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《CHINESE JOURNAL OF ENVIROMENTAL SCIENCE》 1998-05
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Synthesis of Carboxylcontaining Grafted Chitosan Polymer and ItsAdsorption Properties for Heavy Metal Ions

Peng Changhong\ Wang Yuting\ Cheng Ge(Dept.of Environ.Sci.,Wuhan Univ.,430072) Tang Yurong(Center of Analysis Measurement,Wuhan Univ.,430072)  
Water insoluble crosslinkedchitosan was prepared by crosslinking soluble chitosan with epichlorodydrin and carboxylcontaining grafted chitosan polymer was obtained by grafting acrylonitrile onto the crosslinkedchitosan with ferrous sulfatehydrogen peroxide as the initiator and finally by subjecting it to basing saponification,whose structure was confirmed by elemental analysis,FTIR spectra analysis and Xray diffraction analysis.The adsorption properties for Cu2+、Cr3+、Cd2+ and Pb2+ were studied also.It could be seen that the content of nitrogen in CTCA is lower than that in CTS and CCTS,and the characteristic peak of —COONa appeares at 1570cm-1 and 1470cm-1 in CTCA.It was also found that CCTS and CTCA have the characteristic peak of pyranylibration at 900cm-1 which demonstrats that the ring of pyanyl is not destroyed in the reaction of crosslinking and grafting.The adsorption experimental results showed that CTCA has good adsorption capacities for Pb2+ and Cd2+;the adsorption speed of CTCA for Cd2+ is higher than that of Cu2+ and the adsorption capacities are also affected by the acidity of medium.The chelate mechanism was investigated by FTIR spectra analysis and the XPS data of CTCA and CTCACu2+.
【Fund】: 国家自然科学基金
【CateGory Index】: TQ424.3
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【References】
Chinese Journal Full-text Database 10 Hits
1 YU Jie;WANG Xing;LU Quan-fang;ZHENG Ji-dong;ZHANG Xiao-min;College of Chemistry and Chemical Engineering,Northwest Normal University;Editorial Department of the University Journal,Northwest Normal University;;Adsorption mechanism of chitosan/poly(acrylic acid) hydrogel for Pb~(2+)[J];西北师范大学学报(自然科学版);2017-04
2 LIN Yue-cheng;WANG Hong-peng;GONG Jin-yan;YANG Jun-xing;HU Sheng;MEI Le-he;HUANG Jun;School of Biological and Chemical Engineering, Zhejiang University of Science and Technology;Center for Environmental Remediation, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences;School of Biological and Chemical Engineering, Ningbo Institute of Technology, Zhejiang University;;Preparation of Modified Chitosan Microspheres and their Anionic Dye Adsorption Behaviors[J];高校化学工程学报;2017-02
3 JI Lei;XIE Shu-yuan;LIU Yan-ji;QIU Li-xin;LIU Jing-hai;DUAN Li-mei;Inner Mongolia University for Nationalities;;Study on lead ion adsorption of fly ash/chitosan composite[J];世界有色金属;2016-15
4 CAO Wei;LV Tong;CUI Li;DU Xiao;WANG Jun;School of Environment and Chemical Engineering Tianjin Polytechnic University;School of Material Science and Chemical Engineering Tianjin Polytechnic University;;ADSORPTION OF Cd(II) BY GLYCINE- AND 5-AMINOSALICYLIC ACIDS-MODIFIED STARCH[J];离子交换与吸附;2016-01
5 LIU Siman;WEN Jiang;BIN Shengnan;JIANG Shi;School of Chemistry and Chemical Engineering,Mianyang Normal University;;On Adsorption Properties of Modified Chitosanby Alanine for Strontium[J];绵阳师范学院学报;2015-08
6 XIA Qiang,LI Chen(School of Chemistry and Environmental Science,Shaanxi University of Technology,Hanzhong 723001,China);Research Progress on Wastewater Treatment with Chitosan and it′s Derivatives[J];化工技术与开发;2013-03
