Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of the Chinese Ceramic Society》 2014-07
Add to Favorite Get Latest Update

Fabrication of Hollow Silica Microsphere Using Zinc Oxide as Template and Its Effect on Polyacrylate Film Properties

BAO Yan;YANG Yongqiang;MA Jianzhong;LIU Junli;College of Resources and Environment,Shaanxi University of Science and Technology;  
Mono-dispersed zinc oxide/silica core/shell microsphere was prepared by ultrasound/surfactant-assisted template method with zinc oxide as a template and tetraethoxysilane as a silicon source.The zinc oxide/silica core/shell microspheres were treated with hydrochloric acid to etch the core of zinc oxide and obtain the hollow silica microsphere.The structure and morphology of hollow silica microsphere were characterized by Fourier transform infrared spectroscopy(FT-IR)and transmission electron microscopy(TEM),respectively.The hollow silica microspheres were used for a polyacrylate film.The effect of hollow silica microspheres on the water-vapor permeability and mechanical properties of the polyacrylate film was investigated.The results show that Tween-80and polyvinyl pyrrolidone can be used for the dispersion of zinc oxide and the cover of silica.The zinc oxide/silica core/shell microsphere was formed.Hydrochloric acid is effective in etching the zinc oxide core of zinc oxide/silica core/shell microsphere when pH=2to obtain the hollow silica microsphere.The FT-IR results show that the inner surface of the shell of hollow silica microsphere contains some zinc oxide.The TEM results show that the particle size of the hollow silica microspheres is 47nm,the thickness of silica shell is 12nm and the diameter of hollow cavity is 23nm.The introduction of hollow silica sphere can improve the water-vapor permeability and mechanical properties of polyacrylate film.The optimum water-vapor permeability of polyacrylate film can be obtained when the dosage of hollow silica microspheres is 1.5wt%.
【Fund】: 教育部新世纪优秀人才支持计划(NCET-13-0885);; 国家自然科学基金(21376145);; 陕西科技大学科研创新团队(TD12-03)
【CateGory Index】: TQ127.2;TQ320.721
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 6 Hits
1 CHEN Li-jun1,2,SHI Hong-xin1,WU Hong-ke1,XIANG Ju-ping1(1.School of Chemical Engineering and Materials Science of Zhejiang University of Technology,Hangzhou 310032,China;2.Department of Materials Science and Engineering of Tsinghua University,Beijing 100084,China);Structure and Properties of Nano-SiO_2/Acrylic Composite Emulsion Prepared via Soap-Free Emulsion Polymerization[J];Polymer Materials Science & Engineering;2009-10
2 ZHENG Jing,CHEN Xiao-hui (College of Chemistry and Chemical Engineering,National Engineering Research Center of Chemical FertilizerCatalyst,Fuzhou University,Fuzhou 350002,China);Synthesis and Characterization of Ultrafine SiO_2[J];Bulletin of the Chinese Ceramic Society;2008-06
3 ZHANG Jiao-ru, PI Pi-hui, WEN Xiu-fang, ZHANG Xing-juan, CAI Zhi-qi, XU Shou-ping, CHENG Jiang, YANG Zhuo-ru School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China;Synthesis of nano-SiO_2/polyacrylate composite emulsion and its film performance[J];Electroplating & Finishing;2012-09
4 Chun Liu, Aili Wang, Hengbo Yin , Yutang Shen, Tingshun Jiang Faculty of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China;Preparation of nanosized hollow silica spheres from Na_2SiO_3 using Fe_3O_4 nanoparticles as templates[J];颗粒学报(英文版);2012-03
