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《Industrial Catalysis》 2003-04
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Advances in synthesis of dimethyl carbonate directly and indirectly from carbon dioxide

ZHOU Li, LI Zhong, XIE Kechangf Chemistry Engineering for Coal, Taiyuan University of Technology, Shanxi Taiyuan 030024, China)  
The synthesis of dimethyl carbonate (DMC) from carbon dioxide is an attractive route to chemical industry and environmental protection. Direct synthesis (synthesis directly from carbon dioxide and methanol) and indirect synthesis (synthesis via formation of carbonate or urea from CO2 and then transesterification of ester carbonate with methanol or urea alcoholysis) of DMC were reviewed. Catalysts and reaction condition of direct synthesis were discussed, too. It was pointed out that direct synthesis of DMC may become a technology of promising prospect. 
【Fund】: 山西省归国留学基金 (990 0 3 3 );; 山西省自然科学基金
【CateGory Index】: TQ225.24
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