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《GONGYE CUIHUA (INDUSTRIAL CATALYSIS)》 1996-02
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Study on COS Hydrolysis Kinetics on Y-906 Catalyst in Reducing Atmosphere

Li Jianwei;Li Chengyue(Dept Chem Eng,Beijing Univ Chem Technol Beijing,100029)Liu Jindun;Fang Wenji(Dept Chem Eng,Zhengzhou Inst Technol Zhengzhou,450002)  
The intrinsic and maerosopic kinetic model of COS hydrolysis over r-906 catalyst were investigated in a gradientless reactor with internal-recycle under following conditions:30-70℃,atmospheric pressure and reducing atmosphere. Multiple regression method was used to estimate the parameters of the kinetic model of this system. The established intrinsic kinetic model is as follows:35370rcos=4. 593× 106exp(-RT)ycosyH2o)and the macroscopic kinetic model is:31266.rcos=1.025× 105exp(-RT) ycosyH2o0. 66-order and 0. 06-order behavior were observed for COS and H2O,respectively.
【CateGory Index】: TE665.3
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【References】
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