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《Journal of The Chinese Ceramic Society》 1990-04
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STUDY ON COLOURING AND FADING MECHANISM OF ZnWO_4 CRYSTAL

Xu Yuheng Xu Chongquan Long Xinbin Zhao Yequan Li Minghuo(Applied Chemistry Department, Harbin Institute of Technology)Zhu Guoyi He Yingtang Gu Yipan Qian Zhongmin(Institute of High Energy physics, Academia Sinica)  
The undoped ZnWO_4 with different purity of raw materials and the ZnWO_4 crystal doped with Sb_2O_3, CeO_2, Ag_2O etc. are griven. High temperature annealing of the crystal in oxygen, testing of crystal properties before and after annealing and study of colouring and fading mechanism of ZnWO_4 crystal are carried out.It is pointed out that the colour of ZnWO_4 crystal is caused by a colourcenter-complex "Fe~(2+)+[O~(2-)]+electron"
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