7 ;Chitosan modification and the application in adsorption for metal ions[J];海洋科学;2010-06
8 ZHENG Yi-an~1,XIE Yun-tao~(1,2),WANG Ai-qin~1(1.Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China;2.Graduate University of Chinese Academy of Sciences,Beijing 100049,China);Adsorption of Pb~(2+) onto Chitosan-Grafted-Poly (Acrylic Acid)/Sepiolite Composite[J];环境科学;2009-09
9 XIAO Hong-yan1,PAN Si-yi2,ZENG Qing-xiao(1.College of light industry and food science,South China University of Technology,Guangzhou 510640,China)(2.College of Food Science and Technology,Huazhong Agricultural University,Wuhan 430070,China);Optimization of Graft Copolymerization of Konjac Glucomannan and Acrylonitrile[J];现代食品科技;2009-01
10 YU Shao-ying (Fuzhou Technology College,Fuzhou 350000,China);Study on the adsorption of metal ion by cross-linked chitosan[J];吉林化工学院学报;2007-04
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 JIANG Yuan;HAO Ruixia;YANG Shiqin;School of Earth and Space Science, Peking University;;Natural Bioaccumulation of Heavy Metals onto Common Edible Macrofungi and Equilibrium and Kinetic Studies on Biosorption of Pb(Ⅱ) to Them[J];北京大学学报(自然科学版);2017-01
2 LU Quan-fang;ZHENG Ji-dong;YU Jie;YANG Shu-xiu;LI Yun;WANG Xing;ZHANG Xiao-min;Editorial Department of the University Journal,Northwest Normal University;Key Lab of Bioelectrochemistry and Environmental Analysis of Gansu Province,College of Chemistry and Chemical Engineering,Northwest Normal University;;Preparation of Chitosan/Poly(acrylic acid) Hydrogel and Its Adsorption Properties for Cu~(2+) and Cd~(2+)[J];精细化工;2016-12
3 YU Jie;ZHENG Jidong;LU Quanfang;YANG Shuxiu;WANG Xing;ZHANG Xiaomin;Key Lab of Bioelectrochemistry and Environmental Analysis of Gansu Province,College of Chemistry and Chemical Engineering,Northwest Normal University;Editorial Department of the University Journal,Northwest Normal University;;Adsorption selectivity and reusability of chitosan/poly (ethylene glycol)/acrylic acid adsorbent for Cu~(2+),Co~(2+) and Ni~(2+)[J];环境科学学报;2017-03
4 LIU Wan-Yi;YANG Lu-Ze;YU Meng;LIU Miao;Key Laboratory of Groundwater Resource and Environment,Ministry of Education,College of Environment and Resources,Jilin University;;Preparation of Poly( Acrylate-Acrylamide) Hydrogel and Its Adsorption Performance to Heavy Metal Ions[J];分析化学;2016-05
5 XIANG Yujun;XU Aiqing;ZHOU Xin;CHEN Lijuan;College of Life Science, Hunan University of Science and Technology;Key Laboratory of Ecological Remediation and Safe Utilization of Heavy Metal-Polluted Soils College of Hunan Province;;RESEARCH ON ADSORPTION OF CADMIUM IONS BY MODIFIED SODIUM LIGNOSULFONATE HYDROGEL[J];离子交换与吸附;2015-02
6 CHEN Da;LIU Fuqiang;XU Chao;WEI Mengmeng;WANG Junfei;State Key Laboratory of Pollution Control and Resource, School of the Environment Nanjing University;;EFFECTIVE REMOVAL OF HEAVY METAL IONS FROM HYPERSALINE WASTEWATER BY AMINOACETIC CHELATING RESIN[J];离子交换与吸附;2015-01
7 ZHANG Cong-lu;HU Xiao-min;ZHAO Yan;SU Lei;School of Pharmaceutical Engineering,Shenyang Pharmaceutical University;Institute of Resources and Civil Engineering,Northeastern University;;Adsorption Behavior of Anionic Dyes onto Magnetic Chitosan Derivatives[J];环境科学;2015-01
8 Du Fengling;Xu Min;Wang Gang;Chang Qing;School of Environmental and Municipal Engineering,Lanzhou Jiaotong University;;Research progress in flocculants applied to the treatment of wastewater containing heavy metals[J];工业水处理;2014-12
