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Preparation of an Enantioselective Ligand-exchange Membrane and its Application in Optical Resolution of DL-Amino Acids

Long,Yuan-De Huang,Tian-Bao (Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041)  
A new optical resolution membrane, crosslinked polyvinyl alcohol membrane with L-proline as chiral ligand-exchange selector, was prepared and the examination of enantioselective permeability for DL-Tyr, DL-Phe and DL-Trp through the membrane was carried out. It was found that L-amino acids used experimentally were permeated predominately through the membrane. The mechanism of enantiomer resolution of racemic amino acids through the membrane would be similar to that of resolution by chiral ligand-exchange chromatography and the enantioselective absorption would play an important role in the enantioselective permeation of DL-amino acids via the membrane.
【Fund】: 国家自然科学基金! ( No.2 95752 1 0 );; 四川省应用基础基金
【CateGory Index】: TQ028
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Chinese Journal Full-text Database 6 Hits
1 FANG Yanxiong,WANG Yali,XIONG Xujie,ZHANG Kun(Faculty of Chemical Engineering and Light Industry,GDUT,Guangzhou 510090 China);Study on Resolution of Chiral Amino Acid Enantiomers[J];Journal of Guangdong University of Technology;2002-03
2 ZHAO Lei,ZHAO Ping(College of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang Hebei 050018,China);Research development of enantiomer separation by membrane process[J];Hebei Journal of Industrial Science and Technology;2009-01
3 SONG Fa-jun 1, LIU Ming-fang 2, LAN Dong-mei 1,DING Zhi-gang 1 (1. South-Central University for Nationalities, Wuhan 430074, China; 2. Hubei Institute for Nationalities, Enshi 445000, China);Chial Separation of Amino Acid Enantiomer Through β- Cyclodextrin Derivative for Stationary of Column Chromatography[J];Journal of Hubei Institute For Nationalities;2002-02
4 ZHANG Guojun1,RUAN Zhengang1,GAO Xue1,JI Shulan1,LIU Zhongzhou2(1 College of Environmental and Energy Engineering,Beijing University of Technology,Beijing 100022,China;2Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China);Chiral separation with affinity membrane technology and chiral selective solid membrane[J];Chemical Industry and Engineering Progress;2008-06
5 LI Guoxiang1,2,AI Ping1,ZHOU Lingling1,XIE Shengming1,YUAN Liming1 (1.School of Chemistry,Yunnan Normal University,Kunming 650092,China;2.School of Chemistry and Environmental Engineering,Hubei Institute for Nationalities,Enshi 445000,China);Application of carbohydrate compounds in membrane separation of enantiomers[J];Membrane Science and Technology;2008-04
6 LIU Jing(School of Chemistry and Chemical Engineering,Xianyang Normal University,Xianyang,Shaanxi 712000,China);Progress on the Asymmetric Synthesis of Chiral Amino Acid and its Derivatives[J];Journal of Xianyang Normal University;2009-06
Chinese Journal Full-text Database 1 Hits
1 LONG YuanDe, HUANG TianBao (Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041);Enantioselective Permeation of Amino Acids Through Cyclodextrin Polymer Membranes[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1999-06
Chinese Journal Full-text Database 10 Hits
1 LIU Lihua\ ,\ GUAN Luxiong (College of Chemistry and Chemical Engineering, Central South Univ.,Changsha, 410083 P.R.China);Kinetic Studies on the Formation of Self-Assembled Monolayer of Thiol-Terminated β-Cyclodextrin Derivative[J];Journal of Transcluction Technology;2001-02
2 WT5BZ]GUAN Lu-xiong, LIU Li-hua [WT5”HZ][ST5”HZ](Coll. of Chem. and Chem. Engin., Central South University,Changsha 410083,China) [HT5”SS][WT5”HZ];Molecular recognition of thiol-terminated β-cyclodextrin derivative by using quartz crystal microbalance[J];Journal of Transducer Technology;2001-06
3 XU Hao, CHEN Liang (The Analysis and Test Center of Shanxi University, Taiyuan 030006, China);Preparation and Study Methods of Cyclodextrin Inclusion Complexes[J];Analysis and Testing Technology and Instruments;2001-03
4 Zhu Yang,Qiu Zhiqiang(Department of Chemistry Engineering,Jingmen Technical College,Jingmen 448000,China);Application of Polymer on Chiral Separation[J];Guangdong Chemical Industry;2007-05
5 YONG Guo-Ping~*, LI Guang-Shui, ZHENG Fei, ZHOU Hui-Shun (Department of Food Science and Engineering, Institute of Economics and Technology, University of Science and Technology of China, Hefei 230052, China);The Structure Study of the β-Cyclodextrin Inclusion Complexes[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-07
6 YANG Guo Sheng , YAN Bo, LEI Lin, WANG Wen Gang, LIU Cheng Bu [WT5”BX](School of Chemistry, Shandong University, Jinan 250100, China);Studies of Chiral Discrimination of Diniconazole by Molecular Mechanics[J];Chemical Research In Chinese Universities;2000-11
7 XIA Bao Yun, CAI Wen Sheng , PAN Zhong Xiao, SHAO Xue Guang (Department of Chemistry, University of Science and Technology of China, Hefei 230026, China);Chiral Recognition Study for the Inclusion Complexes of Amino Acid with β-Cyclodextrin Using a Fast Annealing Evolutionary Algorithm[J];Chemical Research In Chinese Universities;2002-06
8 ZHANG Jin-Nan 2, YE Ling 2, ZHENG Xiao-Yan 1, LI Qi 1 * (1. Department of Chemistry, Beijing Normal University, Beijing 100875, China; 2. Department of Chemistry, Basic Medical College, Capital University of Medical Science, Beijing 100054, China);Synthesis and Crystal Structures of Tetraethyl Ammonium Inclusion Complex with Urea, Fumarate and Water Molecules as Anionic Host Lattice Building[J];Chemical Research In Chinese Universities;2002-12
9 QIAN Jin-Wen 1*, WANG Li-Na 1, AN Quan-Fu 1, CHEN Huan-Lin 2 (1. Department of Polymer Science and Engineering; 2. Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China);Preparation of Etherified β-Cyclodextrin and Selectivity in Its Blend Membrane for Xylene Isomers[J];Chemical Research In Chinese Universities;2003-06
10 WANG Hai-Dong,CHU Liang-Yin,CHEN Wen-Mei,XIE Rui,JU Xiao-Jie,ZHANG Jie,YANG Mei(School of Chemical Engineering,Sichuan University,Chengdu 610065,China);Development of the Application of Cyclodextrin in Enantioseparation[J];Journal of Filter & Separator;2004-04
China Proceedings of conference Full-text Database 1 Hits
1 WU Ju-xian~(1,2),SHI Xiao-yan~3,WANG Xiao-ming~(1,4),LIN Xue~2,HUANG He~(1*) (1.Guangdong Ocean University Guangdong,Zhanjiang.524008.2.Zhuhai Eulong Foodstuff Co.,Ltd Engineering R&D Center, Guangdong,Zhuhai,519000,China.3.College of Agriculture,Northeast Agricultural University,Heilongjiang Harbin 150030,China. 4.Guangdong Province Huahai Sugar Industry Development Co.,Ltd,Zhanjiang 524132);Research Progress of Separation Membrane Composrd by Polysaccharide in Chiral Separation of amino acids[A];[C];2010
Chinese Journal Full-text Database 10 Hits
1 Cao Junwei Gao Chundong Liu Zhijian (School of Life Sciences, Wuhan Universite, Wuhan 430072);High-Producers of Aminoacylase selected from mutants of Aspergillus oryzae[J];AMINO ACIDS & BIOTIC RESOURCES;1999-03
2 Liao Xiaoyuan (Dongshen Fine Chemical Institute, SHENZHEN, 518057);Study on the Production of D-Lysine Monohydrochloride From L-Lysine Monohydrochloride[J];AMINO ACIDS & BIOTIC RESOURCES;1999-03
3 Tang Jiafang Zhang Yizhu (College of Life Science,Wuhan University,Wuhan 430072);Stereoselective Synthesis of α-Amino Acids[J];AMINO ACIDS & BIOTIC RESOURCES;1999-04
4 LIANG Yuan-jun LIU Ke-liang (Institute of Toxicology and Pharmacology, Academy of Military Medical Sc iences 100850) Yu Wen-sheng ZHAO Yu-fen (Department of chemistry, Tsinghua University 100084);Synthesis and Resolution of Ring-substituted phenylalanines[J];Amino Acids & Biotic Resources;2001-02
5 LI Huan, LI Rui, CHENG Guo-guang,WEI Ping (College of Life Science and Pharmacy, Nanjing University of Technology, Nanjing 210009, China);Characterization of L-aminoacylase in Bioengineered Bacterium 1016[J];Amino Acids & Biotic Resources;2004-01
6 ZOU Xue -Man (Gaungzhou Hua Li Company of Technical Study on Amino Acids, Guangzhou 510405, China);Comparison of Different Production Techniques of Natural Amino Acids[J];Amino Acids & Biotic Resources;2004-03
7 GAO Da-xiang,LI Zhao-lan,JIAO Qing-cai,GUO Li-yun (College of Life Science, Nanjing University, Nanjing 210093, China);Study on Resolution of DL-Alanine by Aminoacylase from Cunnighamella echinulata[J];Amino Acids & Biotic Resources;2005-02
8 Li Rui ping(Yichang Pharmaceutical Factory, Hubei Province.);Amino Acid Analysis of Industrial Wastes Disested by Microwave Using Precolumn Phenyl Isothiocyanate Derivatization and Reversed-phaseHPLC[J];AMINO ACIDS & BIOTIC RESOURCES;1995-02
9 Jin Yan; Jin Xinrong; Yin Zhengquan(Institute of Science, East China University of Science and Technology);An Approach to Determination of Salt Content in Amino Acid Mother Liquor[J];AMINO ACIDS & BIOTIC RESOURCES;1995-02
10 Yun Zihou; Lu Hai tao(Department of Chemistry, Beijing Normal University, Beijing 100875);Optimization of DL-Amino Acid Separation[J];AMINO ACIDS & BIOTIC RESOURCES;1996-01
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 CHEN Yang,YU Yan-mei,LUO Guang-sheng (State Key Laboratory of Chemical Engineering,Department of Chemical Engineering,Tsinghua University,Beijing 100084,China);High Performance Liquid Chromatographic Analysis of Tryptophan Enantiomers[J];Analysis and Testing Technology and Instruments;2006-04
2 HE Le-qin1,ZHANG Gui-qin2,BIAN Li1(1.College of Sciences,Hebei University of Engineering,Handan Hebei 056038,China;2.Shijingxiang Middle School of Luquan of Shijiazhuang,Shijiazhuang Hebei 050200,China);Preparation and enantioselective epoxidation catalysis of chiral C_2-asymmetry Salen-Mn(Ⅲ) complex supported on MCM-41[J];Hebei Journal of Industrial Science and Technology;2009-03
3 QI Jian~(1), ZHANG Xiao-lin~(1,2), TAO Ying~(1), TIAN Jian-wen~(2 ) (1.College of Environmental Science and Engineering , Nanchang University, Nanchang 330029,China;2.Basic Chemistry Experimental Centre, Nanchang University,Nanchang 330029,China);Application of Configuration's Transformation and Resolution in the Preparation of D-Amino Acids[J];;2005-04
4 LI Guo-xiang1,AI Ping2,YUAN Li-ming2(1.School of Chemical and Environmental Engineering,Hubei University for Nationalities,Enshi 445000,China;2.School of Chemistry,Yunnan Normal University,Kunming 650092,China);Study on Preparation of Cellulose Trisphenylcarbamate Composite Membranes and Primary Application to Separate(±)-1-(1-Naphthyl) Ethanol[J];Journal of Hubei University for Nationalities(Natural Science Edition);2009-02
5 NI Fang,JIA Hong-hua,ZHOU Hua,WEI Ping(College of Life Science and Pharmaceutical Engineering,Nanjing University of Technology,Nanjing 210009,China);Study on immobilization of Burkholderia cepecia JS-02 with PVA[J];Journal of Nanjing University of Technology;2004-04
6 NONG Lan-ping,HUANG Min,ZHUANG Yu-ping(Chemistry & Life Science College of Maoming University,Maoming 525000,Guangdong,China);Preparation and Selective Permeation Characterization of L-Tryptophane Molecular Imprinting Chitosan Film[J];Chemical Research;2009-03
7 Shi Kaifeng Cao Fei Zhou Hua Wan Honggui Wei Ping (College of Life Science and Pharmacy,Nanjing University of Technology,Nanjing, 210009);Optimization of Aspergillus Oryzae 3042 Liquid Fermentation Producing Aminoacylase[J];Food and Fermentation Industries;2004-07
8 Wu Fangning(Tianjin Center for Drug Evaluation,Tianjin 300052);Application of membrane technology in separation of pharmaceuticals[J];Tianjin Pharmacy;2010-02
9 Cui Guohong(Sichuan Tianzheng Chemical Co.,Ltd.,Chengdu 610218,China);Study on the New Synthesis of DL-isoleucine[J];Sichuan Chemical Industry;2010-04
10 JIA Hong-hua, WEI Ping, ZHOU Hua, OUYANG Ping-kai(College of Life Science and Pharmacy, Nanjing University of Technology,Nanjing 210009, China);Enzymatic conversion of D,L-benzylhydantoin to N-carbamoyl-D-phenylalanine[J];Modern Chemical Industry;2003-06
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 Huang Tianbao~*, Huang Sugui, Kuang Changyu, Wu Banggui, Zhou Jingxian (Chengdu Institute of Organie Chemistry, Academia Sinica, Chengdu, 610015);Determination of Fenvalerate Stereoisomers on the Chiral Stationary Phase by High-Performance Liquid Chromatography[J];Chinese Journal of Analytical Chemistry;1991-03
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