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《Chinese Journal of Synthetic Chemistry》 2002-02
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Synthesis and Properties of Two New Charge Transfer Complexes of Vanadium Substituted Molybdophosphorate with Dawson Structure

WANG Shi ming, HUANG Jin feng, ZHENG Ying, CHEN Li juan, WU Quan fa (Department of Chemistry, Fujian Normal University, Fuzhou 350007, China)  
The charge transfer salts 8C 8H 11 N·H 8P 2Mo 16 V 2O 62 ·3C 3H 7NO·5H 2O, 8C 8H 11 N ·H 10 P 2Mo 14 V 4O 62 ·4C 3H 7NO have been synthesized. Their structures and properties were investigated by elemental analysis, ICP, IR, UV vis and ESR. Spectroscopic data support the presence of an electronic interaction between electron rich aromatic organic and inorganic anions in the solid state.
【Fund】: 福建省科委资助项目 (KE1 0 1 4 )
【CateGory Index】: O641.4
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