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《New Chemical Materials》 2008-06
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Study on graft of methyl methacrylate on silicone rubber by co-irradiation

Suo Jinxuan~(1,2) Luo Shikai~2 Zhang Changsheng~2 Li Xiaoyan~3(1.Institute of Materials Science and Engineering,Southwest University of Science andTechnology,Mianyang 621010;2.Chinese Academy of Engineering and Physics,Mianyang 621900;3.Sichuan Sciencel Cobalt Source Co.Ltd,Mianyang 621900)  
The graft polymerization of methyl methacrylate(MMA) on silicone rubber under irradiation of 60Co γ-rays was described.The effects of irradiation dose,monomer concentration,dose rate and solvents on grafting were discused.The structure and properties of graft copolymer were studied by FT-IR,DSC and contact angle measurement.The result showed that the dose and monomer concentration had a great effect on the grafting reaction,the optimum grafting effcet of the graft copolymer was obtain when 20kGy and m(MMA)/m(SR)=0.6;the heat performance and hydrophilicity of silicone rubber were improved after being grafted.
【Fund】: 中物院化工材料研究所所长基金资助课题(No:62601080315)
【CateGory Index】: TQ333.93
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