Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《JOURNAL OF EASTCHINA NORMAL UNIVERSITY(NATURAL SCIENCE)》 1997-03
Add to Favorite Get Latest Update

Studies on the Kindtics of Electrochemical Asymmetric Reduction of Phenylglyoxylic Acid

Xu Chengtian; Chen Gang; Lu Jiaxing ; Zhu Renkang; Chen Liang ;Zhang Wuchang(Department of Chemistry , East China Normal University , Shanghai 200062)  
Phenylglyoxylic acid(PGA) was reduced to chiral product[S(+ ) - mandelic acid], usingpoly - L - valine graphite electrode (CelPLV). On the basis of electrolysis, the characteristics and kinetic parameters of electrode processes were also determined by electrochemical techniques. The possible mechanism of the asymmetric electroreduction of PGA was obtained as a theoretical basis of choiceof condition of electrolysis.
【Fund】: 国家自然科学基金
【CateGory Index】: O643
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 2 Hits
1 SHAO Heng,GAN Yong-ping*,ZHANG Wen-kui,HUANG Hui,YE Zhang-jun (College of Chemical Engineering and Materials Science,Zhejiang University of Technology,Hangzhou 310032,China);Advances in resolution of mandelic acid and synthesis of chiral mandelic acid[J];Chemical Reagents;2007-03
2 LU Hai-ying,CHEN Jing,ZHENG Yu-guo,SHEN Yin-chu(Institute of Bioengineering,Zhejiang University of Technology,Hangzhou 310014,China);Progress in synthesis of chiral mandelic acid and resolution of racemic mandelic acid[J];Modern Chemical Industry;2007-S2
【Citations】
Chinese Journal Full-text Database 2 Hits
1 Zhang,Wu-Chang;Chen, Gang; Chen, Liang;Lu, Jia-Xin;Xu,Cheng-Tian(Department of Chemistry, East China Normal University, Shanghai, 200062);The Development of Electrochemical Asymmetric Synthesis[J];CHINESE JOURNAL OF SYNTHETIC CHEMISTRY;1995-01
2 Chen Gang;Lu Jiaxing;Xu Chengtian;Gao Jiannang;Chen Liang;Zhang Wuchang(Department of Chemistry,East China Normal University,Shanghai 200062);Asymmetric Reduction of Phenylglyoxylic Acid Using Poly-L-Valine Modified Graphite Electrode[J];CHINESE JOURNAL OF APPLIED CHEMISTRY;1996-06
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 GUI Xue-qin~1,WANG Hai-yan~(2),WANG Shi-jun ~2,JIN Bao-kang~2(1.Center of Modern Experiment and Technology,Anhui University,Hefei 230039,China;2.School of Chemistry and Chemical Technology,Anhui University,Hefei 230039,China);The preparation and electrochemical behaviors of binary self-assembled gold nano-particles interface[J];Journal of Anhui University(Natural Sciences);2006-05
2 Tian Chunxiang,Chen Yanling,Yuan Junhua,Wang Xiuzhong(China University of Geoscience,Wuhan430074);Preparation of Carbon Paste Electrode Modified by YPA_4 and Its Application in the Cadmium Trace Determiration[J];Anhui Chemical Industry;2003-03
3 MAO DingWen TIAN YanHong (College of Materials Science and Technology; Beijing University of Chemical Technology,Beijing 100029, China);Use of polyaniline/activated carbon doped with lithium as an electrode material in supercapacitors[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2007-06
4 LIU Yan, \ PANG Zhi cheng (School of Chemical Engineering and Materials Science, Beijing Institute of Technology, Beijing100081, China);A Study on the Redox Reaction of Auxiliary Catalyst Component Iron on the Oxygen Electrode[J];Journal of Beijing Institute of Technology;2002-04
5 Kong Esheng,Xu Bing,Yu Fenglan,Ren Shu (Biomedical Engineering Lab. of Tongji Medical University,Wuhan 430030);Development of a In Vivo Monitor of the Partial Pressure of Oxygen[J];Beijing Biomedical Engineering;1995-02
6 MU Dong yan, CUI Li feng (College of Chemical Engineering, Beijing Technology and Business University, Beijing 100037, China);RESEARCH OF TYROSINASE BIOSENSOR FOR DETECTION OF PHENOLS[J];Journal of Beijing Institute of Light Indusry;2002-01
7 Sun yuanxi (Hunan Changde Teatchers College,Changde, 415000);Conducting Polymer Film Modified Electrodes and Its Analytical Application[J];;1997-03
8 ZHOU Gu-zhen 1,WU Ai-zhen 2, SUN Yuan-xi 1,ZHANG Xu-liang 1 (1.Chemistry Department of Hunan University of Arts and Sciences; 2.NO.2 Phonix School,Pheonix,Hunan,416000);The Electrocatalysis Action of Poly (fluorescein) Film Modified Electrode on Uric Acid[J];;2005-01
9 MA Jian-guo, LIU Shu-juan, CAO Xiao-hong (Applied Chhemistry Department of East China Institute of Technology, Fuzhou Jiangxi 344000, China);A Study on Electrocatalization of Polymeric Amino-β-cyclodextrine Modified Electrode for Ascorbic Acid[J];Journal of Transcluction Technology;2005-01
10 SUN Xiao-liang,WANG Jing,SUN Xiao-jie,LI Dong-dong,XIAO Ying-hong*(School of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China);Morphology of Conducting Polypyrrole Electropolymerized Via Al/Al_2O_3 Template[J];Chinese Journal of Sensors and Actuators;2006-06
China Proceedings of conference Full-text Database 3 Hits
1 ZHANG Xin ZHANG Yu-lin LIU Guo-song(1.School of Control Science and Engineering,Shandong University,Jinan 250061,China;2.School of Management,Tianjin University,Tianjin 300072,China);Circuit design for the micro-current signal in amperometric detection[A];[C];2005
2 XU Li-ping ZHANG Sheng-tao QIAN Ying (1.Zhengzhou Research Institute,Aluminum Corporation of Chins Limited,Zhengzhou 450041,China; 2.College of Chemistry and Chemical Engineering,Chongqing University,Chongqing 400044,China);Electrode reactive mechanism of chromium residue solution treatment by electrolytic method[A];[C];2008
3 Mu Dongyan (Beijing Tsinghua Novel Environmental Protection Co.,Ltd.);Study on A Tyrosinase-memberane Electrode Modified with Maltodextrin for Detection of Phenols[A];[C];2004
【Co-references】
Chinese Journal Full-text Database 9 Hits
1 Nie Mengyan, Zhou Liangmo *, Wang Qinghai, Zhu Daoqian (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Gas Chromatographic Enantiomer Separation of Mandelates and Its Analogs on Permethylated Cyclodextrin Chiral Stationary Phases[J];Chinese Journal of Analytieal Chemistry;2000-11
2 Zhang Guofeng Zhang Yingju (State Key Laboratory of Fine Chemicals,Dalian University of Technology, Dalian 116012);Synthesis of the Mandelic Acid and Its Derivatives[J];DYESTUFF INDUSTRY;1997-03
3 XIAO Mei-tian1,2, HUANG Ya-yan1, SHENG Jun1, MENG Chun1, SHI Xian-ai1, GUO Yang-hao1 (1. Institute of Pharmaceutical Biotechnology and Engineering, Fuzhou University, Fuzhou, Fujian 350001, China; 2. Department of Chemical Engineering, Huaqiao University, Quanzhou, Fujian 362011, China);Influencing Factors of Asymmetric Biosynthesis of R-(-)-mandelic Acid[J];The Chinese Journal of Process Engineering;2004-01
4 ZANG Jian, WANG Zhi-jun, WU Yi-zu(Nanjing University of Technology, Jiangsu 210009,China);The Optical Resolution of Mandelic Acid[J];Fine Chemical Intermediates;2005-01
5 ZANG Jian , WANG Zhi-jun , WU Yi-zu (Nanjing University of Technology, Nanjing 210009, China);Research on optical resolution of DL-mandelic acid by D- (-)- phenylglycine derivates[J];Journal of Chemical Industry & Engineering;2005-01
6 RUAN Yuanping~(1,2), ZHANG Xueman~(1,2), CHEN Anqi~1, QIU Haiyuan~1, HUANG Peiqiang~1(1. Department of Chemistry, Xiamen University, Xiamen 361005, China; 2. The Key Laboratory of AnalyticalSciences of Ministry of Education, Xiamen University, Xiamen 361005, China);Enantiomeric Separation of Mandelic Acid and Its Analogues by High Performance Liquid Chromatography with 2,6-Di-O-Pentyl-β-Cyclodextrin Coated Symmetry C_8 Column[J];Chinese Journal of Chromatography;2004-04
7 HUANG Han-rong,PAN Jiang,XU Yi,XU Jian-he(Laboratory of Biocatalysis and Bioprocessing,State Key Laboratory of Bioreactor Engineering,East China Universityof Science and Technology,Shanghai 200237,China);Preparation of (S)-mandelic acid and its derivatives by enantioselective degradation of racemic mandelates with Pseudomonas putida CGMCC1388[J];Chinese Journal of Bioprocess Engineering;2005-03
8 TANG Ke-Wen*,1 CHEN Guo-Bin1 ZHOU Chun-Shan2(1Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414000)(2College of Chemistry and Chemical Engineering, Central South University, Changsha 410083);Enantioselective Separation of Mandelic Acid Enantiomers by Chiral Ligand[J];Chinese Journal of Inorganic Chemistry;2004-03
9 TANG Ke-Wen a,b*, ZHOU Chun-Shan b ( aDepartment of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology,Yueyang 414000; bCollege of Chemistry and Chemical Engineering,Central South University,Changsha 410083);Enantioselective Separation of Racemic Mandelic Acid by Chiral Extraction with Lipophilic L-Tartaric Esters[J];Chinese Journal of Applied Chemistry;2003-11
【Secondary References】
Chinese Journal Full-text Database 2 Hits
1 Wang Zhen,Chen Xiaoqing,Jiao Feipeng,Yang Ling,Li Yisheng(College of Chemistry and Chemical Engineering,Central South University,Changsha 410083);Enantioseparation of Mandelic Acid Enantiomers by Co-extractants with Di(2-ethylhexyl)phosphoric Acid and Tartaric Acid Derivatives[J];Chemistry;2009-06
2 Lei Shuangshuang,Yang Xi,Shen Jingru,Lu Jianjie(Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission,College of Chemistry and Materials Science,South-Central University for Nationalities,Wuhan 430074,China);Application of New β-Cyclodextrin Derivative for Separation of Mandelic Acid by High Performance Capillary Electrophoresis[J];Journal of South-Central University for Nationalities(Natural Science Edition);2008-01
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 Li Ning, Chen Qirui, Pang Kaiqi (Shenyang College of Pharmacy);The Effect of a New Electrolysis Mode on Asymmetric Reduction of Acetophenone[J];Chemical Research In Chinese Universities;1989-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved