Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Hebei University(Natural Science Edition)》 2009-04
Add to Favorite Get Latest Update

Preparation of Supported Copper Based Catalysts and Its Application in Coupling Process of 2-Butanol Dehydrogenation and Furfural Hydrogenation

BAI Guo-yi1,WANG Hai-long1,NING Hui-sen1,FAN Xin-xin1,DOU Hai-yang1,ZHAO Wei2(1.College of Chemistry and Environmental Science,Hebei University,Baoding 071002,China;2.College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China)  
A series of supported copper based catalysts for the coupling process of 2-butanol dehydrogenation and furfural hydrogenation were prepared by different methods.The effect of promoters and silicon sources on the catalysts' activities were emphatically investigated.The results showed that the CMS-Ce catalyst supported on the self-prepared hollow silica had the best activity.The conversion of furfural and the selectivity to furfuryl alcohol both reached 100%,while the conversion of 2-butanol reached 52.9% and the selectivity to methyl ethyl ketone was 100% under the optimized reaction conditions.Cu0 was believed to be the active site of the catalysts based on XRD and TPR characterization.
【Fund】: 河北省自然科学基金资助项目(B2007000156);; 河北大学自然科学基金资助项目(2006Y03)
【CateGory Index】: O643.36
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 2 Hits
1 WANG Zhen-Lü, WU Tong-Hao, YANG Piao-Ping, YU Jian-Feng, ZHU Wan-Chun, JING Shu-Bo, LIU Guo-Zong, WANG Guo-Jia* (College of Chemistry, Jilin University, Changchun 130023, China);Dehydrogenation of 2-Butanol over Supported Copper Catalysts[J];Chemical Research In Chinese Universities;2004-09
2 SHEN, Wei YANG, Xin-Yan HUANG, Jing-Jing SHEN, Jiang DU, Jun-Ming XU, Hua-Long (Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433);Coupling Process of Dehydrogenation of 1,4-Butanediol and Hydro- genation of Dimethyl Maleate over CuO/SiO_2 Catalysts[J];Acta Chimica Sinica;2007-07
Chinese Journal Full-text Database 10 Hits
1 He Jieyu (Department of Chemical Engineering, Yueyang Normal College, Yueyang 414000);Synthesis of n-Butyl Acetate Catalysed by Ti(SO_4)_2/SiO_2[J];Anhui Chemical Industry;2002-01
2 Li Anmei (Jingmen Vocational Technology College ,Hubei Province 434500);The Production and Application of a New Energy--Dimethyl Ether[J];Anhui Chemical Industry;2005-03
3 LI Chao1,WANG Gui-ying2,Yao Ri-sheng1 (1. College of Chemical Industry, Hefei Technology University,Hefei 230009,China; 2. Anhui Fengle Agriculture Chemistry Co.,Ltd.,Hefei 230031,China);The Application & Synthetical Technology of p-Hydroxybenzaldehyde[J];Anhui Chemical Industry;2008-03
4 XU Zi-ao,LI De-gang,XU Yu-mei,LI Xiao-xiang(Anhui NewStar Pharmaceutical Development Co.,Ltd,Hefei 230031,China);Studies on the Synthesis of 4-Methyl-3-decan-5-ol[J];Anhui Chemical Industry;2009-03
5 LIU Yuan-sheng(Anhui HuaxingChemical IndustryCo.Ltd.,Chaohu 238251,China);One-pot Synthegic Technology of 2-Amino-4-methyl Benzothiazole[J];Anhui Chemical Industry;2009-03
6 GU Jia-shan, HE Xin-wei, CHU Dao-bao~*(College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Normal University. Wuhu, China 241000);ELECTROCATALYTIC SYNTHESIS OF BUTANEDIOIC ACID ON NANOCRYSTALLINE TiO_2 FILM CATHODE[J];Journal of Anhui Normal University(Natural Science);2005-03
7 FENG Qing-qin (Department of Chemistry Anyang Teachers College , Anyang 455000,China);The Preparation and the Characteristic of Adsorption Properties for Modified Cellulose of Core Straw[J];Journal of Anyang Teachers College;2004-02
8 SUN Jian(Shanghai Baosteel Chemical Co.,Ltd.,Shanghai 200941,China);Pilot-plant Experiment Research on Synthesis of N-ethyl Carbazole[J];Bao Steel Technology;2004-04
9 ZHANG Hai-hao,WANG Bo-zhou,LIU Qian,XIONG Cun-liang,JIA Si-yuan (Xi′an Modern Chemistry Research Institute,Xi′an 710065,China);Synthesis of 2-Nitroimino-5-nitrohexahydro-1,3,5-triazine(NNHT)[J];Chinese Journal of Explosives & Propellants;2007-06
