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《Spectroscopy and Spectral Analysis》 2004-09
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Biosynthesis and Characterization of Jarosite

ZHOU Shun-gui 1, ZHOU Li-xiang 1, WONG Jonathan W. C. 2 1. College of Resources and Environmental Sciences, Nanjing Agricultural University, Nanjing 210095, China 2. Department of Biology, Hong Kong Baptist University, Hong Kong, China  
A yellow ochre-colored jarosite was synthesized by bacterial oxidation of ferrous ion by Thiobacillus ferrooxidans at 28 ℃ and 1 atm. The identification of the bacterially oxidized ion precipitate was carried by SEM, XRD, FTIR and chemical analysis. Results showed that resting T. ferrooxidans cells could completely oxidize ferrous ions to ferric ions in FeSO 4-K 2SO 4-H 2O system at pH 2.5. In the presence of suitable monovalent K + and excess sulfate, the yellow precipitate was produced from bacterially oxidized iron solutions. The subsequent characterization showed that it was high-quality jarosite without by-product such as amorphous ferric hydroxysulfates.
【Fund】: 国家自然科学基金 (2 0 1 770 1 6);; 国际科学基金 (IFS C/ 2 669 2 );; 江苏省自然科学基金 (BK2 0 0 1 0 72 )资助项目
【CateGory Index】: TQ622
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