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Li Wenjun Shi Erwei Zheng Yanqing Xia Changtai Yin Zhiwen (State Key Laboratory on High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics,Chinese Academy of Sciences)  
The pure BaTiO 3 powder was prepared using Ba(OH) 2·8H 2O and TiO 2 as precursor under hydrothermal condition. It is found that the phase of obtained product is related to the reaction temperature and the molar ratio of Ba 2+ and Ti 4+ . The formation mechanism of BaTiO 3 powder is studied by growth unit model of anion ion coordinated polyhedra. It is pointed out that the growth units of BaTiO 3 crystal are Ba(OH) 10- 12 and Ti(OH) 2- 6. Moreover, the effect of the reaction temperature or the molar ratio of Ba 2+ and Ti 4+ on phase is explained reasonably.
【CateGory Index】: TQ134.1
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