Deshan(1);Recent Development of the Research on the Structure Effects and Responsive Mechanism of Intelligent Hydrogels[J];CHEMISTRY;2000-10
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 XU Li xin 1 WANG Xiu fen 1 GAN Ni 1 ZHANG Li qun 2(1.The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education; 2.Key Laboratory for Nanomaterials,Minstry of Education, Beijing University of Chemical Technology, Beijing 100029,China);Preparation of intelligent calcium alginate/PNIPAAm interpenetrating network hydrogel beads[J];Journal of Beijing University of Chemical Technology;2005-01
2 YANG Lianli ,LIANG Guozheng(College of Science , Northwestern Polytechnical University , Xi’an 710721);Hot-spot Research and Application of Hydrogel in Biomedicine Field[J];Materials Review;2007-02
3 ZHANG Qingsong1,2, ZHA Liusheng1,2, MA Jinghong1,LIANG Borun1(1 State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 200051;2 Research Center for Analysis and Measurement, Donghua University, Shanghai 200051);The Latest Advance in the Research on pH and Temperature-sensitive Polymer Gels[J];Materials Review;2007-05
4 REN Mingfang,XU Muhui,WANG Hua,XU Jiwen(Department of Information Material Science and Engineering,Guilin University of Electronic Technology,Guilin 541004);Study on Properties of ZAO Thin Films Prepared by Sol-gel Process[J];Materials Review;2009-02
5 ZHAO Yi-ping,CHEN Li,ZHAO Guo-bu(School of Material Science and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300160, China);Study on Gel-modification of Nylon-6 Fishnet Materials by UV Irradiation[J];Journal of Materials Science and Engineering;2005-05
6 ZHAO Zhenxia~(1,2) LI Zhong~(1**) XIA Qibin~2 XU Jinfang~1 1.School of Chemical and Energy Engineering,Key Laboratory of Enhanced Heating Transfer and Energy Conservation,Ministry of Education,South China University of Technology,Guangzhou 510641 2.School of Chemical and Energy Engineering,Guangdong Provincial Laboratory of Green Chemical Technology,Guangzhou 510640;Microwave irradiation preparation and properties of PNIPAAm copolymer hydrogel[J];Chinese Journal of Materials Research;2008-04
7 YANG Ming-cheng1,2, HE Su-qin1, LIU Wen-tao1, SONG Hong-yan1, ZHU Cheng-shen1 1 School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450052, China 2 Isotope Institute of Henan Academy of Sciences, Zhengzhou 450015, China;Characterization of pH-sensitive Poly (acrylic acid-co-N-vinyl-2-pyrrolidone) Hydrogels Prepared by Gamma Radiation[J];东华大学学报(英文版);2007-04
8 ZHANG Gao-qi~1, ZHOU Mei-hua~2, MA Jing-hong~1, LIANG Bo-run~1(1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 200051; 2. College of Environment Science and Engineering, Donghua University, Shanghai, 200051);Preparation and Swelling Properties of Cross-linked Poly (cis-1,4 butadiene) Organogels[J];Journal of Donghua University,Natural Science;2004-02
9 SHI Yan-li,XU Ya-jing,ZHANG Gao-qi,MA Jing-hong, LIANG Bo-run(State Key Laboratory for Modification of Chemical Fibers and Polymer, Donghua University,Shanghai,200051);Preparation and Performance Characterization of pH/Temperature-sensitive Carboxymethylchitosan/Poly(N-isopropylacrylamide) Semi-IPN Hydrogels[J];Journal of Donghua University,Natural Science;2005-06
10 GAO Qingyu 1,2 , ZHANG Yujuan 2, YU Xianda 1 ( 1Institite of Lanzhou Chemistry and Physics, Chinese Academy of Sciences, Lanzhou\ 730000) ( 2Laboratory of Lubrication and Functional Materials, Henan University, Kaifeng\ 475001);THE SYNTHESIS AND CHARACTERIZATION OF THERMO- AND pH-SENSITIVE POLY( N -VINNYLPYRROLIDONE-co-β-HYDROPROPYL ACRYLATE)/POLY(ACRYLIC ACID) IPN HYDROGEL[J];Acta Polymerica Sinica;2001-03
