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《Journal of Functional Materials》 2005-09
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Compatibilization effect of methyl-methacrylate grafted polypropylene on mica filed polypropylene

LIN Shui-dong~1,LIN Zhi-yong~2,DING Ma-tai~(1,2),XIAO Feng-yin~2 (1.Department of Chemistry & Material Engineering,Longyan College,Longyan 364012,China;2.College Material Science & Engineering,Huaqiao University,Quanzhou 362011,China;3.College Chemistry & Chemical Engineering,Xiamen University,Xiamen 361005,China)  
The effect of methyl-methacrylate grafted polypropylene(PP-g-MMA) as an interface compatiblizer on the mechanical properties and non-isothermal crystallization of mica filled polypropylene(PP/mica),which were prepared with different grafting rate and different size of mica,was studied.The results showed that the strength properties of PP/mica improvement and the toughness properties of PP/mica decrease were due to the addition of PP-g-MMA.The strength and toughness properties of PP/mica were lightly improved with the decreas of size of mica.The analysis of DSC indicated that the heterogeneous nucleation of mica on PP was observed.The nucleating efficiency was improved and the growth of ball crystallization of polypropylene was hindered by strong bond between mica and PP due to the addition of PP-g-MMA.The size of mica and the graftage degree of PP-g-MMA ligthly influenced the rate of crystallization of polypropylene.The Avrami exponent(n) and K were about 2.50,10~(-5) s~(-n) respectively.
【Fund】: 龙岩学院自然科学研究基金资助项目(Z03102)
【CateGory Index】: TQ325.14
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