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《Polymer Bulletin》 2011-05
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Progress of the Non-free Radical Polymerizations in the Channel of Mesoporous Molecular Sieve

ZHANG Fa-ai~1,SONG Cheng~1,YU Cai-li~2(1.College of Material Science and Engineering,2.College of Chemistry and Biochemical Engineering,Guilin University of Technology,Guilin 541004,China)  
Mesoporous materials are potentially used in catalysis,absorption and separation.Lately,researchers applied the order channel of the material as microreactor for monomer polymerization.Many polymerizations were carried out within the channel,including free radical polymerization and non-free radical polymerization.The latest 20 year's progress of the non-free radical polymerizations in the channel of mesoporous molecular sieve was reviewed.These polymerizations included the oxidative polymerization,coordination polymerization,condensation polymerization,ring-opening polymerization and ionic polymerization.Some effects on the polymerization and polymer composite were discussed.The application fields of the obtained polymer/mesoporous composites were overlooked.
【Fund】: 国家自然科学基金项目(21064002);; 新材料及其制备新技术广西区重点实验室基金项目(桂科能0842003-5A)
【CateGory Index】: O631.5
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