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《Acta Scientiae Circumstantiae》 2011-09
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Determination of avermectin in pharmaceutical wastewater by rapid resolution liquid chromatography-tandem mass spectrometry

LI Zaixing1,2,*,ZUO Jian'e1,WU Chunxu1,ZHANG Jingxuan3,LI Hui3,JU Panpan2,YU Xin1 1.School of Environment,Tsinghua University,Beijing 100084 2.School of Environmental Science and Engineering,Hebei University of Science and Technology,Shijiazhuang 050018 3.China National Center for Quality Supervision and Test of Environmental Protection Products,Shijiazhuang 050015  
A method based on solid phase extraction-rapid resolution liquid chromatography-tandem mass spectrometry(SPE-RRLC-MS/MS) was developed to determine avermectin in pharmaceutical wastewater.Water samples were firstly purified through centrifugation and protein precipitation processes,and then the avermectin was enriched and purified with HLB SPE,separated through Agilent Plus C18 RRLC(rapid resolution liquid chromatography) using 0.1% formic acid solution and 50% to 90% methanol as mobile phase,and detected by mass spectrometry in positive ion mode with multiple reaction monitoring(MRM) using an electrospray ionization interface.The detection limit was 0.5 μg·L-1.The linear range was 0.1 μg·L-1 to 20 μg·L-1,with a coefficient of determination of 0.997.The recoveries at spiked concentrations of 0.1 μg·L-1,0.5 μg·L-1 and 4.0 μg·L-1 ranged from 73.31% to 111.03%,with a relative standard deviation(RSD) from 4.97% to 9.37%.The procedure provides a rapid,reliable and sensitive method for determination of avermectin in pharmaceutical wastewater.
【Fund】: “十一五”国家水体污染控制与治理科技重大专项(No.2008ZX07529-006)~~
【CateGory Index】: X832
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