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《Arid Environmental Monitoring》 2001-04
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Study on Spectrophotometric Determination of Nickel(Ⅱ) with 2-(2-Quinolinylazo)-4-Diethylaminobenzoic Acid

HU Qiu fen\+1, CHEN Jiang hong\+1, YANG Guang yu\+2, TANG Dan yu\+1, YIN Jia yuan\+1(1 Department of Chemistry, Yunnan University, Kunming Yunnan 650091, China; 2.Chemical Lab, Yunnan Academy of Tabacco Science, Kunming Yunnan 650106, China)  
Quinolinylazo)-4-Diethylaminobenzoic Acid(QADEABA) has been synthesized, and its color reaction with nickel(Ⅱ) is studied. At the condition of pH=8.0 buffer solution, QADEABA can react with nickel(Ⅱ) to form a stable 2∶1 complex in the medium of Tween-80. The molar absorptivity is 1.18×10\+5 L·mol\+\{-1\}·cm\+\{-1\} at 590 nm. Beer's law is obeyed in the range of 0~0.4 mg/L. This method can be applied to the determination of nickel in water with satisfactory results.
【CateGory Index】: X830.2
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