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《Journal of Functional Materials》 2010-12
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Adsorption of sulfur-containing compounds on CuCl/SBA-15 molecular sieve prepared by the thermal diffusion method

SHAN Jia-hui1,LIU Xiao-qin2(1.School of Chemistry and Chemical Engineering,Nantong University,Nantong 226019,China;2.State Key Laboratory of Materials-oriented Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China)  
The adsorbent CuCl/SBA-15 was prepared with the thermal diffusion method,the dispersions of CuCl on SBA-15 were studied by XRD,and adsorptive performance of the adsorbents for thiophene was investigated via static adsorption experiments.The effects of CeO2 added into the adsorbent and toluene content in model fuel on thiophene removal were also studied.The results showed that:CuCl dispersed uniformly on SBA-15 surface when CuCl loading was lower than the threshold,0.3502g CuCl/g SBA-15 measured by XRD method.When the CuCl loading amount was 0.33g CuCl/g SBA-15,the adsorbent had the best desulfurization performance and it's adsorption capacity was high to 0.8767mmol/g,indicating the threshold effect.With the addition of CeO2,the adsorption capacity improved 7.3%,and the best quality ratio was m(Ce)/m(Cu)=0.3.There was dramatic decrease in the capacity on CuCl/SBA-15 for thiophene removal in model fuel with a small toluene content,but toluene had a less effect on thiophene adsorption over CuCl/SBA-15 with CeO2.
【Fund】: 国家自然科学基金资助项目(20976082);; 南通大学自然科学基金资助项目(09Z009)
【CateGory Index】: TE624.55
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Chinese Journal Full-text Database 3 Hits
1 JIANG De\|En, ZHAO Bi\|Ying\+*, XIE You\|Chang (Institute of Physical Chemistry, Peking University, Beijing 100871, China);Studies on the Adsorption Performance of K_2CO_3/γ-Al_2O_3 to SO_2[J];Chemical Research In Chinese Universities;2001-10
2 ZHANG Wei1,2,XU Hengyong2,BI Yadong 2,LI Wenzhao2(1 Department of Chemistry,Harbin Normal University,Harbin 150025,Heilongjiang,China;2 Laboratory of Applied Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,Liaoning,China);Recent progress of modification of mesoporous silica SBA-15[J];Chemical Industry and Engineering Progress;2007-02
3 Deng Cun(Department of Chemistry,Ningde Teachers College,Ningde 352100);Monolayer Dispersion Thresholds and Threshold Effect Displayed by Supported Catalysts[J];Chemistry;2007-12
Chinese Journal Full-text Database 10 Hits
1 An Jun, Wu Haixia, Xin Yinchang (College of Chemical Engineering and Material Scince, Shandong Normal University, Jinan 250014, China);PREPARATION AND RESEARCH OF RESIN/NANO-LEAD COMPOSITE FOR HIGH-ENERGY RADIATION PROTECTION[J];Engineering Plastics Application;2004-12
2 XIE Youchang\ TANG Youqi (College of Chemistry and Molecular Engineering,Peking University,Beijing,100871);Spontaneous Dispersion of Oxides and Salts to Zeolites and Its Applications[J];ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS;1998-Z1
3 Song Chang you 1 Wu Nian zu 2 Wang Ping 1 (1 College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029; 2 College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China);The monoplayer dispersion capacity of Sr~(2+) on the surface of nanometer-size TiO_2[J];Journal of Beijing University of Chemical Technology;2004-04
4 Zhu Teng;Rong Bin(Department of Chemistry,USTB,Beijing 100083.PRC);Polarographic Behaviour of Rhodamine 6G Ⅱ Adsorptive Complex Wave of Antimony(Ⅲ)[J];JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING;1995-05
5 LI Song-bo,CAI Ying (Chemistry and Chemical Engineering School,UST Inner Mongolia,Baotou 014010,China);New method for assembling magnetic materials Fe_3O_4 into zeolites molecular sieves ZSM-5 and their magnetism[J];Journal of Baotou University of Iron and Steel Technology;2004-04
6 XU Yongqiang, ZHAO Ruiyu, SHANG Hongyan, ZHAO Huiji, LIU Chenguang *(Key Laboratory of Catalysis, CNPC, College of Chemistry & Chemical Engineering, University of Petroleum (East China), Dongying 257061, Shandong, China);Dispersion and Adsorption of Dibenzothiophene on the Surface of CoMo/γ-Al_2O_3 Catalyst[J];Chinese Journal of Catalysis;2003-04
