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《Journal of Chemical Industry and Engineering(China)》 2005-11
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Measurement and correlation of solubility of carbon monoxideand other gases solubility in phenol

ZHANG Guangxu~(1,2),WU Yuanxin~1,MA Peisheng~(2),WU Guangwen~(1,2) ,LI Dinghuo~1(~(1)Department of Chemical Engineering,Wuhan Institute of Chemical Technology,Wuhan 430074, Hubei, China;()~2School of Chemical Engineering and Technology, Tianjin University,Tianjin 300072,China)  
A new instrument of measuring gas solubility was developed,and the solubility values of carbon monoxide, oxygen and other gases in phenol were measured respectively within temperature range of 55 to 95 ℃ and pressure range of 1.00 to 8.00 MPa.The results showed that the solubility values of carbon dioxide decreased with rising temperature,but the case was reversed for carbon monoxide, oxygen and nitrogen.By using the regular-solution theory and the virial expansion for the Redlich-Kwong equation of state, an equation was proposed to relate the solubility values of the gases in the non-volatile solvent to temperature and pressure.The equations used to correlate the high-pressure gas solubility values of carbon monoxide,oxygen and nitrogen in phenol at various temperatures were accurate.
【Fund】: 国家自然科学基金项目(20476083).~~
【CateGory Index】: O645
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