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《Journal of Chemical Engineering of Chinese Universities》 2012-04
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Study on the Kinetics of L-Tryptophan Adsorption by Ion Exchange Resin

XIE You-ping,JING Ke-ju,YAO Chuan-yi,LU Ying-hua(Department of Chemical and Biochemical Engineering,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China)  
The isothermal adsorption and adsorption kinetics of L-tryptophan by 001×7 cation-exchange resin were studied by static experiments.The Moving Boundary Model was applied to describe the kinetics of the ion exchange process.The effects of experimental conditions including the concentration of L-tryptophan,resin particle diameter and adsorption temperature on the ion exchange process were investigated.The results show that the maximum L-tryptophan adsorption capacity of 001×7 cation-exchange resin increases with decreasing solution pH.It was found that the Langmuir equation fits the adsorption isotherm data best,and the particle diffusion is the rate-limiting step of the adsorption process.The adsorption ratio increases with the increase of L-tryptophan concentration and adsorption temperature,but decreases with the increase of the resin particle diameter.The rate constant of exchange(k0),reaction order() and the apparent activation energy of reaction(Ea) were obtained as follows: k0=1.199×10 5,Ea=19.94 kJ mol 1,and the kinetics equation was obtained too.
【Fund】: 国家自然科学基金(3107488);; 福建省自然科学基金(2011J01058);; 中央高校基本科研专项基金(2011121017)
【CateGory Index】: O647.31
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【References】
Chinese Journal Full-text Database 1 Hits
1 LEI Wen;WEI Rong-qing;LIU Xiao-ning;GU Ai-xi;WU Hao;JIANG Min;College of Biotechnology and Pharmaceutical Engineering,Nanjing University of Technology;;Static Adsorption of Succinic Acid with Comb Weakly Basic Resin (MKF-D30X)[J];Journal of Chemical Engineering of Chinese Universities;2013-05
【Citations】
Chinese Journal Full-text Database 9 Hits
1 WU Cai-lian,GUO Chang-jiang,YANG ji-jun,WEI jing-yu,XU Qi-shou(Institute of Hygiene and Environmental Medicine,Academy of Military Medical Science,Tianjin 300050,China);Separaton and Purification of L-Tryptophan from Fermentation Liquor[J];Amino Acids & Biotic Resources;2007-03
2 WEN Yan-xuan; WANG Li-sheng; JIN Zuo-mei; ZHOU Hui-nan(College of Chemical Engineering, Sichuan University, Chengdu 610065, China);Ion Exchange Kinetics of Removing Mg~(2+) from Demagging Waste Liquor of Phosphate Ore[J];JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES;1999-06
3 LI Changhai,SHI Hongren and TANG Hongyu (Department of Chemical Engineering, Changchun University of Technology, Changchun 130012, Jilin,China);ADSORPTION SEPARATION OF β -NAPHTHALENESULPHONIC ACID WASTEWATER ON WEAKLY BASIC RESIN AND THERMODYNAMICS[J];Journal of Chemical Industry and Engineering(China);2004-07
4 ZHANG Deqiang1,2 KANG Haiyan2 YANG Lili3 LI Na2 1 Hebei Academy of Sciences, Shijiazhuang 050081, China 2 College of Chemistry & Environmental Science, Hebei University, Baoding 071002, China 3 College of Chemistry, Hebei Normal University, Shijiazhuang 050016, China;STUDY ON THE KINETICS OF ADSORPTION OF CADMIUM BY ION-EXCHANGE RESIN[J];Ion Exchange and Adsorption;2004-02
5 WANG Yongli1 MA Xiaojian1 CHANG Chun1,2 1. School of Chemical Engineering and Technology Zhengzhou University, Zhengzhou 450002, China 2. College of Material Science and Chemical Engineering Zhejiang University, Hangzhou 310027, China;STUDY ON THE KINETICS OF ADSORPTION OF LEVULINIC ACID BY ION-EXCHANGE RESIN[J];Ion Exchange and Adsorption;2007-04
6 ZHANG Xing RUAN Qi YE Changshen College of Chemical and Engineering,Fuzhou University,Fuzhou 350002,China;STUDY ON ADSORPTION PROPERTIES OF THE MACROPOROUS WEAKLY-ACID RESIN FOR SISOMICIN[J];Ion Exchange and Adsorption;2007-05
7 Wang Jian Chen Ning Xu Yongquan Yang Haijun Zhang Kexu (College of Food Science and Bioengineering, Tianjin University of Science and Technology, Tianjin,300222);Quick Determination of L-Tryptophan in Fermented Broth[J];Food and Fermentation Industries;2004-02
8 Chen Tao, Chen Ning (Tianjin Institute of Lignt Industry, Tianjin 300222);The production of L-tryptophan and breeding of tryptophan-producting strains by metabolic control[J];Letters in Biotechnology;2000-02
9 HOU Jing-Wei, MA You-Guang* (Chemical Engineering Research Center,Tianjin University,Tianjin 300072) GAO Xi-Qun (Liaoyang Petro-chemical Fibre Co. Yinghua Economy and Development Co. ,Liaoyang);Factors Influencing the Extraction of Tryptophane by Tri-n-octylmethylammonium Chloride[J];Chinese Journal of Applied Chemistry;2003-07
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Zuo Zuzhen1 et al. (College of life science,Fujian Normal University,Fuzhou 350108,China);Progress of study on L-tryptophan[J];Anhui Agricultural Science Bulletin;2010-07
2 WANG Jian, CHEN Ning, TAN Qing-qiao, ZHANG Ke-xu (College of Food Science and Bioengineering, Tianjin University of Science and Technology, Tianjin 300222, China);Study on Breeding of L-tryptophan-producing Strain and Its Fermentation Conditions[J];Amino Acids & Biotic Resources;2003-03
3 CHEN Ben,XU Jianmiao,ZHENG Yuguo(College of Biological and Environmental Engineering, Zhejiang University of Technology,Hangzhou 310014,Zhejiang,China);Determination of Tryptophan and Tryptophanamide in Biocatalysis Process[J];Amino Acids & Biotic Resources;2012-01
4 ZONG Gang 1.2,JIN Qi-ting1,QING Chun-xia2,ZHANG Jian-min2 (1.College of Environmental and Municipal Engineering, Xi'an University of Architecture & Technology, Xi'an 710055, China; 2.College of Environmental and Chemical Engineering, Xi'an University of Engineering Science & Technology, Xi'an 710048, China).;Extraction of Nickel Citrate in Wastewater of Electroless Nickel Plating by Tri-n-Octylmethylammonium Chloride[J];Materials Protection;2006-01
5 HOU You song,ZHOU Guang qi,YU Ling,WANG Hong hua,WANG Shi long (Dept.of Food Sci.and Biotechnol., Dalian Inst.of Light Ind., Dilian 116001, China);Deep fermentation of Cordyceps militaris in wort medium[J];Journal of Dalian Institute of Light Inoustry;2000-04
6 SU Hui-dong,HUANG Wei-hua*(School of Environmental and Chemical Engineering,Shenyang University of Technology,Shenyang 110168,China);Kinetics and Thermodynamics of Sorption of Ni~(2+) Macroporous Adsorption Resin D113[J];Environmental Science & Technology;2009-10
7 ZHENG Hong1,WANG Zhong-lai1,CHEN Xian2(1. College of Biological Science and Technology,Fuzhou University,Fuzhou,Fujian 350108,China;2. Zhicheng College,Fuzhou University,Fuzhou,Fujian 350002,China);Adsorption equilibrium of L-tryptophan and L-phenylalanine on 732 cation-exchange resins in a constant-temperature bath[J];Journal of Fuzhou University(Natural Science Edition);2010-01
8 XU Wan-zhen,YAN Yong-sheng,YANG Mo-hui,JING Jun-jie College of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013,China;Study on the Adsorption Behavior of Nickel on Potassium Tetratitanate Whisker by Flame Atomic Absorption Spectrometry[J];Spectroscopy and Spectral Analysis;2009-06
9 JIN Zhao-hui, ZHANG Feng-bao, ZHANG Guo-liang (School of Chemical Engineering, Tianjin University, Tianjin 300072, China);Determining the Dissociation Degree of Counter Ions in Ion-exchange Resin by Conductivity Measurement[J];Journal of Chemical Engineering of Chinese Universities;2004-06
10 ZHANG Yang,WANG Li-sheng,ZHOU Yong-hong,LIU Xiong-min(School of Chemistry & Chemical Engineering,Guangxi University,Nanning 530004,China);Adsorption Kinetics of Dihydrocapsaicin on Ion Exchange Fiber[J];Journal of Chemical Engineering of Chinese Universities;2011-02
【Co-references】
Chinese Journal Full-text Database 6 Hits
1 QU Weiguang, WEI Rongqing, HE Bingfang, LIU Xiaoning*, ZHONG Yu, CHEN Xinying College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China;Flexible Immobilization of Lipase on Hydrophilic and Comblike Polymer Support Containing Epoxy Group[J];Chinese Journal of Catalysis;2011-12
2 CHEN Xin-ying,WEI Rong-qing,HE Bing-fang,LIU Xiao-ning,JI Jie,XU Yan-hua(Biotechnology and Pharmaceutical Engineering,Nanjing University of Technology,Nanjing 210009,China);Immobilization of Pseudomonas stutzeri LC2-8 Lipase by a Comblike and Hydrophilic Support with Epoxy Groups[J];Journal of Chemical Engineering of Chinese Universities;2012-04
3 WEI Rong-qing,WANG Jin,FANG Shuo,LIU Xiao-ning*(Center of Chromatography,College of Biology and Pharmaceutical Engineering, Nanjing University of Industry,Nanjing 210009,China);Application of Chromatographic Column Packed with Copolymer to Separation and Determination of Organic Acids by HPLC[J];Physical Testing and Chemical Analysis(Part B:Chemical Analysis);2012-02
4 LI Jieying CHEN Jinlong FEI Zhenghao LU Zhaoyang LI Aimin LIU Fuqiang ZHANG Quanxing State Key Laboratory of Pollution Control and Resources Reuse, Department of Environmental Engineering, Nanjing University, Nanjing 210093, China;ADSORPTION OF O-CRESOL ON MACROPOROUS ADSORBENTS[J];Ion Exchange and Adsorption;2004-05
5 WANG Yongli1 MA Xiaojian1 CHANG Chun1,2 1. School of Chemical Engineering and Technology Zhengzhou University, Zhengzhou 450002, China 2. College of Material Science and Chemical Engineering Zhejiang University, Hangzhou 310027, China;STUDY ON THE KINETICS OF ADSORPTION OF LEVULINIC ACID BY ION-EXCHANGE RESIN[J];Ion Exchange and Adsorption;2007-04
6 Li Song,Yao Zhong,Liu Hui,Wu Hao,Jiang Min(College of life Science And Pharmaceutical Engineering, Nanjing University of Technology, Nanjing 210009, China);Selective Separation of Succinic Acid by Basic Resin[J];Food and Fermentation Industries;2007-07
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 WEN Yan-xuan; WANG Li-sheng; JIN Zuo-mei; ZHOU Hui-nan(College of Chemical Engineering, Sichuan University, Chengdu 610065, China);Ion Exchange Kinetics of Removing Mg~(2+) from Demagging Waste Liquor of Phosphate Ore[J];JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES;1999-06
2 Wang Renyuan and Shi Jun(Department of Chemical Engineering, Nanjing University of Chemical Technology, Nanjing 210009);INTERPRETATION AND PREDICTION OF THE NONIDEAL BEHAVIORS OF ELECTROLYTE SOLUTIONS[J];Journal of Chemical Industry and Engineering(China);1997-02
3 SONG YINJIE;ZHAO AIMIN(Department of Modern Physics, Lanzhou University,730000);A COMPARATIVE STUDY ON KINETICS OF ION EXCHANGE IN BINARY SYSTEM FITTED BY THREE MODELS[J];JOURNAL OF NUCLEAR AND RADIOCHEMISTRY;1994-03
4 XING ZHENG CHEN XING-QU TAO ZU-YI(Department of Modern Physics, Lanzhou University);KINETICS OF SHELL-PROGRESSIVE REACTION IN ION EXCHANGE RESIN Ⅰ. ION EXCHANGE REACTION IN FINITE SOLUTION VOLUME[J];Acta Chimica Sinica;1983-11
5 Li Changhai,Shi Pengfei (Department of Applied Chemistry,Harbin Institute of Technology,Harbin 150001);Treatment of β-Naphthalenesulfonic Acid Waste Water by the Weakly Basic Resin[J];Chemical Engineering(China);2001-06
6 Tao Zuyi (Department of Modern Physics, Lanzhou University);Four Ordinary Models and Rate Laws for Ion Exchange Kinetics[J];Ion Exchange and Adsorption;1990-03
7 Zhang Xinshen(Ion Chromatographic Laboratory, Leather Dept., Sichuan Union University, 610065);DYNAMIC RESEARCH ON LOW PRESSURE ION CHROMATOGRAPHY[J];ION EXCHANGE AND ADSORPTION;1996-03
8 Gao Jingzhi\ Fang Hua(Department of Chemistry,Capital Normal University);Spectrophotometric Determination of L Tryptophan by Condensation with p Dimethylaminobenzaldehyde[J];JOURNAL OF CAPITAL NORMAL UNIVERSITY(NATURAL SCIENCE EDITION);1999-03
9 liu Zhirong\ Guo Jinyong\ Zhou Xiangyou (Beijing Research Institute of Chemical Engineering and Metallurgy,CNNC);Kinetics of Adsorption of Platinum with P951 Resin[J];SHANDONG METALLURGY;1997-02
10 Zhang Weimin Shen Ming Yan Chunhong Tong Xuanxia (Institute of Zhuzhau Pharmaceutical Factory, Hunan 412000)Ding JiuyuanGong dianhua (Institute of Microbiology, Academta Sinica, Beijing 100080);EXTRACTION OF L-ARGININE FROM FERMENTATION BROTH BY ION-EXCHANGE PROCESS[J];Microbiology;1992-05
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