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 SHI Shu xian XIA Yu zheng GUO Zu peng JIAO Shu ke LI Xiao yu (College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China);Synthesis and characterization of D,L-lactide[J];Journal of Beijing University of Chemical Technology;2003-02
2 Cui Dafu, Cao Qiang, Han Jinghong, Cai JineLi Yating, Zhu Zemin, Fan Jie, Gao Ning(Institute of Electronics, Academia Sinica);Optical Fibre pH Sensor[J];Journal of Transducer Technology;1991-06
3 Chen Yan Tang Xiaodou (Chenguang Chemical and Industry Institute,China National Blue Star,Chengdu 610041)Dai Yafei (Jiangsu Chang Long Chemicals Co.,Ltd,Jiangsu 213031);A Study of Biodegradable Polymers as Drug Carriers[J];Materials Review;2001-09
4 LI Xin-gui,XIA Yu,HUANG Mei-rong (Tongji University, Shanghai 200092, China);Electrochromic Property of Conducting Polymers and Their Application on Smart Windows[J];Development and Application of Materials;2004-02
5 Zhang Shenglan, Shen Xinyuan and Yang Qing;pH-Sensitive Polymer Materials[J];Technical Textiles;2000-04
6 ;β-cyclodextrin sulfate:study on toxicity[J];Academic Journal of Second Military Medical University;2005-09
7 WANG Man-li, HU Pan-pan (State Key Laboratory for Modification of Chemical Fiber and Polymer Materials, Donghua University, Shanghai, 200051);Structure Analysis of HEMA and DMEAMA Copolymer[J];Journal of Donghua University,Natural Science;2004-06
8 WANG Chun yan,WU Zong hua (Institute of Polymer Science, Fujian Teachers University, Fuzhou 35007,China);The Synthesis of the Low-molecular-weight Polyacrylamide by Precipitation Polymerization[J];Journal of Fujian Teachers University(Natural Science);2002-04
9 Li Peizhi , Mao Minyuan, Zhu Tingting (Department of Applied Chemistry, Jiangnan University, Wuxi 214063);Study of the Drugs β-Cyclodextrin Inclusion Complexes by Cyclic Voltammetry[J];Chinese Journal of Analytieal Chemistry;1994-01
10 Zhu Lizhong, Lu Zhoushun, Qi Wenbin (Department of Environmental Science, Hangzhou University, Hangzhou 310028);Some Factors for Improving Fluorescence Enhancement of β-Cyclodextrin and its Derivatives on Naphthylamine[J];Chinese Journal of Analytieal Chemistry;1997-05
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 CHEN Li-gui et al(College of Material Science and Engineering,Shaanxi University of Technology,Hanzhong,Shaanxi 723003);Swelling Kinetics of Konjac Glucomannan/Poly(Acrylic Acid) Hydrogels and Affecting Factors of its Performance[J];Journal of Anhui Agricultural Sciences;2007-29
2 Yang Xiaoling1,Chen Youning1,Jiang Yufeng2,Zhao Wei1(1.Department of Chemistry,Xianyang Normal University,Xianyang 712000;2.Huangshi Institute of Technology,Huangshi 435003,China);Synthesis and Characterization of Corn-starch/β–cyclodextrin Composite Microspheres as Drug Carrier[J];Guangdong Chemical Industry;2007-10
3 Pan Cuilin,Zhou Hongbin,Yin Guoqiang,Zeng Shuangxia,Cai Chou(Department of Chemical Engineering,Zhongkai University of Agriculture and Technology,Guangzhou 510000,China);Preparation of Planting Colorful Absorbent Polymer[J];Guangdong Chemical Industry;2008-05
4 PAN Tong~1,ZHANG Guolin~3,MA Jianbiao~2( ~1Department of Chemistry & Envimmental Engineering, Changsha University of Science and Technology, Changsha 410077)( ~2Institute of Polymer Chemistry, Nankai University, Tianjin 300071)( ~3School of Chemical Science and Engineering, Liaoning University, Shenyang 110036);SYNTHESIS AND CHARACTERIZATION OFβ-CYCLODEXTRIN/POLY(DL-LACTIDE) GRAFT COPOLYMERS[J];Acta Polymerica Sinica;2006-02
