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Semiconductor Photocatalytic Degradation of Anionic Sodium Dodecylbenzenesulphonate in Aqueous Solutions

Jiang Weichuan and Wang Qiquan(Dept. of Chemistry, Zhejiang University,Hangzhou 310027)  
Anionic sodium dodecylbenienesulphonate (DBS) can be photodegradated in aqueous suspension of TiO2 powder by irradiation with a 300W high pressure mercury lamp. The photocatalytic ability of anatuse and rutile TiO2 in the solutions at different PH values has been studied. The effects of adding H2O2 and Cu2+ on the photodegradation have also been discussed. The results show that anatase TiO 2has a more efficiently catalytic ability than rutile TiO2. H2O2 can reduce the rate of degradation in a basic solution. Cu2+ can increase the rate of degradation in an acidic solution.
【Fund】: 国家自然科学基金
【CateGory Index】: X783.03
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