5 QIU Wen-jie,CAI Hong,ZHANG Yong-li(Department of Chemistry,Hanshan Normal University,Guangdong Chaozhou 521041,China);Property Research of Nano-ZnO Coated by Silica on Its Surface[J];Contemporary Chemical Industry;2010-03
6 WEI Gui-ming1,DU Ji-min2,RONG Hao-jie,ZHANG De-jing(1.Library of Anyang Normal University,Anyang,455002,China;2.College of Chemistry and Chemical Engineering,Anyang Normal University, Anyang,455002,China);Zinc Oxide Nano-materials Synthesis,Structural Characterization,Optical and Catalytic Properties[J];Journal of Salt Lake Research;2011-03
Chinese Journal Full-text Database 10 Hits
1 ZHANG Li-gong 1,ZHAO Gui-mei1,WU Xiao-hong2(1.China Academy of Space Technology,Beijing Spacecrafts,Beijing 100080; 2.Dept.of Chemistry,Harbin Institute of Technology,Harbin 150001,China);Preparation of thermal control coatings of ZnO/SiO_2 core-shell[J];Materials Science and Technology;2011-04
2 Zhang Heng Liu Li-li Zhang Yan-chong (College of Chemical Engineering,Qingdao University of Science and Technology,Qingdao 266042,Shandong,China);Preparation and Application of Nano SiO_2/Styrene-acrylic Soap-free Emulsion by In-situ Polymerization[J];Paper Science & Technology;2012-02
3 GUAN Lu-xiong,OU Ye-xiu(College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China);Study of Silica Aerogels Prepared by Sol-gel Process Dried at Ambient Pressure[J];Bulletin of the Chinese Ceramic Society;2010-02
4 JIANG Xiao-yang,LI Xia(College of Materials Science and Engineering,Qingdao University of Science and Technology,Qingdao 266042,China);Progress in Application and Preparation of Nano-silica Microspheres[J];Bulletin of the Chinese Ceramic Society;2011-03
5 SU Xiao-li1,2,XU Su-peng1,CAI Tian-cong3(1 Department of Metallurgy and Chemical Engineering,Jiyuan Vacational and Technical College, Henan Jiyuan 454650;2 Key Laboratory for Special Functional Materials Ministry of Education,Henan University, Henan Kaifeng 475001;3 Henan Mt Nanotechnology Limited Liability Co.,Ltd.,Henan Jiyuan 454650,China);Jet Grinding and Surface Modification of ZnO Nanoparticles[J];Guangzhou Chemical Industry;2012-10
6 LU Bin,HU Ke,LIU Qi,SUN Jun-yan,ZHANG Ding-ri(School of Materials Science and Engineering,Central South University,Changsha 410083,China);Synthesis and Properties of SiO_2 Aerogel by Co-precursor and Ambient Pressure Drying Process[J];Bulletin of the Chinese Ceramic Society;2013-07
7 Zhang Shaoyun;Wang Yong;Huang Xiuping;Yang Siwei;Chen Denglong;College of Materials Science and Engineering,Fujian Normal University;College of Chemical Science and Engineering,Fujian Normal University;Quangang Petrificstion Research Institute,Fujian Normal University;College of Environmental Science and Engineering,Fujian Normal University;;Study on waterborne acrylate pressure sensitive adhesive for surface protective film[J];China Adhesives;2013-09
8 Xu Yun-he;Xu Hui-fang;Gao Bei-ling;Zhang Hai-jiao;Wei Hua-wei;School of Chemical Engineering and Technology,Harbin Institute of Technology;Engineering Institute of Graphite New Materials,Heilongjiang University of Science and Technology;;Research progress of composite conductive polymer /magnetic nanoparticles[J];Materials Protection;2013-S2
9 LIU Bo;JIU Hong-fang;JIA Wan-bao;HUANG Chang-shui;College of Science,North Un iversity of China;;Progress of Hollow Materials Prepared via Polymer Template[J];Technology & Development of Chemical Industry;2014-01
