Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《The Chinese Journal of Process Engineering》 2008-06
Add to Favorite Get Latest Update

Preparation of Bio-diesel from Jatropha curcas Oil by Transesterification with Solid Acid Catalysts

SUN Jin-feng, REN Tian-rui, XUE Si-jia (College of Life and Environmental Sciences, Shanghai Normal University, Shanghai 200234, China)  
Transesterification of Jatropha curcas oil was carried out in the presence of solid acid, the effects of types of catalysts and reaction conditions on the bio-diesel yields and the components in the process of the preparation of methyl esters (bio-diesel) were examined. Solid acid catalysts ZrO2-SO42- and K4Zn4[Fe(CN)6]3 were prepared with precipitation. Their structures and characteristics identified by XRD, FT-IR, BET and elemental analysis were compared. Their catalytic activities changed with acid value and reaction temperature. The detail components of the bio-diesel production were analyzed by GC-MS. The results showed that the ZrO2-SO42- lost its catalytic activity in high acid value Jatropha curcas oil. The yield of methyl ester declined to 84%. Otherwise, K4Zn4[Fe(CN)6]3 remained its good catalytic activity and stability. The yield of methyl ester was 93%. After it was used five times, the yield of methyl ester still reached 90%.
【Fund】: 国家“十一五”科技支撑基金资助项目(编号:2006BAE01A07-10);; 国家高技术研究发展计划(863)基金资助项目(编号:2006AA100204)
【CateGory Index】: TE667
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 XU Gui-zhuan et al(Mechanical and Electrical Engineering College of Henan Agricultural University,Key Laboratory of Renewable Energy of Ministry of Agriculture,Zhengzhou,Henan 450002);Research Development of Solid Catalysts for Biodiesel Production[J];Journal of Anhui Agricultural Sciences;2009-28
【Citations】
Chinese Journal Full-text Database 2 Hits
1 WU Guo-ying, LIN Xi-ping, WU Miao-xin, WANG Lin, ZHOU Ya-jun (Jiangsu Key Lab of Finechemical Technology,Jiangsu Polytechnic University, Changzhou 213016, China);Kinetics of Cottonseed Oil Transesterification in a Batch Reactor[J];Journal of Chemical Engineering of Chinese Universities;2003-03
2 CHEN He,WANG Jin-fu(Department of Chemical Engineering,Tsinghua University,Beijing 100084,China);Biodiesel Preparation from Transesterification of Cotton Seed Oil by Solid Acids Catalysis[J];The Chinese Journal of Process Engineering;2006-04
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 YAO Jian et al(Department of Chemical Engineering,Jiangsu Polytechnic University,Changzhou,Jiangsu 213164);Formation Kinetics of Bio-diesel Component Prepared by Solid Base Catalysis[J];Journal of Anhui Agricultural Sciences;2008-05
2 LI Shu-min1,2,GUO Hai-fu1,YAN Peng1,WU Yan-ni1,WANG Lan-ying1,2(1.School of Chemistry and Chemical Engineering,Zhaoqing University,Zhaoqing 526061,China;2.College of Chemical Engineering,Inner Mongolia University of Technology,Huhhot 010051,China);Preparation of biodiesel using solid superacid Zr(SO_4)_2/TiO_2 as catalyst[J];China Surfactant Detergent & Cosmetics;2008-03
3 SONG Cheng-cai1,2,QI Yong-qin1,HOU Xiang-lin1(1.Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,China;2.Graduate University of Chinese Academy of Sciences,Beijing 100039,China);Study of fatty acid esterification under subcritical condition[J];China Surfactant Detergent & Cosmetics;2008-04
4 Zhao Guixing (Harbin Business University Starbin 150076;Soybean Research Institute, Heilongjiang Academy of Agricultural Sciences, Harbin 150086);STUDY ON SOYBEAN BIODIESEL PRODUCTION-GREEN LIQUID FUEL[J];Soybean Science;2005-03