5 WANG Xin,FAN Xiaodong,WANG Shengjie,KONG Jie,LIU Yuyang,GONG Yan(Department of Applied Chemistry,School of Science,Northwestern Polytechnical University,Xi' an 710072);SYNTHESIS AND CHARACTERIZATION OF HYPERBRANCHED POLY(SILOXYSILANES)[J];Acta Polymerica Sinica;2006-09
6 WANG Jing,JIANG Ming(The Key Laboratory of Molecular Engineering of Polymers,Department of Macromolecular Science,Fudan University,Shanghai 200433);STUDIES ON SELF-ASSEMBLY FROM LIGHTLY-CROSSLINKED POLYMERS via INCLUSION INTERACTION[J];Acta Polymerica Sinica;2007-10
7 TIAN Wei,FAN Xiaodong,JIANG Min,WANG Shengjie,LIU Yuyang,YU Yu(Department of Applied Chemistry,School of Science,Northwestern Polytechnical University,Xi'an 710072);STNTHESIS AND CHARACTERIZATION OF HYPERBRANCHED POLYCARBOSILANE-g-CYCLODEXTRIN POLYMER BRUSHES[J];Acta Polymerica Sinica;2007-11
8 GAO Min, WANG Bingbing, JIA Xinru, LI Wusong, KUANG Guichao(Department of Polymer Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Beijing 100871)WEI Yen(Department of Chemistry, Drexel University, Philadelphia, PA 19104, USA);PHOTO AND H~+ DUAL-RESPONSIVE BEHAVIORS OF AZOBENZENE-SHELLED POLY(AMINOAMINE) DENDRIMERS[J];Acta Polymerica Sinica;2008-01
9 HUANG Yi1,YANG Zhen1,HUANG Fang-qian1,JING Ya-ping1, WANG Cui1,FAN Xiao-dong2 (1.Department of Chemistry,Xianyang Normal College,Xianyang 712000,China; 2.Department of Applied Chemistry,Northwestern Polytechnical University,Xi'an 710072,China);Preparation and characterization of a novel responsive hydrogel with β-cyclodextrin[J];Journal of Functional Materials;2007-05
10 CHEN Wei-xing,FAN Xiao-dong,LIU Yu-yang(School of Science,North-western Polytechnical University,Xi'an 710072,China);Study on the self-assembly and the drug controlled release of amphiphilic star block copolymer[J];Journal of Functional Materials;2008-04
【Secondary Citations】
Chinese Journal Full-text Database 6 Hits
1 GUO Kai LI Jun YI Min (Department of Technical Physics, Peking University,Beijing 100871) The work was supported by Foundation of Nuclear Science (No. Y7197FY006);PHOTOGRAFTING OF ACRYLIC ACID ONTO POLY(ETHYLENE TEREPHTHALATE) FILM[J];JOURNAL OF RADIATION RESEARCH AND RADIATION PROCESSING;1999-02
2 YU Xisheng, TONG Shuixin and SUN Yishi(Department of Chemical Engineering, Tinghua University, Brijing;ON SYNTHESES AND PROPERTIES OF TEMPERATURE SENSITIVE HYDROGELS[J];Acta Polymerica Sinica;1989-04
3 DU Fusheng, ZHENG Peng, LI Fumian(Department of Chemistry, Peking University Beijing, Post code: 100871);PHOTOPOLYMERIZATION OF ACRYLONITRILE INITIATED BY POLYMERIZABLE BENZOPHENONE-ALIPHATIC TERTIARY AMINE PHOTO-REDOX INITIATION SYSTEM[J];Acta Polymerica Sinica;1992-03
4 LI Wangjin, HUANG Lan, LI Fumian(Department of Chemistry, Peking University, Beijing, Post code: 100871);SYNTHESES AND POLYMERIZATION OF ACRYLATES HAVING LACTAM MOIETY[J];Acta Polymerica Sinica;1993-01
5 JIN Manrong; ZHANG Guiying; WU Changfa; LIU Peiyi; HOU Wei(Department of Pharmacy, Tianjin Second Medical College.Tianjin 300203);N-ALKYL ACRYLAMIDE GELS AND THEIR TEMPERATURESENSITIVE PROPERTIES[J];ACTA POLYMERICA SINICA;1995-03
6 GAO Qingyu,\ YANG Gengxu,\ CUI Yuanchen,\ ZHANG Fulian,\ ZHANG Juxian (Department of Chemistry,Henan University,Kaifeng 475001) LI Fumian (Department of Chemistry,Peking University,Beijing 100871);PHOTOPOLYMERIZATION OF ACRYLONITRILE INITIATED BY POLYMERIZABLE PHOTO REDOX INITIATION SYSTEM CONSISTING OF N (4 BENZOYLPHENYL) ITACONIMIDE AND N,N DIMETHYLAMINOETHYL METHACRYLATE[J];ACTA POLYMERICA SINICA;1997-06
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved