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《Bulletin of the Chinese Ceramic Society》 2007-05
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Synthesis and Pore Structural Characterization of Mesoporous Molecular Sieves SAN-01

WU Xiu-wen1,2,MA Hong-wen1,2,ZHENG Zhi-yuan1,LI Zhi-hong3,ZHANG Lin-tao1,2(1.National Laboratory of Mineral Materials,China University of Geosciences,Beijing 100083,China;2.School of Materials Science and Technology,China University of Geosciences,Beijing 100083,China;3.Beijing Synchrotron Radiation Laboratory,Institute of High Energy Physics,Chinese Academy of Science,Beijing 100049,China)  
Mesoporous molecular sieves,named SAN-01,were hydrothermally synthesized with microcline,a natural ore,as starting material,and the seeds of 13X zeolite as pore-wall's crystal source.During the process,the mixture of microcline and Na2CO3 with a molar ratio of 1:1.05 was first calcined at 820℃ for 2h;the calcined materials were then dissolved in 0.01mol/L NaOH aqueous solution and aged for 24h at room temperature;the as-prepared Si,Al sources and 50mL cetyltrimethylammonium bromide(C16TMABr) aqueous solution(containing 7.4g C16TMABr) were mixed,crystallized at 105℃ for 48h,centrifuged and washed 3 times with water.The powder was calcined at 550℃ for 10h,resulting in mesoporous molecular sieves.When pores in SAN-01 were supposed to be spheroid,the mean pore-wall distance of SAN-01 calculated by SAXS(small-angle X-ray scattering) is about 5.42nm;which is bigger than that determined by XRD about 8.8%.The pore-wall distance distribution determined by SAXS(0.2-11.3nm) is wider than that by N2 adsorption and XRD(3.8-5.6nm).The difference above mentioned maybe caused by closed porous structure,or the force between N2 molecules and OH-groups on the pore-surface.SAXS can also be used to characterize the pore structure of samples with template,but N2 adsorption cannot be used to do so.
【Fund】: 中国地质大学矿物材料国家专业实验室开放基金资助(06006)
【CateGory Index】: TB383.4
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