5 CHEN Shun-yu,LU Wei,CHEN Denglong,HOU Youde,ZHUO Jianle(1.College of Chemistry and Materials Science,Fujian Normal University,Fujian Fuzhou 350007,China; 2.The Institnte of Fujian Modified Research and Develop Technology,Fujian Fuzhou 350007,China);Advance in Research for Preparation of Biodiesel[J];Journal of Fuqing Branch of Fujian Normal University;2008-02
6 HAN Yi, DENG Yu(College of Material Science and Chemical Engineering, Tianjin University of Science and Technology, Tianjin 300457, China);Development Situation and New Technologies of Biodiesel[J];Technology & Development of Chemical Industry;2007-03
7 SONG Ji-Bin1,YIN Jian-Zhong1,ZHANG Li-Ming1,LI Hui-Rong1,SUN Yuan-Fei2(1.School of Chemical Engineering,Dalian University of Technology,Dalian 16012,China;2.Dalian Petroleum Chemical Company,Dalian 116023,China);Research Development on Biodiesel Production Methods[J];Technology & Development of Chemical Industry;2007-09
8 BAO Peng,YANG En-fang,LI Xiu-mei (National Engineering Research Center for Fine Petrochemical Intermediates,Institute of Chemical Physical,The Chinese Academy of Sciences,Lanzhou 730000,China);Synthesis of Biodiesel with Heterogeneous Catalyst[J];Technology & Development of Chemical Industry;2008-11
9 CHEN Zheng-zhong (Green New Energy Co.,Ltd.,Shanghai 200335,China);Systems Viscosity of Biodiesel Produced with Vegetable Oil[J];Technology & Development of Chemical Industry;2009-03
10 CHEN Zheng-zhong (Green New Energy Co.,Ltd.,Shanghai 200335,China);Study on Production Process of Biodiesel from Olive Oil[J];Technology & Development of Chemical Industry;2009-04
China Proceedings of conference Full-text Database 4 Hits
1 CAO Weiliang1 2, LIU Jin1, LIU Jing1, ZHANG Jingchang1 2* (1. BeiJing University of Chemical Technology, Institute of modern catalyst, 100029 2. HaiNan Institute of Science and Technology, 571126);Synthesis of biodiesel with CO_2 as cosolvent[A];[C];2008
2 Ren Qinggong Yah Jie Qiu Taiqiu~* (College of Light Industry and Food Sciences,South China University of Technology,Guangzhou 510641,China);Advances in Biodiesel production by means of ultrasonically enhanced transesterification[A];[C];2007
3 CAO Wei-liang~(1 2) LIU Jin~1 LIU Jing~1 ZHANG Jing-chang~(1 2*)1.BeiJing University of Chemical Technology,Institute of modern catalyst,100029 2.HaiNan Institute of Science and Technology,571126;Synthesis of biodiesei with CO_2 as cosolvent[A];[C];2008
4 Qian Weiwei,Yang Liang,LU Xiaoping (Institute of Sonochemical Engineering,Nanjing University of Technology,Nanjing 210009,Jiangsu,China);Preparation of biodiesel catalyzed by KF/CaO with ultrasonic[A];[C];2008
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 SONG Hua-min et al(Key Laboratory of Renewable Energy,Ministry of Agriculture of the People's Republic of China,College of Mechanical and Electrical Engineering,Henan Agricultural University,Zhengzhou,Henan 450002);Research Progress on the Preparation of Biodiesel Production by Solid Base Catalyst[J];Journal of Anhui Agricultural Sciences;2008-05
2 CHEN Ying1,SUN Xue1,LI Jinlian1,ZOU Wanli2,LI Jia1,ZHANG Yawen1(1 School of Chemistry and Chemical Engineering,Daqing Petroleum Institute,Daqing 163318,Heilongjiang,China;2 No.4 Oil Production Company,Daqing Oilfield Company Limited,Daqing 163414,Heilongjiang,China);Research progress of biodiesel preparation with solid superacid catalysts[J];Chemical Industry and Engineering Progress;2009-03
3 Liao Weiying, Cai Jianguo, Wang Shiwen (Chemical Engineering Research Institute, East China University of Science and Technology, Shanghai 200237);Progress on Preparation of Diesel oil Solid Catalyst and Its Strengthening Research on the Process[J];Chemical Production and Technology;2008-02
4 CHEN He,WANG Jin-fu(Department of Chemical Engineering,Tsinghua University,Beijing 100084,China);Biodiesel Preparation from Transesterification of Cotton Seed Oil by Solid Acids Catalysis[J];The Chinese Journal of Process Engineering;2006-04
5 Zhang Hairong, Wu Guoying, Lin Xiping (Jiangsu Province Key-laboratory of Fine-petrochemical Technology, JPU. ).;Study of Producing Bio-diesel from Cooking Oils by Solid Acid Catalyst[J];Chemical Engineering of Oil & Gas;2007-02
6 Tian Zhiming1,2, Deng Qigang2, Zhao Defeng1(1.State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian Liaoning 116012,China;2.College of Chemistry and Chemical Engineering of Qiqihar University,Qiqihar Heilongjiang 161006,China);Preparation of SBA-15 Mesoporous Molecular Sieve Modified by Cerium for Catalytic Synthesis of Methyl Palmitate[J];Petrochemical Technology;2007-08
7 YANG Ying(1.Department of Biological and Chemical Engineering,Panzhihua University,Panzhihua Sichuan 617000;2.School of Chemical Engineering,Sichuan University,Chengdu Sichuan 610065);Advances on study of biodiesel preparation[J];Science and Technology of Cereals,Oils and Foods;2007-05
8 XU Shen-min,CHEN Hui,LIANG Bao-chen (School of Chemistry and Chemical Engineering,Tianjin University of Technology,Tianjin 300191,China);Transesterification reaction of waste oil catalyzed by solid base Na_2O/MCM-41[J];Journal of Tianjin University of Technology;2008-02
9 WANG Yang-dong1,LIU Guo-wen2(1.Torch High Technology Industry Development Center,Beijing 100045,China;2.Beijing Feiyan Petrochemical Environmental Protection Technological Development Co.Ltd.,Beijing 102500,China);Study on a new catalyst of solid acid for preparation of bio-diesel from waste oil[J];Modern Chemical Industry;2007-11
10 WU Zhi-peng1,2,ZHOU Yu-jie2,ZHANG Jian-an2,CHENG Ke-ke2, LIU Hong-juan2,DAI Ling-mei3,LIU De-hua3,DI Xiao-wei1(1.School of Chemistry & Chemical Engineering,Inner Mongolia University,Hohhot 010021,China;2.Division of Green Chemistry and Technology,Institute of Nuclear and New Energy Technology,Tsinghua University,Beijing 100084,China;3.Department of Chemical Engineering,Tsinghua University,Beijing 100084,China);Progress in solid acid catalysts for biodiesel production[J];Modern Chemical Industry;2008-S2
【Secondary Citations】
Chinese Journal Full-text Database 3 Hits
1 SHENG Mei, WU Guo-ying, XU Ge, WU Miao-xin (Key Laboratory of Fine Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016,China);Preparation of Biodiesel from Rapeseed Oil[J];Journal of Chemical Engineering of Chinese Universities;2004-02
2 Chen HaisongYu LixinXu HaishengWang LeiLiu Dazhuang(Department of Chemical Engineering, Zhengzhou University of Technology,Zhengzhou 450002);Macrokinetics of Propane Dehydrogenation on CrAl Catalyst Improved by Rareearth Aids[J];JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES;1999-01
3 XIN Yaon-ian,B.Sondermann, B.Emersleben (Cimbria Sket GmbH/Germany and Beijing Office,CITIC Building 2501A,Beijing 100004);Production and Application of Bio Diesel Fuel[J];China Oils and Fats;2001-05
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved