Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Chemical Industry and Engineering(China)》 2007-04
Add to Favorite Get Latest Update

Coupling reaction of formaldehyde and methyl formate over sodium bisulfate catalyst

WANG Kebing1,2,YAO Jie1,LEI Yongcheng1,WANG Yue1,WANG Gongying1(1Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu 61004l,Sichuan,China;2Graduate School of Chinese Academy of Sciences,Beijing 100039,China)  
The coupling reaction of formaldehyde (FA) and methyl formate (MF) with solid sodium bisulfate catalyst was investigated in an autoclave.The effects of reaction temperature,reactants ratio,catalyst dosage and reaction time on the yields of methyl glycolate (MG) and methyl methoxy acetate (MMAc) were examined.Under optimal reaction conditions:formaldehyde 1.08 mol,methyl formate 1.66 mol,sodium bisulfate 0.24 mol,reaction temperature 160℃,reaction time 4 h,the overall yield of MG and MMAc was 42.15%.The catalyst could be easily recovered and reused,and had very good activity and stability.The reaction process was confirmed and the performance of sodium bisulfate catalyst was also compared with other acid catalysts.The catalytic activity of sodium bisulfate catalyst was higher than others.
【CateGory Index】: TQ032.4
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 Xiang Dongsheng, Zhu Xun (Department of Chemistry Engineer Yancheng Textile Vocational Technology Yancheng 224005);Coupling Reaction of Formaldehyde and Methyl Formate over Zeolite Hβ Catalyst[J];China Chemicals;2008-04
【Citations】
Chinese Journal Full-text Database 4 Hits
1 Bai Liang;Zhao Yulong;Zhong Bing;Peng Shaoyi(Institute of Coal Chemistry,Chinese Academy of Sciences State Key Laboratory of Coal Conversion,Taiyuan);SOLUBILITIES OF H_2,CO IN METHANOL AND METHYL FORMATE IN A SURFACE-AERATED AGITATED REACTOR[J];JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY;1996-06
2 Li Bengao, Wang Zheng, Li Yahong (Water Treeting Center of SINOPEC, Beijing 100083);HARMFULNESS OF LEAKED SUBSTANCE FROM PETROCHEMICAL UNITS ON CIRCULATING WATER TREATMENT[J];Petroleum Processing and Petrochemicals;2001-02
3 WANG Ke-bing~(1,2),WANG Gong-ying~1(1.Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu 610041,China;2.Graduate School,Chinese Academy of Sciences,Beijing 100039,China);Progress in synthesis of ethylene glycol through non-petroleum routes[J];Modern Chemical Industry;2005-S1
4 QI Wei dong 1,LI Zhi feng 2,CHEN Liang 2 (1 Yunnan Research Institute of Chemical Industry, Kunming 650041,China; 2 School of Biology and Chemical Engineering, Kunming University of Science & Technology, Kunming 650093,China);Progress on the Synthesis of Methyl Glycolate by Formaldehyde and Methyl Formate[J];Yunnan Chemical Technology;2002-04
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 LIU Lei1,DANG Jian2,REN Run-bao1(1.The Technology Monitoring Center of Tu Ha oil field,Xinjiang Shanshan 838202,China);A research of the monitoring system for the leakage of heat exchanger[J];Electronic Instrumentation Customer;2009-02
2 WANG Ke-bing1,2,YAO Jie1,WANG Yue1,WANG Gong-ying1(1.Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences, Chengdu Sichuan 610041,China;2.Graduate School of Chinese Academy of Sciences,Beijing 100039,China);Analysis of Process for the Coupling Reaction of Trioxane and Methyl Formate with Acid Catalyst[J];Journal of Molecular Catalysis;2007-03
3 LU Zhaohui,ZHAO Liangfu,ZHAO Yulong and ZHANG Kai (Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,Shanxi,China);MATHEMATICAL MODELING OF LOW-TEMPERATURE LIQUID PHASE METHANOL SYNTHESIS PROCESS IN A BUBBLE SLURRY REACTOR[J];Journal of Chemical Industry and Engineering(China);2001-04
