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《Acta Polymerica Sinica》 2004-02
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SYNTHESIS AND CHARACTERIZATION OF FAN-SHAPE PAMAM DENDRONS

WANG Bingbing, LUO Yufei, JIA Xinru, GONG Yongmei, JI Yen, YANG Ling (College of Chemistry, Peking University, Beijing 100871, China) Yen Wei (Chemistry Department, Drexel University, Philadelphia, PA 19104, USA)  
An azyl group of ethylene diamine was protected by N-tert-butoxycarbonyl.The remaining azyl group then successively reacted with methyl acrylate, ethylene diamine and methyl acrylate again to afford the compound Boc-NH 2-(B-COOCH 3) 4 3 (AB-4).The ester groups and the Boc-end group of 3 were transferred to carboxylate 4 and azyl group 5 via hydrolyzation and deprotection respectively.The fan-shape dendron molecules with 16 exterior groups 6 were obtained by condensation of 4 and 5 in the presence of DCC.The dumbbell-like dendrimer molecules 7 could expediently prepared by coupling the dendrons with two functional groups of hexanedioyl chloride.The paper describes the synthesis procedures,reports the characterization results of FTIR、 1H-NMR、 13C-NMR and MALDI-TOF.Comparing with the PAMAM dendrimers from the divergent method, the synthesized compounds possess accurate structures and few defections.
【CateGory Index】: O631
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