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《Journal of Chemical Engineering of Chinese Universities》 2001-01
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Study on Adsorption Properties to Metal Ion and Physical Properties of Bead Ni~(2+ )Templated Chitosan Chelated Resins

HE Xiao-jin1, ZHANG Bing-ling2, TAN Tian-wei1, DU Wei-xia1 (1. College of Chemical Engineering Biochemical Engineering Department, Beijing University of Chemical Engineering, Beijing 100029, China; 2. Education and Train Center Beijing Yanshan Petroc  
Preparation of Ni2+ template chitosan beads using a nozzle was investigated. Epichlorohydrin and ethylene glycol diglycidyl ether(EGDE) were used to cross link the resin to enhance rigidity of resin. This resin has high mechanical strength, low pressure drop in packing column and good reusability. After reused 10 times, the adsorption capacities were still big enough. It could adsorb Ni2+, Cu2+, Zn2+selectively. At the same condition, the adsorption capacities of bead Ni2+ template chitosan resins to Ni2+, Cu2+,Zn2+ were two times as those of general bead chitosan resins, but no difference for Cr6+. The adsorption equilibrium isotherm of Ni2+ for the Ni2+ template chitosan resin was determined and the influences of pH, particle pores dimension, Ni2+concentration of template resin and kind of cross-linking agents on adsorption capacities of Ni2+ were also discussed. The adsorption isothems of this resin for Ni2+ could be correlated by the Freundlich equation, but not by the Langmuir equation.
【Fund】: 本课题为国家“95”攻关项目!(96-A12-08-01-04)
【CateGory Index】: O647
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