4 ZHANG Guangxu~(1,2),WU Yuanxin~1,MA Peisheng~(2),WU Guangwen~(1,2) ,LI Dinghuo~1(~(1)Department of Chemical Engineering,Wuhan Institute of Chemical Technology,Wuhan 430074, Hubei, China;()~2School of Chemical Engineering and Technology, Tianjin University,Tianjin 300072,China);Measurement and correlation of solubility of carbon monoxideand other gases solubility in phenol[J];Journal of Chemical Industry and Engineering(China);2005-11
5 Xiang Dongsheng, Zhu Xun (Department of Chemistry Engineer Yancheng Textile Vocational Technology Yancheng 224005);Coupling Reaction of Formaldehyde and Methyl Formate over Zeolite Hβ Catalyst[J];China Chemicals;2008-04
6 He Jun-hai, Huang Ji-yue, Shi Ming-yan, Qi Xiang-yang, Liu Gao-bo (1.Research Instiute of Liaoyang Petrochemical Company, PetroChina, Liaoyang 111003, Liaoning, China; 2. Aromatic Plant of Liaoyang Petrochemical Company, PetroChina, Liaoyang 111003, Liaoning, China);Advances of Ethylene Glycol Synthesizing Process[J];Fine Chemical Industrial Raw Materials & Intermediates;2008-11
7 Zhu Yongjian Xu Anyang (College of Chemical Engineering,Qingdao University of Science and Technology,Qingdao 266032);Research Progress in Synthesis of Ethylene Glycol by Way of Coal or Natural Gas[J];Advances in Fine Petrochemicals;2007-08
8 CHEN Liang1, NING Ping1, ZHANG Jiang-hong2, CHEN Yun-hua1, Wan Rong-hui3 (1.Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2.Faculty of Science, Kunming University of Science and Technology, Kunming 650093, China; 3.Yunnan Jianglin Group Co. Ltd., Jiangchuan,Yunnan 652600, China);Synthesizing Methyl Formate by Methanol Carbonylation Using DMF Promoter[J];Journal of Kunming University of Science and Technology;2005-01
9 LI Xinzhu,Chen Yao and Chen Jiqiang(Technology Development Center,Hongri Acron Chemical Co.,Ltd.,Linyi 276021);Progress in the Synthesis of Ethylene Glycol through Coal Chemical Industry Route[J];Coal Chemical Industry;2007-03
10 SU Xing-ye1,2,LI Zhi-yi1,JIN Yan3(1.R&D Institute of Fluid and Powder Engineering,Dalian University of Technology,Dalian 116012,China;2.Shenyang University of Technology Liaoyang Campus,Liaoyang 111003,China;3.School of Mechanic and Automation,Dalian Institute of Light Industry,Dalian 116012,China;Design of an Online Monitoring System Based on Electrochemical Sensor for Oil Leakage in Circling Water Systems[J];Journal of Agricultural Mechanization Research;2006-05
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 QIAN Hua,YE Zhi-wen,Lü Chun-xu (School of Chemical and Engineering,Nanjing University of Science and Technology,Nanjing 210094,China);HZSM-5 Assisted Clean Nitration of Toluene with Dinitrogen Pentoxide[J];Chinese Journal of Explosives & Propellants;2006-05
2 Lu Chunxu;Cai Chun(Nanjing University of Science & Technology);INVESTIGATION ON A NITRATING AGENT CONSISTING OFMETALLIC NITRATES AND ACETIC ANHYDRIDE[J];Acta Armamentarii;1994-02
3 Guo Can-xiong 1 Luo Chun-dan 1 Zhang Qiang 2 (1.College of Science, Beijing University of Chemical Technology, Beijing 100029; 2.School of Science, Beijing Institute of Technology, Beijing 100084, China);Catalytic para-selective nitration of toluene with NO_2 over zeolite beta[J];Journal of Beijing University of Chemical Technology;2004-06
4 XIE Fu-sheng ZHANG Jin-chang LI Cheng-yue(The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry ofEducation, Beijing University of Chemical Technology, Beijing 100029, China);Investigation of reaction conditions in synthesis of linear alkylbenzene using supported heteropoly acid in a fixed-bed reactor[J];Journal of Beijing University of Chemical Technology;2005-02
5 WEN Rui-ming LUO Xin-xiang YOU Pei-qing YU Shan-xin (Department of Chemistry,Hunan City University,Yiyang,Hunan 413049);Catalytic Synthesis of Ethyl Cinnamate with Sodium Bisulfate[J];Journal of Changde Teachers University;2003-01
6 Gao Zi; Yang, Xiao-bo and Gao, Guang-ye(Department of Chemistry, Fudan University, Shanghai 200433);NITRATION OF TOLUENE ON SOLID ACID CATALYSTS[J];CHINESE JOURNAL OF CATAL YSIS;1994-06
7 ZHANG Xiao-ni~1, HE Shi-zhong~2, ZHANG Xi-wen~3, WEN Shou-bin~4 ( 1. Daqing Normal University, Daqing, Heilongjiang 163712, China; 2. Educational Administration, Daqing Vocation College, Daqing, Heilongjiang 163255, China 3. Xinli Oil Recovery Plant, Jilin Oilfield Corp. Ltd., Songyuan, Jilin 138004, China; 4. Petroleum Engineering College, Daqing Petroleum Institute, Daqing, Heilongjiang 163318, China );Effect of H_3PMo_(12)O_(40) on catalytic visbreaking of heavy oil from alax in Daqing peripheral oilfields[J];Journal of Daqing Petroleum Institute;2005-04
8 LIN Wanzhen,XU Daoxuan,ZHAO Chongtao(College of Chemistry and Materials Science,Fujian Normal University, Fuzhou350007,China);Synthesis of Butyl Isovalerate Using Sodium Bisulphate as Catalyst[J];Journal of Fujian Normal University(Natural Science);2003-03
9 MAO Xuan, YIN Yuan\|qi (State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000) WANG Hao, ZHONG Bang\|ke (Department of Chemistry, Jinan University, Guangzhou 510632);Heteropolyacid Catalysts for Selective Oxidation of Propene to Acrylic acid[J];Journal of Molecular Catalysis (China);2000-05
10 YANG Shui\|jin, YU Xie\|qing, LIANG Yong\|guang (Department of Chemistry, Hubei Normal University, Huangshi 435002, China);Synthesis of Benzoates Using TiSiW_(12)O_(40)/TiO_2 Catalyst[J];Journal of Molecular Catalysis (China);2001-06
【Secondary Citations】
Chinese Journal Full-text Database 7 Hits
1 ZHAO Xiuge, L Xinglong, ZHAO Honggang, ZHU Yuqun, XIAO Wende *(UNILAB Research Center of Chemical Reaction Engineering, East China University of Science and Technology, Shanghai 200237, China);Study on Pd/α-Al_2O_3 Catalyst for Vapor-Phase Coupling Reaction of CO with CH_3ONO to (CH_3OOC)_2[J];Chinese Journal of Catalysis;2004-02
2 Li Zhuxia Qian Zhigang Zhao Xiuge Xiao Wende (UNILAB Research Center of Chemical Reaction Engineering, ECUST, Shanghai 200237, China);Studies on Hydrogenation of Dimethyl Oxalate on Cu/SiO_2 Catalyst[J];Chemical Reaction Engineering and Technology;2004-02
3 Du Bilin; Chu Wei; Yu Zuolong(Chengdu Institute of Organic Chemistry, the Chinese Academy of Sciences 610041);Preparation of Methyl Glycolate and Development of Its Derivative Products[J];Coal Chemical Industry;1999-01
4 Chen Dongliang; Chu Wei, et al.(Chengdu Institute of Organic Chemistry, the Chinese Acadcmy of SciencesCEOG, 1999,28 (1);Studies on the Synergetic Effect of Solid Superacid and Protonic Acid for the Synthesis of Methyl Glycolat[J];CHEMICAL ENGINEERING OF OIL AND GAS;1999-01
5 Chen Dongliang,Qu Meizhen,Bai Yuxin,Du Bilin,Chu Wei,Yu Zuolong(Chengdu Institute of Organic Chemistry, the Chinese Academy of Sciences) [WT5,5”HZ];STUDIES ON THE H~+ CATALYSIS FOR THE SYNTHESIS OF METHYL GLYCOLATE[J];Chemical Engineering of Oil and Gas;2002-02
6 Du Bilin Chu Wei Yu Zuolong (Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041);Synthesis of methyl glycolate by coupling of methyl formate with trioxane Ⅱ.Effect of sulfuric acid and metal carbonyl[J];Natural Gas Chemical Industry;1998-03
7 Du Bilin, Chu Wei, Yu Zuolong (Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041);Synthesis of methyl glycolate by coupling methyl formate with trioxane Ⅲ.Exploration of carbonyl reaction mechanism[J];Natural Gas Chemical Industry;1998-05
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved