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《Journal of Functional Materials》 2003-06
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Research to synthesis and characterization of the organic intercalated vermiculite functional material

WU Ping-xiao(Department of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, China)  
The organic-vermiculite has been obtained by modifying with hexatrimethylammonium (HDTMA). The basic characteristic of organic moiety intercalated vermiculite has been studied by XRD, DTA etc. Alkylammonium cations can enter into the vermiculite interlayer easily and form paraffin-type structure in the vermiculite interlayer. The interaction of HDTMA with vermiculite includes ion exchange and molecular adsorption. As a result of compacted arrangement of HDTMA in the interlayer, the BET specific surface area of organic-vermiculite doesn′t increase although vermiculite was expanded by HDTMA. When the HDTMA was less than the CEC of vermiculite, HDTMA enter into the vermiculite interlayer by compact array mode. And they have high stability, low de-adsorption capacity.
【Fund】: 国家自然科学基金资助项目(40202007);; 广东省自然科学基金资助项目(000623 020938)
【CateGory Index】: TB34
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