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《Journal of Functional Polymers》 2005-02
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Photochromism of the Modified Hyperbranched Poly(amide-ester)

DING Hai-tao, BA Xin-wu, WANG Su-juan, ZHANG Shu-wen (College of Chemistry and Environment Science of Hebei University, Baoding 071002, China)  
The hyperbranched poly(amide ester) was synthesized based on AB_3 type monomer prepared by the reaction of succinic anhydride and tri(hydroxymethyl)-aminomethane in a ice bath.The hyperbranched poly(amide-ester)s were modified by 4-(4′-dimethylaminophenylazo)benzoic acid (DABCYL), which had photochromism and acid-base discoloration. The photochromism were examined by UV and reveal substitutional effect of the functional group, which had photochromism and acids-bases discoloration, on the hyperbranched poly(amide-ester). The results showed that the absorption intensity for ultraviolet light increased as the irradiating time increased and the blue shift of the UV spectra occurred as pH increased.
【Fund】: 国家自然科学基金(20174008);; 河北省自然科学基金(B2004000093)。
【CateGory Index】: O631.3
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