9 WU Xiuhong;TAO Weihua;CHEN Jian;FEI Zhenghao;Jiangsu Provincial Key Laboratory of Coastal Wetland Bioresources and Environmental Protection, Yancheng Teachers University;;ADSORPTION OF o-CRESOL ON MODIFIED ADSORPTIVE RESINS[J];离子交换与吸附;2014-06
10 YU Jie;YANG Gege;PAN Yuanpei;LU Quanfang;YANG Wu;GAO Jinzhang;Gansu Key Lab of Bioelectrochemistry and Environmental Analysis, College of Chemistry and Chemical Engineering, Northwest Normal University;Editorial Department of Journal of Northwest Normal University, Northwest Normal University;;Poly(Acrylamide-co-Acrylic Acid) Hydrogel Induced by Glow-Discharge Electrolysis Plasma and Its Adsorption Properties for Cationic Dyes[J];Plasma Science and Technology;2014-08
【Secondary References】
Chinese Journal Full-text Database 9 Hits
1 TIAN Ye;ZHANG Zhi-qiang;LIU Ying;ZHANG Lei;Dalian Ocean University,Aquaculture Engineering R&D Center;;Adsorption Materials Base on Chitosan for Treatment of Dye Wastewater[J];染料与染色;2017-06
2 WU Xue-wen;FU Yan;CHEN Hao-yu;YANG Jing;College of Environmental and Chemical Engineering, ShenYang Ligong University;;Study on Preparation of Chitosan and Blast Furnace Slag Composite Material and its Application in Wastewater Treatment[J];辽宁化工;2017-05
3 ZHANG Zhuanling;ZHANG Yi;LIU Ye;ZHANG Hao;School of Textiles, Tianjin Polytechnic University;;PROCESS OPTIMIZATION OF ARGININE GRAFTED CHITOSAN AND ADSORPTION CHARACTERISTICS OF Cu~(2+) AND Ni~(2+)[J];离子交换与吸附;2016-05
4 Tu Yujuan;Zhou Li;Zhang Sijia;Liang Longmei;Wang Zegong;Zhang Sinuo;College of Chemistry and Environmental Engineering Shenzhen University;;Preparation of Modified Chitosan and Its Adsorption Research of Metal Ions[J];广东化工;2016-22
5 XIE Jing-ru;CHEN Ben-shou;ZHANG Jin-zhong;LIU Jiang;Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment,Ministry of Education,College of Resources and Environment,Southwest University;Chongqing Chemical Engineering Vocational College;Chongqing Key Laboratory of Agricultural Resources and Environment;;Adsorption of Hg(Ⅱ) in Water by Sulfydryl-Modified Sepiolite[J];环境科学;2016-06
6 ZHOU Ai-hua;WANG Ai-ping;School of Biological and Chemical Engineering,Qingdao Technical College;Institute of Materials Science and Engineering,Ocean University of China;;Study on the Adsorption Properties of Cu( Ⅱ) on Crosslinked Chitosan Microsphere Resin[J];广州化工;2015-07
7 LI Chen;XIA Qiang;DAI Baocheng;School of Chemistry and Environmental Science,Shaanxi University of Technology;College of environmental science and engineering,Beijing forest university;ydrology and Water Resources Bureau of the Ningxia-Inner Mongolia Reach,Yellow River Conservancy Committee;;Research on Modification and Application of Sepiolite in Lead and Zinc Contained Wastewater Treatment[J];电镀与精饰;2015-01
8 GUAN Ju;SHEN He-ding;LIU Chen;WANG Dong-feng;LI duo;Key Laboratory of Exploration and Utilization of Aquatic Genetic Resources, Ministry of Education,Shanghai Ocean University;;Depuration of Cu and Cd in Onchidium struma[J];海洋科学;2015-01
9 Zhang Chenmu;Liu Jingyang;Sun Xiaoming;Xu Tongkuan;Bai Weinan;Key Laboratory of Eco-Industry of the Ministry of Environmental Protection,Chinese Research Academy of Environmental Sciences;Faculty of Light Industry and Chemical Engineering,Dalian Polytechnic University;;Treatment of wastewater containing low concentration of Cu ion using complexation-ceramic membrane with chitosan[J];环境工程学报;2015-01
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