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《Journal of Functional Materials》 2006-01
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The arrangement models of organic-pillar structure in the interlayer of organic pillared hydrobiotite

WU Ping-xiao,ZHU Neng-wu,DANG Zhi,LI Rong(College of Environmental Science and Engineering,South China University of Technology,Guangzhou 510640,China)  
Hydrobiotite,a vermiculite-phlogopite interstratified mineral,is intercalated by octadecyltrimethylammonium bromide(C_(18)TAB);the complexes were tested by X-ray diffraction(XRD).In order to investigate the evolvement of arrangement models of organic ion group in vermiculite interlayer and phlogopite interlayer of hydrobiotite,the quantity of C_(18)TAB was increased step by step.The results showed there are two arrangement models,paraffintype monolayer(PM) and paraffin-type bilayer(PB),in different concentration,as the organic stow density of vermiculite interlayer increased;and that in phlogopite interlayer there is only one arrangement model,paraffin-type bilayer;the evolvement of space arrangement models is as follows:PM in vermiculite interlayerPB in vermiculite interlayerPB in vermiculite and phlogopite interlayer;at last in the two interlayers of hydrobiotite C_(18)TAB has the same arrangement model.
【Fund】: 国家自然科学基金资助项目(40202007);; 广东省自然科学基金资助项目(020938 04020017)
【CateGory Index】: TB34
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