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《Polymer Materials Science & Engineering》 2006-01
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SYNTHESIS OF ORGANOSILICON MONOMER WITH HIGH SILICON CONTENT AND STUDY OF THEIR PROPERTIES OF MODIFIED ACRYLATE EMULSION

TANG Min-feng,FAN Xiao-dong,WANG Zhao-di,LIU Xiang(Department of Applied Chemistry,Science College,Northwestern Polytechnical University,Xi′an 710072,China)  
A novel reactive organosilicon monomer mathacryloxy propyl tris-(trimethlsiloxy)silane(MATS),was synthesized by substitution reaction between mathacryloxy propyl trimethloxy silane(MPS) and chlorotrimethylsilane(CMS).The structure of MATS was characterized by FT-IR and()~1H-NMR spectrum.A stable BA/MMA/MATS copolymer emulsion with high MATS content was prepared by seeded semibatch emulsion polymerization.The mechanical properties,contact angle and hydroscopicity of the films of the latexes were tested,respectively.The result indicates that the branched large group of MATS can effectively increase the content of organosilicon of the latexes prepared,decrease the surface energy of the films,provide the copolymer excellent water-resistance and mechanical strength.
【Key Words】: branched organosilicon acrylates emulsion high organosilicon content
【CateGory Index】: O627.41
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