10 DING Liang;YANG Hui;XI Ya-Nan;ZHANG Jin-Chao;SHEN Shi-Gang;School of Basic Medicine,Hebei University;College of Chemistry & Environmental Science,Hebei University;;Signal Amplification Effect of Non-fluorescent Zinc Sulfide Nanoparticles Cluster for Detection of Trace Proteinsbiological Molecules[J];Chinese Journal of Analytical Chemistry;2014-06
China Proceedings of conference Full-text Database 1 Hits
1 ;Influence of Transition of Silica Coating on the Properties of Quartz Fiber and Phosphate of Chrome-Alumina Composite[A];[C];2012
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 YANG Wenshu 1,2*, FANG Dingye 1, XIANG Hongwei 2, LI Yongwang 2, LIU Jisen 1(1 College of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;2 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, The ChineseAcademy of Sciences, Taiyuan 030001, Shanxi, China);Characterization and Catalytic Performance of Co/HMS and Co/SiO_2 Catalysts for Fischer-Tropsch Synthesis[J];Chinese Journal of Catalysis;2005-04
2 ;The Summary of Nanocrystalline Materials[J];Materials Review;1997-02
3 ZOU Jian1,GAO Jia-cheng1, WANG Yong1,LI Yi-dong2,WEN Min2 (1.Department of Material Science and Engneering, Chongqing University, Chongqing 400044,China; 2.Chongqing Yu-Gang Tioxide Co.Ltd,Chongqing 400055,China);Trial Study on Nanosize TiO_2 Coated by Dense SiO_2 Film[J];Journal of Materials Science and Engineering;2004-01
4 HUO Yu-qiu~(1,2), ZHAI Yu-chun~1, TONG Hua-nan~1(1. School of Materials & Metallurgy, Northeastern University, Shenyang 110004, China; 2. School of Science, Northeastern University, Shenyang 110004, China. Correspondent: HUO Yu-qiu, E-mail: huoyuqiu @ eyou.com);Influence of Three Cosolvents on Hydrolysis of Tetraethyl-orthosilicate[J];JOURNAL OF NORTHEASTERN UNIVERSITY;2004-02
5 Yang Chunli, Huang Yudong(Harbin Institute of Technology, Harbin 150001, P. R. China); Wang Zhenyu(Northeast Forestry University);Synthesis of Acrylic Resin Modified by Silicone[J];Journal of Northeast Forestry University;2003-05
6 Zhou Yuxin Yu Xuping WU Yuan (School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology,Hubei Key Lab of Novel Reactor & Green Chemical Technology,Wuhan 430074,China);Preparation of"ultrafine"white carbon black by impinging stream reaction-precipitation[J];Chemical Engineering & Equipment;2007-04
7 LIU Zhong Yi (Department of Chemistry, Heilongjiang University, Harbin, 150080) WANG Li Wei, WANG Zi Chen *, ZHAO Jing Zhe, YANG Hua, ZHAO Mu Yu (Department of Chemistry, Jilin University, Changchun, 130023) ZHAO Dong Mei (Qinhuangdao Institute of Med;Preparation of Porous SiO 2 with High Specific Surface Area by Sodium Silicate[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1998-05
8 LIN Zhi-xian,ZHANG Yong-ai,QIN Hua-fang,GUO Tai-liang(College of Physics and Information Engineering,Fuzhou University,Fuzhou 350002,China);Study of preparation and field emission properties of ZnO nanomaterial[J];Journal of Functional Materials;2010-02
9 Shi Liyi Hua Bin Zhang Jianping(School of Chemistry, and Chemical Engineering, Shanghai University,Shanghai, 200072,China);Structure of Microemulsion and Application of W/O Microemulsion in the Preparation of Ultrafine Particles[J];JOURNAL OF FUNCTIONAL MATERIALS;1998-02
10 Yu Jiaguo Zhang Lianmeng Tong Bing Chen Pei(Wuhan University of Technology);Studies on the Preparation of SiO_2 Ultrafine Powder by Sol-gel Process and its Mechanism[J];Bulletin of the Chinese Ceramic Society;1992-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved