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《Spectroscopy and Spectral Analysis》 2004-12
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Absorption Spectra Study of Cation Surfactant-[AuI_4]~- Association Particle System and Its Analytical Application

LUO Yang-he, JIANG Zhi-liang * Department of Resource and Environmental Science, Guangxi Normal University, Guilin 541004  
In 0.01 mol·L -1 HCl medium, there is an absorption peak at 350 nm for [AuI 4] -. The association particle system of CTMAB-[AuI 4] - exhibits violet-red color. It has a new absorption peak at 520 nm. The CTMAB concentration c CTMAB in the range of 0-7.0×10 -5mol·L -1 is linear to the A 520 nm value. Its regression equation is A 520 nm=0.989×10 4c CTMAB+0.013 8, regression coefficient is 0.999 5, and the mole absorption coefficient is 1.059×10 4 L·mol -1·cm -1. A new spectrophotometry has been proposed for the determination of cation surfactant. The resonance scattering spectra show that the CTMAB + and [AuI 4] - combine to form(AuI 4-CTMAB) association molecule with hydrophobicity by means of attraction forces. The association molecules automatically aggregate to form(AuI 4-CTMAB) n association particles. So, the particles exhibit two resonance scattering peaks at 580 and 470 nm, and the system exhibits violet-red.
【Fund】: 广西自然科学基金 (0 1 4 4 0 3)资助项目
【CateGory Index】: O657.3
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