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《Journal of Chemical Industry and Engineering(China)》 2002-05
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INTRINSIC KINETICS OF CATALYTIC HYDROGENATION OF ROSIN ON RANEY NICKEL

CHEN Xiaopeng, WANG Linlin, YANG Chengli and DUAN Wengui (College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004,Guangxi, China)  
The intrinsic kinetics of catalytic hydrogenation of rosin on Raney nickel was investigated at temperature 423 K to 453 K and under pressure 4 0 MPa to 7 0 MPa. Gas hold-up and reaction in autoclaves with different types of stirrers were determined. The result showed that the catalytic hydrogenation of rosin on Raney nickel is a reaction of external diffusion control. The external diffusion effect was eliminated by adding No 200 solvent oil, changing stirrer type and increasing rotational speed. Based on the experimental results, a suitable reaction model was selected from 17 probable reaction mechanism models, i e the main component abietic-acid in rosin is not absorbed and absorption of atomic hydrogen with reaction between atomically absorbed hydrogen on catalyst surface and abietic-acid could be the controlling step. The intrinsic kinetic equation was acquired. It is useful to provide a theoretical basis for the development of industrial process.
【Fund】: 国家自然科学基金资助项目 (No 2 97660 0 2 );; 广西自然科学基金资助项目 (桂科配 982 40 0 6)~~
【CateGory Index】: O643.38
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【References】
Chinese Journal Full-text Database 6 Hits
1 CHEN Xiao-peng, WANG Lin-lin, YANG Cheng-li, ZHANG Dong-yun, Tong Zhang-fa (College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China);Equilibrium Solubility of H_2 in Pine Gum and Rosin at High Pressure[J];Journal of Chemical Engineering of Chinese Universities;2003-03
2 Zhu Yuanjiao Chen Xiaopeng Wang Linlin Yang Chengli~* Tong Zhangfa(College of Chemistry and Chemical-Engineering,Guangxi University,Guangxi Nanning 530004;*Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080);Preparation and Application of Hydrogenated Rosin[J];Chemical Industry Times;2006-10
3 WANG Linlin1,LI Liming2,CHEN Xiaopeng1,PU Xiaodong1,TONG Zhangfa1 (1School of Chemistry and Chemical Engineering; 2Business School, Guangxi University,Nanning 530004,Guangxi,China);Lumping kinetic model for catalytic disproportionation of rosin on Pd/C[J];Journal of Chemical Industry and Engineering(China);2007-02
4 CHEN Xiao peng, WANG Lin lin, YANG Cheng li, MA Jian, ZHU Yuan jiao, WEI Xiao jie (College of Chemistry and Chemical Engineering, Guangxi University, Guangxi Nanning 530004, China);Study on Catalytic Hydrogenation of Rosin at Low Pressure[J];Huaxue Shijie (Chemical World);2003-06
5 CHEN Xiao peng,WANG Lin lin,YANG Cheng li,ZHU Yuan jiao,WEI Xiao jie (College of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China);Catalytic Hydrogenation of Pine Gum to Hydrogenated Rosin and Pinane of High Cis-trans Ratio[J];Fine Chemicals;2002-11
6 CHEN Xiao-peng, WANG Lin-lin, ZHU Yan-jiao, ZHANG Dong-yun, WEI Xiao-jie(College of Chemistry and Chemical-Engineering, Guangxi University, Nanning530004, China);VOLUMETRIC MASS TRANSFER COEFFICIENT OF H_2 IN PINE GUM AND ROSIN[J];Journal of Fuel Chemistry and Technology;2003-06
【Citations】
Chinese Journal Full-text Database 6 Hits
1 ZHANG Dong yun 1, CHEN Xiao peng 1, LI Bo 1, LI Gang 2 (1.College of Chemistry and Chemical Engineering,Guangxi University, Nanning 530004,China; 2.College of Electrical Engineering,Guangxi University,Nanning 530004,China);Comput control system in high-pressure hydrogenation experiment[J];JOURNAL OF GUANGXI UNIVERSITY;2000-01
2 Chen Rongfu Gu Qiwei (East China Institute of Chemical Technology);A STUDY ON THE INTRINSIC KINETICS OF CATALYTIC HYDROGENATION OF 1,4-BUTYNEDIOL TO 1,4-BUTANEDIOL BY RANEY NICKEL CATALYST[J];Chemical Reaction Engineering and Technology;1988-02
3 CHEN Xiao peng, WANG Lin lin, MA Jian, YANG Cheng li (College of Chemistry and Chemical Engineering,Guangxi University,Nanning 53004,China);STUDY ON HYDROGENATED ROSIN PREPARATION CATALYZED BY RANEY′S NICKEL[J];Journal of Chemical Industry of Forest Products(Bimonthly);2001-06
4 Zhang Yunming; Tan Yaxian; Chen Xiaopeng; Zhou Yonghong(Research Institute of Organic Chemistry and Chemical Engineering of Guangxi University,Nanning 530004);STUDY ON HYDROGENATION REACTIONS OF PINE GUM LIQUOR[J];CHEMISTRY AND INDUSTRY OF FOREST PRODUCTS;1995-03
5 Yuan Xianyou (Lingling Teachers College,Hunan Yongzhou 425000) Yin Dulin Li Qianhe (Institute of Fine Catalysis and Synthesis,Hunan Normal University Changsha 410081);STUDY ON THE CATALYSIS OF FAUJUSITE IN FINE ORGANIC SYNTHESIS (XIII) ——Acetalization of Citral with 1,2 Propanediol Catalyzed by Dealuminated USY[J];CHEMISTRY AND INDUSTRY OF FOREST PRODUCTS;1997-03
6 DUAN Wen gui 1, CHEN Xiao peng 1, WANG Lin lin 1, DENG Shuang 1, ZHOU Yong hong 2, AN Xin nan 3 (1 College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China; 2 Industrial Testing and Experimental Center,;Analysis of Main Chemical Composition in Hydrogenated Rosin from Zhuzhou[J];Chinese Journal of Chromatography;2001-01
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 FENG Guang-zhu,ZHU Chun-shan (Department of Chemistry and Chemical Engineering,Zhengzhou Institute of Technology,Zhengzhou450052,China);Preparation and performance of disproportionated rosinoyl sarcosine[J];China Surfactant Detergent & Cosmetics;2004-01
2 ZHANG Shudong,LEI Yuanjin,LIU Xiaorong,GU Yongwan,PAN Zaifu(Kunming Institute of Precious Metals,Kunming,Yunnan 650221,China);Study on Preparation of Pd/C Catalyst with Palladium(Ⅱ)Acetylacetonate as Precursor[J];Precious Metals;2006-02
3 TAN Pei1,2,WU Zhi-Gao2(1.College of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China;2.Department of Petroleum and Chemistry Engineering,Guangxi Vocational & Technical Institute of Industry,Nanning 530001,China);Review on Test Methods of Rosin and its modified Products[J];Technology & Development of Chemical Industry;2007-05
4 WU Zhi-Gao1,TAN Bo2(1.Guangxi Vocational & Technical Institute of Industry,Nanning 530001,China;2 Guangxi Research Institute of Chemical Industry,Nanning 530001,China);Production and Application of Hydrogenated Rosin and Hydrogenated Rosin Glycerin[J];Technology & Development of Chemical Industry;2008-09
5 YANG Cheng-li, CHEN Xiao-peng, WANG Lin-lin, LIN Jie, TONG Zhang-fa (College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China);The Intrinsic Kinetics of Catalytic Hydrogenation of Rosin Using Pd/C Catalyst[J];Journal of Chemical Engineering of Chinese Universities;2003-01
6 WANG Lin-lin,SUN Wen-jing,CHEN Xiao-peng,HU Xiong-guang,TONG Zhang-fa(School of Chemistry and Chemical-Engineering,Guangxi University,Nanning 530004,China);Study on Catalytic Disproportionation of Pine Gum over Pd/C[J];Journal of Chemical Engineering of Chinese Universities;2007-05
7 CHEN Xiao-peng, WANG Lin-lin, WEI Xiao-jie, ZHU Yuan-jiao, ZHANG Dong-yun, LIN Jie (College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China);Study on experimental equipment for catalytic hydrogenation of rosin[J];Journal of Guangxi University(Natural Science Edition);2004-02
8 Zhu Yuanjiao Chen Xiaopeng Wang Linlin Yang Chengli~* Tong Zhangfa(College of Chemistry and Chemical-Engineering,Guangxi University,Guangxi Nanning 530004;*Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080);Preparation and Application of Hydrogenated Rosin[J];Chemical Industry Times;2006-10
9 Ruan Fuxian1 Zhou Longchang2(1.China Academy of Science and Technology Development Guangxi Branch,Guangxi Nanning 530022;2.College of Chemistry and Chemical-Engineering,Guangxi University,Guangxi Nanning,530004);Preparation and Application of Disproportionated Rosin[J];Chemical Industry Times;2008-08
10 WANG Linlin1,LI Liming2,CHEN Xiaopeng1,PU Xiaodong1,TONG Zhangfa1 (1School of Chemistry and Chemical Engineering; 2Business School, Guangxi University,Nanning 530004,Guangxi,China);Lumping kinetic model for catalytic disproportionation of rosin on Pd/C[J];Journal of Chemical Industry and Engineering(China);2007-02
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 ZHU Jinhong 1, LIU Jing 1* , ZHAO Wenjiang 1, WANG Xiangsheng 1, LIU Xiumei 2, BAO Xinhe 2(1 State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, Liaoning, China; 2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China);Synthesis and Characterization of Al-MSU-S Mesoporous and Meso-Microporous Molecular Sieves and Their Catalytic Performance[J];Chinese Journal of Catalysis;2004-09
2 CHEN Yangying, HAN Xiuwen, BAO Xinhe~*(State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics,The Chinese Academy of Sciences, Dalian 116023, Liaoning, China);Direct Synthesis of W-SBA-15 Mesoporous Molecular Sieves and Their Catalytic Performance for Epoxidation of Cyclohexene[J];Chinese Journal of Catalysis;2005-05
3 CUI Yuehua,XU Hengyong~*,GE Qingjie,BI Yadong,WANG Yuzhong,HOU Shoufu,LI Wenzhao(Dalian Institute of Chemical Physics,The Chinese Academy of Sciences,Dalian 116023,Liaoning,China);High Temperature Desorbed Hydrogen in Ni/La_2O_3/α-Al_2O_3 Improves the Initial Reaction Rate of CH_4/CO_2 Reforming[J];Chinese Journal of Catalysis;2006-08
4 Zhao, Xiu-song; Wang, Qing-xia; Xu, Long-Ya; Xie, Su-juan(Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023)and Li, Xin-sheng(State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics,Chinese Academy of Science;THE NOVEL MESOPOROUS MATERIAL MCM-41 I.Synthesis, Acidity and Stability[J];CHINESE JOURNAL OF CATAL YSIS;1995-05
5 Song Ye(Northeast ForestryUniversity Harbin 150040. P. R. China); Lu An(Harbin Light Industry institute); Wang Yufeng; HaoWanrong(Northeast Forestry University)Journal of Northeast Forestry University. - 1999, 27(5). - 40 ~ 42;Study on Heterogeneous Phase Catalysis Process to Synthesize Rosin Ester with Solid Supper-acidCatalyst(I): Preparation and Activity of Catalyst of ZT-1(TiO_2/SO_4~(2-))[J];JOURNAL OF NORTHEAST FORESTRY UNIVERSITY;1999-05
6 LI Wen xia * (Department of Material Engineering Beijing Institute of Clothing, Beijing, 100029) YAN Bao zhen, JIAO Shu ke (Beijing University of Chemical Technology, 100029);Derivative Spectrophotometric Determination of Resin Acid Isomer in Disproportionated Rosin[J];Journal of Analytical Science;2001-03
7 Fu Ruo-nong (Department of (Chemistry) Beijing Institute of Technoligy, Beijing 100081);Advances on gas chromatography in China in recent two years[J];Analytical Laboratory;2005-04
8 HUANG Qi-wei, ZHANG Shi-ying(Department of Applied Chemistry and Environmental Science, Changsha University, Changsha 410003, China);Studies on Esterification Reactions of Carboxylic Acids over Silicoaluminophosphate Molecular Sieve Catalysts[J];Journal of Molecular Catalysis;2003-06
9 SHEN Bao-jian~*, REN Shen-yong, GUO Qiao-xiaoalysis of CNPC, University of Petroleum, Beijing 102249, China);Covalent Grafting of Zirconocene Dichloride Moiety on MCM-41[J];Journal of Molecular Catalysis;2004-02
10 LI Qing-hua, LIU Yun-qi, LIU Chun-ying, LIU Chen-guang a);Cyclohexane Hydroconversion on Pt/HY-Al_2O_3 Catalysts[J];Journal of Molecular Catalysis;2004-05
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 Lin Jie (Department of Chemical Engineering, Maoming Vocational and Technical College, Maoming 525000, China);Study on the Optimal Process Condition of Producing Hydrogenated Rosin from Pine Gum[J];Guangdong Chemical Industry;2009-06
2 TAN Pei1,2,WU Zhi-Gao2(1.College of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China;2.Department of Petroleum and Chemistry Engineering,Guangxi Vocational & Technical Institute of Industry,Nanning 530001,China);Review on Test Methods of Rosin and its modified Products[J];Technology & Development of Chemical Industry;2007-05
3 CHEN Xiao-peng, WANG Lin-lin, YANG Cheng-li, ZHANG Dong-yun, Tong Zhang-fa (College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China);Equilibrium Solubility of H_2 in Pine Gum and Rosin at High Pressure[J];Journal of Chemical Engineering of Chinese Universities;2003-03
4 SONG Huai-jun1,2, ZHANG Hai-tao1, YING Wei-yong1 (1. College of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China; 2. College of Chemical Engineering, Zhengzhou University, Zhengzhou 450002, China);Study on Solubility and Volumetric Mass Transfer Coefficient of Dimethyl Ether in Liquid Paraffin[J];Journal of Chemical Engineering of Chinese Universities;2005-02
5 Zhu Yuanjiao Chen Xiaopeng Wang Linlin Yang Chengli~* Tong Zhangfa(College of Chemistry and Chemical-Engineering,Guangxi University,Guangxi Nanning 530004;*Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080);Preparation and Application of Hydrogenated Rosin[J];Chemical Industry Times;2006-10
6 Ruan Fuxian1 Zhou Longchang2(1.China Academy of Science and Technology Development Guangxi Branch,Guangxi Nanning 530022;2.College of Chemistry and Chemical-Engineering,Guangxi University,Guangxi Nanning,530004);Preparation and Application of Disproportionated Rosin[J];Chemical Industry Times;2008-08
7 ZHU Yuan-jiao1,CHEN Xiao-peng1,WANG Lin-lin1,YANG Cheng-li2,TONG Zhang-fa1(1.College of Chemistry and Chemical-Engineering,Guangxi University,Nanning,530004,China; 2.Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China);Mechanism of catalytic hydrogenation reaction of rosin by Pd/C catalyst[J];Chemical Research and Application;2007-02
8 SHI Xiao-jie,JIANG Li-hong,MIU Ying-ju,ZHANG Si-hua,WANG Ya-ming(Institute of Chemical Engineering,Kunming University of Science and Technology,Kunming 650224,China);Development of catalyst applied to modified rosin[J];Science & Technology in Chemical Industry;2008-02
9 WANG Lin-lin,XU Xu,CHEN Xiao-peng,CHEN Zu-fen,SUN Wen-jing,TONG Zhang-fa(School of Chemistry and Chemical-Engineering,Guangxi University,Nanning 530004,Guangxi,China);Analysis of Chemical Constituents in the Reaction Products of Catalytic Thermal Isomerization of Turpentine by GC-MS[J];Fine Chemicals;2007-12
10 Zhu Tianxing Ling Kaicheng Shen Jun Wang Yingchun and Zhang Haijun(College of Chemistry and Chemical Engineering,Taiyuan University of Technology,030024 Taiyuan);SOLUBILITIES OF HYDROGEN IN COAL LIQUEFIED OIL[J];Coal Conversion;2006-03
【Secondary Citations】
Chinese Journal Full-text Database 3 Hits
1 ZHANG Dong yun 1, CHEN Xiao peng 1, LI Bo 1, LI Gang 2 (1.College of Chemistry and Chemical Engineering,Guangxi University, Nanning 530004,China; 2.College of Electrical Engineering,Guangxi University,Nanning 530004,China);Comput control system in high-pressure hydrogenation experiment[J];JOURNAL OF GUANGXI UNIVERSITY;2000-01
2 Zhao Shou-pu Chen Yuan-xun Soong Zhanchian Liu Han-chao (Research Institute of Chemical Processing and Utilization of Forest Products, Chinese Academy Forestry);REPORT OF A PILOT SCALE EXPERIMENT ON CONTINUOUS HYDROGENATION OF ROSIN[J];Chemistry & Industry of Forest Products;1981-01
3 Yuan Xianyou (Lingling Teachers College,Hunan Yongzhou 425000) Yin Dulin Li Qianhe (Institute of Fine Catalysis and Synthesis,Hunan Normal University Changsha 410081);STUDY ON THE CATALYSIS OF FAUJUSITE IN FINE ORGANIC SYNTHESIS (XIII) ——Acetalization of Citral with 1,2 Propanediol Catalyzed by Dealuminated USY[J];CHEMISTRY AND INDUSTRY OF FOREST PRODUCTS;1997-03
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