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《ACTA POLYMERICA SINICA》 1998-05
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SYNTHESIS AND SWELLING CHARACTERIZATIONS OF α,β- POLY DL ASPARAMIDE DERIVATIVE HYDROGEL

LIU Zhenhua, WANG Jian, FAN Changlie, ZHUO Renxi (Department of Chemistry,Wuhan University,Wuhan\ 430072)  
A biodegrable hydrogel based on α,β poly DL asparamide was synthesized by polycondensation of DL aspartic acid and 85% phosphoric acid in vacuity at 180℃,and then by ring opening reaction with 2 aminoethanol together with crosslinking reaction with 1,4 butanediamine. The swelling behavior of the gel in several solutions was investigated.The result shows that the swelling ratio of the gel in distilled water is 110~440,and it decreases differently in different concentration of electrolyte solutions.The swelling ratio in 0 16 mol/L 5 Fu solution can reach 140.Effect of molecular weight of polysuccinimide amount of solvent and crosslinking agent on the swelling behavior of the gel was also studied.
【Fund】: 国家自然科学基金
【CateGory Index】: O629.71
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