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《Bulletin of the Chinese Ceramic Society》 2011-01
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Synthesis of Trioctyl Citrate Catalyzed by SO_4~(2-)/Fe-MMT Solid Super Acid

CHANG Yue1,2,REN Xiao-ning1,ZHA Fei1,2,WANG Yong-gang1,LIU Hong-wei1,CHEN Hu-kui1 (1.College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou 730070,China;2.Key Laboratory of Eco-Environment-Related Polymer Materials Ministry of Education,Lanzhou 730070,China)  
An iron pillared montmorillonite(MMT) is prepared by ion exchange,and is modified by H2SO4 to achieve the SO2-4/Fe-MMT solid super acid.It is characterized by IR and XRD.Trioctyl citrate is synthesized using SO2-4/Fe-MMT as catalyst.The results indicate that temperature of the reaction is 160 ℃,the molar ratio of citrate acid to octanol is 1∶ 4,the weight of catalyst is 15% of citrate acid and the reaction time is 4 h,the yield of trioctyl citrate has reached 97.0%.
【Fund】: 2007中科院“西部之光”人才培养计划地方项目;; 2008甘肃省自然基金项目(0803RJZA007)
【CateGory Index】: TQ414
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