10 HE Zhu-sheng1,ZHAO Li-fang1, SUN Jian-zhe1, ZHANG Xiao-guang2 (1.Dept. Chem. & Chem. Eng.,Baoji Coll.Arts & Sci.,Baoji 721007,Shaanxi, China; 2.Yangling Vocation-Technical College,Yangling 712100, Shaanxi, China);Developing the technology of preparing high purity dimethyl disulfide[J];Journal of Baoji College of Arts and Science(Natural Science Edition);2001-01
China Proceedings of conference Full-text Database 4 Hits
1 XU Huiyuan, CHU Wei*, ZHOU Jun(School of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan,China);Catalytic behaviors of CuCo/SiO_2 catalyst for hydrogenation of CO to lower alcohols[A];[C];2008
2 ZHANG Hui-ju,SHENG Jian-yu,LU Shuang,LI Hong-mei,PENG Xin-hua,CHENG Guang-bing School of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China;Preparation of 3-Amino-4-methoxy-acetanilide from 4-Methoxy-3-nitroacetaniline[A];[C];2005
3 LI Bin-dong,LU Chun-xu School of Chemical Engineering,Nanjing University of science and technology,NanJing 210094,China;A New Process Cyclochexy Phenyl Ketone[A];[C];2005
4 LI Xue-mei, XU Ning, LIU Xin-wen, ZHANG Chun-lei, SHAO Jing-ming (Research Institute of Shanghai Huayi Acrylic Acid Co. Ltd. . Shanghai 200137, China);STUDY ON HYDROLYSIS OF DIHYDROPYRAN BY HMCM-22[A];[C];2006
【Secondary Citations】
Chinese Journal Full-text Database 8 Hits
1 CHEN Xuegang, SHEN Wei, XU Hualong, XIANG Yifei (Department of Chemistry, Fudan University, Shanghai 200433, China);Preparation of γ- Butyrolactone from 1,4 Butanediol Dehydrogenation over Cu/ZnO/Al_2O_3 Catalyst[J];CHINESE JOURNAL OF CATALYSIS;2000-03
2 LU Jiqing, LUO Mengfei, LI Can *(State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China);Direct Epoxidation of Propylene on NaCl-Modified Cu/SiO_2 Catalysts Using Air as Oxidant[J];Chinese Journal of Catalysis;2004-01
3 WU Jing\+\{1,2\}, SHEN Yan\|ming\+\{1,2\}, WANG Kun\|yuan\+2 , LIU Chang\|hou\+1, ZHANG Zhen\|xiang\+2 (1. School of Chemical Engineering, Dalian University of Technology, Dalian Liaoning 116012, China; 2. School of Chemical Engineering, Shenyang Institute of Chemical Technology, Shenyang Liaoning 110142, China);Study on Structure of CuO-CaO/SiO_2 Ultrafine Catalysts and Reaction performance for Hydrogenation of Furfural[J];Journal of Molecular Catalysis;2003-05
4 MA Hong-Chao, LIU Zi-Yu, WANG Zhen-Lu, ZHU Wan-Chun, WANG Guo-Jia* (College of Chemistry, Jilin University , Changchun 130023. China);The Effect of La Doped on V_2O_5/γ-A1_2O_3 Catalyst for Activity in the Dehydrogenation of Isobutane[J];Chemical Research In Chinese Universities;2002-05
5 ZHU BO CHEN Ping LUO Meng-Fei YUAN Xian- Xin(Institute of Catalysis, of Hangzhou University , Hangzhou ,310028)WU Hong - Li LU Guang - Lie(Central Laboratory of Hangzhou University , Hangzhou ,310028);Studies on the TPR Characteristics and Oxidation Activities of Catalysts of Cu, Ag and Cu - Ag Supported on γ-Al_2O_3[J];Acta Chimica Sinica;1997-01
6 Gao Huiyuan ( Department of Chemical Engineering, Science and Engineering College of Hebei, Tangshan 063009);Production and Consumption of Methyl Ethyl Ketone[J];Advances in Fine Fetrochemicals;2001-08
7 Shen Wei, Wang Yu, Wu Jingtao, Guo Bailin and Xiang Yifei (Department of Chemistry, Fudan Univers(?)ty Shanghai 200433);γ-Butyrolactone from Maleic Anhydride by Hydrogenation nrude Atmospheric Pressure[J];Petrochemical Technology;1992-09
8 Gao Huiyuan(Department of Chemical Engineering,Science and Engineering College of Hebei,Tangshan 063009)Zhou Zhouhua and Zhang Baoan(Chemical Engineering College,Dalian University of Technology,Dalian 116012);Study on Catalytic Properties of Cu-ZnO-P/SiO_2 ·xK_2O(Catalyst for Dehydrogenation of 2-Butanol )[J];PETROCHEMICAL TECHNOLOGY;1995-11
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved