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《Polymer Materials Science & Engineering》 2009-08
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Preparation and Properties of Amino-Terminated Hyperbranched Polymers and Its Quaternary Ammonium Salt

ZHANG Feng1,2,CHEN Yu-yue1,ZHANG De-suo1,HUA Yan-rong1,ZHAO Bing1(1.College of Material Engineering,Soochow University,Suzhou 215021,China;2.Department of Textile Engineering,Shazhou Institute of Technology,Zhangjiagang 215600,China)  
A water-soluble amino-terminated hyperbranched polymer(HBP-NH2) was synthesized from methyl acrylate and diethylene triamine by polycondensation.Then the 2-hydroxypropyltrimethylammonium chloride hyperbranched polymer(HBP-HTC) was synthesized from HBP-NH2 and 2,3-epoxypropyltrimethylammonium chloride as a grafting agent in aqueous solution.Their molecular weights and possible structure were characterized by Gel permeation chromatography(GPC),Fourier transform infrared spectrophotometry(FT-IR) and nuclear magnetic resonance spectroscopic(1H-NMR) respectively.Dissolution characteristic,antibacterial property,thermal performance and UV absorbing capability of the HBP-NH2 and HBP-HTC were also studied for their application in textile fields.Results indicate that HBP-NH2 and HBP-HTC have good antibacterial properties,good UV absorbing capability and good solubility in H2O,dimethyl surtoxide(DMSO),C2H5OH and CH3OH,etc.
【Fund】: 国家教育部“高等学校博士学科点专项科研基金”(20060285004);; 江苏省“研究生培养创新工程项目”(CX07B-151z)
【CateGory Index】: TQ316.3
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