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《Gongye Cuihua (Industrial Catalysis)》 2001-02
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Synthesis of n-butyl acetate catalyzed by phosphotungstomolybdate heteropolyacid supported on activated carbon

ZHOU Yuan,LIU Xin ling, WANG Huan long,DAI Li qing, YE Qi yue(Department of Applied Chemistry, Hunan Institute of Engineering,Hunan Xiangtan 411101,China)  
Phosphotungstomolybdate heteropolyacid was supported onto activated carbon through vaporization. Reaction condition for synthesis of n butyl acetate was investigated using the heteropolyacid catalyst. N butyl acetate yield of 92 3% was attained under following condition: 5ml cyclohexane as water carrying agent, n butanol/acetic acid=1/1 1(mol)(i e., 10ml acetic acid and 14 4ml n butanol), 1 0g catalyst, with water separation and recycle, reaction time=2h. The heteropolyacid catalyst remains 74 4% activity after four times of repeated use.
【CateGory Index】: TQ225.24
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