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《Journal of the Chemical Industry and Engineering Society of China》 2009-06
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Surface functionalization of polyurethane for medicine and blood compatibility:role of H_2O

ZHOU Xuefeng,JIANG Xiaoli,GU Ning(School of Biological Science and Medical Engineering,Southeast University,Nanjing 210096,Jiangsu,China;Suzhou Key Laboratory of Biomaterial and Technology,Suzhou 215123,Jiangsu,China)  
Interaction of surface with water plays a key role in the blood compatibility of biomedical material.In this article,the research progress in hydrophilic functionalization for the surface of medical polyurethane as the typical model of biomedical polymer was reviewed,and the functions of water to block nonspecific adsorption of blood proteins and the formation of thrombosis were also discussed.The behavior of water molecules and their effect on the blood compatibility of the modified polyurethane,functionalized by the active materials such as hydrophilic vinyl monomer,polyethylene glycol and its derivates,heparin and zwitterionic materials,was explored.The knowledge of the functionalities of water and hydration layer during the interactions between blood and biomedical materials would benefit surface design and application of biocompatible polymer.
【Fund】: 科技部国际科技合作项目(2008DFA51180);; 国家重大科学研究计划项目子课题(2006CB933206 2006CB705602);; 国家自然科学基金杰出青年基金项目(60725101)~~
【CateGory Index】: R318.08
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