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Measurement of Vapor-Liquid Equilibrium Data for Products in Methanol Amination

Xu Xien; An Lihua;Zheng Guowen(Dept.of Chem. Eng.,Tianjin University,Tianjin) Bai Genxing(Beijing institute of Chem. Technol.,Beijing)  
In this article,T, P and total composition data of 9 binaries for the products in the methanol amination with ammonia, which includes NH_3-methanol (MeOH),NH_3dimethylamine (DMA),NH_3-monomethylamine (MMA), NH_3-H_2O,DMA-MeOH, DMA-H_2O, MMA-MeOH,MMA-H_2O and MMA-trimethylamine (TMA),were measured over a temperature range of 20-120℃. The molar fractions for each component were calculated by using indirect method and parameters of Wilson equaiton were correlated as a function of temperature.The maximum relative error was 1.7% according to the accuracies of instruments used.
【CateGory Index】: O623.731
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