7 WANG Chunming, ZHAO Biying *, XIE Youchang(State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China);Advances in the Studies of Spontaneous Monolayer Dispersion of Oxides and Salts on Supports[J];Chinese Journal of Catalysis;2003-06
8 XU Ping1, XU Yunpeng1, TENG Fei1, HU Sheng2, TAN Mingwei2, XU Zhusheng 1, TIAN Zhijian 1* ( 1 Laboratory of Natural Gas Utilization and Applied Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2 Research Ins titute of Daqing Petrochemical Company, Daqing 163714, Heilongjiang , China);Preparation of Pd/WO_3-ZrO_2 Solid Superacid Catalyst and Its Catalytic Performance for n-Heptane Hydroisomerization[J];Chinese Journal of Catalysis;2005-09
9 Guoxingbatu (Department of Chemistry, Inner Mongolia Normal University, Huhehaote 010022) Xiao Fengshou, Xu Ruren (Department of Chemistry, Jilin University, Changchun 130023);STUDIES ON DISPERSION OF MoO_3 ON ZSM 5 ZEOLITE BY HYDROTHERMAL METHOD[J];CHINESE JOURNAL OF CATALYSIS;1998-03
10 Shi Keying, Hou Shoufu, Zhang Xiuzhong, Shang Yongchen,Wei Shuquan, Wei Yongde, Xu Guolin, Xu Hengyong (Department of Chemistry, Harbin Normal University, Harbin 150080);STUDIES OF REGENERATION OF DEACTIVATED CN 16 CATALYST FOR CH 4 CO 2 O 2 REACTION[J];CHINESE JOURNAL OF CATALYSIS;1998-06
China Proceedings of conference Full-text Database 1 Hits
1 Yu Qingchun , Zhang Shichao, Wang Xindong (School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China; School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, China);Determination of Dispersion Threshold of CeO_2 on γ-Al_2O_3 Using Matrix-Flushing Method[A];[C];2006
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 YAN Hongjie, YANG Junying, LIU Heping, REN Feng (Department of Chemistry)WANG Peiying (Department of Geology);A Study on the Forms of Alkali Halides Supported on γ-Al_2O_3[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1989-06
2 Zhao Biying, Zhang yufen, Duan Lianyun, Xie Youchang and Tang Youqi(Institute of Physical Chemistry, Beijing Unioersity);STUDY OF THE ADSORPTION CHARACTERISTICS OF ETHYLENE ON CuO/γA1_2O_3[J];Chinese Journal of Catalysis;1982-02
3 Lia Yingjun, Xie Youchang, Ming Jing, Liu Jun and Tang Youqi(Institute of Physical Chemistry,Beijing University);DETERMINATION OF THE MAXIMUM MONOLAYER DISPERSION OF MoO_3 ON γ-Al_2O_3 BY X-RAY DIFFRACTION[J];Chinese Journal of Catalysis;1982-04
4 Liu Ying-Jun, Xie You-chang, Li Ce, Zou Zhi-yang and Tang You-qi (Institute of Physical Chemistry, Beijing University);MONOLAYER DISPERSION OF MoO_3 ON γ-Al_2O_3 FROM DIFFERENT SOURCES[J];Chinese Journal of Catalysis;1984-03
5 Zhao Bi-ying, Kang Zhi-jun Li Chao(Institute of Physical Chemistry, Beijing University);MEASUREMENT OF THE SURFACE ACIDITY ON SOLIDS BASED ON THE ADSORPTION ISOTHERMS OF n-BUTYLAMINE IN SOLUTION[J];Chinese Journal of Catalysis;1985-01
6 Liu Ying-jun, Xie You-chang, Xie Gang and Tang You-qi (Institute of Physical Chemistry, Beijing University);STUDIES OF THE INTERACTION BETWEEN MoO_3 AND VARIOUS CARRIERS AND DETERMINATION OF THE MONOLAYER DISPERSION CAPACITIES OF MoO_3[J];Chinese Journal of Catalysis;1985-02
7 Zhao Bi-ying, Kang Zhi-jun, Li Chao, Xie You-chang and Tang You-qi (Institute of Physical Chemistry, Beijing University);STUDY OF THE SURFACE ACIDITY OF SYSTEMS MoO_3/Υ-Al_2O_3 AND MoO_3/SiO_2[J];Chinese Journal of Catalysis;1985-03
8 Chen Shu,(Beijing Institute of Chemical Fibre Technology)Li Guo-ying, (Department of Chemistry, Beijing University)Wang Yu-qing and Yu Bo-ling (Beijing Institute of Chemical Fibre Technology);RELATION BETWEEN THE ACTIVITY AND STRUCTURE OF ZINC ACETATE/ACTIVATED CARBON CATALYST[J];Chinese Journal of Catalysis;1986-02
9 Liu Ying-jun, Wu Jiang-ping, Guo Qin-lin, Gui Lin-lin and Tang You-qi (Institute of Physical Chemistry, Beijing University);XRD AND XPS STUDIES OF WO3 ON SILICA[J];Chinese Journal of Catalysis;1987-01
10 Huang Hui-zhong, Zhao Bi-ying, Guo Qin-lin,Gui Lin-lin and Tang You-qi (Institute of Physical Chemistry, Beijing University);APPLICATION OF SSIMS TO DETERMINE THE SURFACE STRUCTURE OF MoO_3-NiO-P_2O_5/τ-Al_2O_3 CATALYSTS[J];Chinese Journal of Catalysis;1987-02
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