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《Chemistry & Bioengineering》 2009-04
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Study on Synthesis of CTS-Fe(Ⅲ) Complex and Its Catalytic Performance for Phenol Hydroxylation

GE Xin1,GAO Leng1,LI Ya-feng2,ZHANG Long2(1.Institute of Chemistry & Life Science,Changchun University of Technology,Changchun 130012,China; 2.Institute of Chemical Engineering,Changchun University of Technology,Changchun 130012,China)  
Complex of chitosan(CTS) and Fe(Ⅲ)was prepared by Fe3+ solution and chitosan,and the influence of reaction time,pH value,reaction temperature and Fe3+ content on the preparation were discussed.The optimized synthetic conditions of CTS-Fe(Ⅲ) were obtained as follows:3% of Fe3+ solution and 1.0 g CTS reacted at 65℃ for 6 h with pH value of 1.8.Under above conditions,the highest Fe3+ adsorption amount was 75 mg·g-1.The structure of CTS-Fe(Ⅲ) was characterized by XRD,FTIR and SEM.When the prepared CTS-Fe(Ⅲ) complex was utilized to catalyze phenol hydroxylation reaction under the following conditions:the mass ratio of catalyst to phenol was 1∶100,the molar ratio of phenol to H2O2 was 1∶2,the reaction temperature was 60℃ and the reaction time was 4 h,the maximum conversion rate of phenol reached 22.88%,and the maximum selectivity reached 99.67%.
【CateGory Index】: O621.25
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