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《Synthetic Fiber in China》 2007-11
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Investigation on Modification of Amidoxime Groups onto PAN Fibers and Its Structures and Properties

TIAN Zhen-bang1, HUANG Wei-qing1, HUANG Zuo-hua2, ZHANG Xiao-zhuan3, ZHAO Liang1 (1. Henan Research Institute for Chemistry, Henan Academy of Sciences, Zhengzhou Henan 450002; 2. Henan G&D Research Institute for Environment and Chemicals, Zhengzhou Henan 450002 3. College of Chemistry and Environmental Science, Henan Normal University, Xinxiang Henan 453007)  
A chelating fiber with amidoxime functional groups had been prepared from PAN fibers through processes of pre-treatment, crosslinkage and modification. The comprehensive properties, chemical structure, mechanical strength, micro-structure and exchange capacity of the fiber had been characteized by infrared spectrum, tensile testing, SEM and chemical analysis. The results showed that the designed synthesis method was simple and reliable, the mechanical intensity of the fiber was optimum, and the amidoxime content of the fiber was about 9.8~11.4 mmol/g.
【Fund】： 国家科技部国际科技合作重点项目(2004DFA05100);; 2005年度河南省重点科技攻关项目(052322000)
【CateGory Index】： TQ342.3
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