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《Journal of Chemical Engineering of Chinese Universities》 2003-03
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Kinetics of Cottonseed Oil Transesterification in a Batch Reactor

WU Guo-ying, LIN Xi-ping, WU Miao-xin, WANG Lin, ZHOU Ya-jun (Jiangsu Key Lab of Finechemical Technology,Jiangsu Polytechnic University, Changzhou 213016, China)  
Methyl esters were produced by transesterification of cottonseed oil with methanol in the present of catalyst (KOH). The kinetics of transesterification was studied at various reaction times, temperature and catalyst concentrations. Samples were withdrawn quickly from the reactor with a pasteur pipet. The composition of the methyl esters was analyzed by gas chromatograph. The experimental data appear to be described by pseudo second-order model for the initial stages of the reaction and followed by first-order and zero-order-model, similar to those reported by Darnoko D and et al.[5] Reaction rate constants for transesterification of cottonseed oil are 0.9179~1.049Lmol-1min-1.and activation energy of transesterification is 10.88kJmol-1.
【Fund】: 中石化集团总公司资助课题(102019;2002)。
【CateGory Index】: TE665
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