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《Journal of the Chinese Ceramic Society》 2007-01
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PREPARATION OF GLASS-CERAMICS BY SLAG OF IRON MELT-REDUCTION FROM LOW GRADE IRON ORE

LI Keqing,XU Yong,NI Wen,YUAN Huaiyu (State Key Laboratory for High-Efficient Mining and Safety of Metal Mines of Ministry of Education, University of Science and Technology Beijing, Beijing 100083, China)  
The feasibility of iron-smelting and making glass-ceramics using low grade iron ore from Sijiaying Iron Mine in Hebei province by the melt-reduction method and casting technology was investigated, and pig iron used in steel-making and glass-ceramics for building decoration were prepared. By using orthogonal design method, the slag-iron separation and crystallization of the slag were studied at different ratios of raw materials, and the optimum composition ratio of raw materials which could be used in industrial test was determined: 62%(in mass, same below) iron ore, 5% alumina powder, 15% quicklime, 3.3% fluor, 8.4% dietary alkali and 6.2% coke. The phase compositions and characteristics of glass-ceramics products were determined by the comprehensive methods such as optical microscopy, X-ray diffraction, physical and chemical properties test. The test results show that the prepared glass-ceramics consist of matrix glass and wollastonite crystals and it has a compressive strength of 827 MPa, a mohs hardness of 6 degree, a volume density of 2.69 g/cm3, a water absorption of 0.016%, a acid resistance of 0.08%, a alkali resistance of 0.05%.
【Fund】: “十五”国家科技攻关计划(2004BA615A0508)资助项目
【CateGory Index】: TF557
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